Product ID:N-4158 BLACK TREE MARKING
MSDS Date:10/31/1991
FSC:8010
NIIN:01-273-3766
MSDS Number: BKMHV

NILES CHEMICAL PAINT CO

3RD AND FORT ST
NILES, MI 49120
US

Emergency Phone: 219-236-5856

Info Phone: 616-683-3377

Preparer: MIKE LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

MINERAL SPIRITS (VP 2.0 MM HG @ 20 C)

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 56%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM; 9293

ALKYD RESIN

Fraction By Weight: 22%

COBALT COMPOUNDS (AS CO)

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: < 1%

OSHA PEL 0.1 MG/M3;AS CO

ACGIH TLV: 0.05 MG/M3;DUST 9293

MANGANESE COMPOUNDS (AS MN)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: < 1%

OSHA PEL (C) 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 DUST 9293

PROPRIETARY INGREDIENTS

VOC 4.51 LBS/GAL

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:EYES;SEVERE IRRITATION, LACRIMATION,
REDNESS, BLURRED VISIONS, VISUAL DISTURBANCES AND EYE BURNS.
SKIN;HARMFUL IF ABSORBED THROUGH SKIN. CAN BE ABSORBED IN TOXIC
AMOUNTS ESPECIALLY FROM PROLONGED OR R EPEATED EXPOSURE.
BREAHTING;NASAL AND RESPIRATORY IRRITATION, CNS DEPRESSION
(DIZZINESS, DROWSINESS, WEAKNESS, FATIGUE**
Effects of Overexposure:**CONFUSION) NAUSEA, HEADACHE, VERTIGO,
POSSIBLE UNCONSCIOUSNESS, EVEN ASPHYXIATION.
SWALLOWING;GASTRIONTESTINAL IRRITATION, ABDOMINAL PAIN, NAUSEA,
VOMITING, DIARRHEA BLINDNESS AND EVEN DEATH.

First Aid:INHALED;MOVE TO FRESH AIR.IF BREATHING STOPPED GIVE
ARTIFICIAL RSPRTN.GET MED ATTN.SKIN;WASH W/SOAP/WATER.EYE;IMMED
FLUSH EYES W/LARGE AMNTS OF WATER FOR 15 MIN,OCCASION LIFTING
UPPER/LOWER LIDS.GET M ED ATTN IMMED.CONTACT LENSES SHOULD NOTBE
WORN.SWALLOWED;INDUCE VOMIT IMMED BY GIVING 2 GLASSES OF
WATER/STICKING FINGER DOWN THROAT.NEVER GIVE ANYTHING BY MOUTH TO
UNCONSCIOUS PERSON.GET MED ATTN.

Flash Point Method:TCC
Flash Point:102F,39C
Autoignition Temp:Autoignition Temp Text:NE
Lower Limits:0.8
Upper Limits:36.0
Extinguishing Media:DRY CHEMICAL, FOAM, CO2
Fire Fighting Procedures:WEAR SCBA W/FULL FACE OPERATED IN POS PRESS
MODE/FULL PROTECT CLOTHES.USE WATER TO COOL CLOSED CNTNRS TO
PREVENT PRESS BUILD-UP POSS AUTO IGNIT/EXPLO IN HEAT.
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLOSED.ISOLATE FROM
HEAT,SPARKS,OPEN FLAME.CLOSED CNTNRS EXPLODE IN HIGH
HEAT.APPLICATION TO HOT SURFACE REQUIRE SPECIAL PRECAUTION.

Spill Release Procedures:ELIMINATE ALL IGNIT SOURCES.MINIMIZE BREATHING
VAPORS/AVOID SKIN CONTACT.ABSORB W/INERT MAT'L;CLAY,SOIL,OR
COMMERCIAL AVAILABLE ABSORBENT.SHOVEL RECLAIMED LIQUID/ABSORBENT
INTO RECOVERY/SALVAGE DRUMS FOR DISPOSAL.DIKE TO PREVENT FURTHER
MOVEMENT.

Handling and Storage Precautions:AVOID STORAGE IN HIGH TEMP AREAS/NEAR
FIRE/OPEN FLAME.KEEP CONTAINERS CLOSED WHEN NOT IN USE.DO NOT
WELD/FLAME CUT ON EMPTY DRUMS.AVIOD ROUGH HANDLE.
Other Precautions:*DURING EMERGENCY CONDITIONS, OVEREXPOSURE TO
DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT
BE IMMEDIATELY APPARENT. OBTAIN MEDICAL ATTENTION.

Respiratory Protection:WEAR APPROPRIATE PROPERLY FITTED HALF-MASK/FULL
FACEPIECE RESPIRATOR DURING/AFTER APPLICATION UNLESS AIR MONITORING
DEMONSTRATES VAPOR/MIST LEVELS ARE BELOW APPLICABLE LIMITS.FOLLOW
RESPIRATOR MANUFAC TURER'S DIRECTIONS FOR USE.
Ventilation:SUFFICIENT VENT IN VOLUME/PATTERN TO KEEP AIR CONCENTRAT
BELOW CURRENT OSHA PERMISSIBLE LIMITS.
Protective Gloves:CHEM RESISTANT (NITRILE/VITON) GLOVES.
Eye Protection:CHEM GOGGLES,SAFETY, FACESHIELDS.
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING, OR USING
RESTROOM. REMOVE ANY CLOTHING THAT BECOMES WET AND WASH BEFORE
REUSE.
Supplemental Safety and Health

HCC:F4
Boiling Pt:B.P. Text:146 TO 330F
Vapor Density:> AIR
Viscosity:800-1000*
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:SLIGHT
Appearance and Odor:LIQUID, ODOR OF SOLVENTS
Percent Volatiles by Volume:70.94

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:HIGH TEMPERATURES, SHOCK FROM DROPPING
Hazardous Decomposition Products:CAN PRODUCE CARBON MONOXIDE AND/OR
CARBON DIOXIDE

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL,
STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.