Product ID:SK3
MSDS Date:12/10/1990
FSC:6810
NIIN:00-084-9334
MSDS Number: BKNSJ

FISHER SCIENTIFIC, CHEMICAL DIV.

1 REAGENT LANE
FAIR LAWN, NJ 07410
US

Emergency Phone: 201-796-7100 OR 201-796-7523

Info Phone: 201-796-7100

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

2-METHOXYETHANOL (EGME) (SARA III)

CAS: 109-86-4

RTECS: KL5775000

Fraction By Weight: 52.3%

OSHA PEL S, 25 PPM

ACGIH TLV: S, 5 PPM; 9192

PYRIDINE (SARA III)

CAS: 110-86-1

RTECS: UR8400000

Fraction By Weight: 26.5%

OSHA PEL 5 PPM

ACGIH TLV: 5 PPM; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

IODINE

CAS: 7553-56-2

RTECS: NN1575000

Fraction By Weight: 13.7%

OSHA PEL C 0.1 PPM

ACGIH TLV: C 0.1 PPM; 9192

SULFUR DIOXIDE (SARA III)

CAS: 7446-09-5

RTECS: WS4550000

Fraction By Weight: 7.4%

OSHA PEL 5 PPM/5 STEL

ACGIH TLV: 2 PPM/5 STEL; 9293

LD50 LC50 Mixture:LD50 (ORAL RAT) IS 891 MG/KG (PYRIDINE)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE-INHALATION:SULFUR DIOXIDE IS
CORROSIVE/SENSITIZER.MAY CAUSE CHEST PAIN,SEVERE CHOKING,VIOLENT
COUGH,UNCONSCIOUSNESS,POSSIBLY DEATH.EYE:IRRITANT &
CORROSIVE.SKIN:CORROSIVE,SENSITIZER,IRRITANT,NAR
COTIC.INGESTION:NARCOTIC,CORROSIVE,NEPHROTOXIN,KIDNEY & LIVER
DAMAGE.CHRONIC-CNS EFFECTS & TOXIC ENCEPHALOPATHY.
Effects of
Overexposure:HEADACHE,DIZZINESS,DROWSINESS,FATIGUE,ATAXIA,WEAKNESS,
TREMORS,GI UPSET,ANOREXIA,WEIGHT LOSS,PERSONALITY
CHANGES,CYANOSIS,ABDOMINAL & BACK PAIN,NAUSEA,VOMITING,INCREASED
URINARY FREQUENCY,NERVOUSNESS,V ERTIGO,GIDDINESS,FACIAL
PARALYSIS,ANEXITY,MENTAL CONFUSION,UNCONSCIOUSNESS.DEATH RESULTED
FROM LUNG & KIDNEY INJURY.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:GET IMMEDIATE MEDICAL CARE.INHALATION:REMOVE TO FRESH
AIR.GIVE CPR IF NEEDED.EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER
FOR 15-20 MINUTES HOLDING EYELIDS OPEN.SKIN:REMOVE CONTAMINATED
CLOTHING.WASH S KIN WITH SOAP AND
WATER.INGESTION:TREATSYMPTOMATICALLY.IF VOMITING OCCURS,KEEP HEAD
LOWER THAN HIPS TO PREVENT ASPIRATION.

Flash Point Method:CC
Flash Point:123F,51C
Extinguishing Media:USE WATER SPRAY, CARBON DIOXIDE, ALCOHOL-RESISTANT
FOAM, OR DRY CHEMICAL.EXTINGUISH ONLY IF FLOW CAN BE STOPPED.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS.KEEP UPWIND.COOL FIRE
EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.ISOLATE FOR 1/2 MILE IN
ALL DIRECTION S IF TANK/RAIL CAR IS INVOLVED IN FIRE

Spill Release Procedures:SHUT OFF IGNITION SOURCES.STOP LEAK IF NO
RISK.USE WATER TO REDUCE VAPORS.SMALL SPILLS:TAKE UP WITH
SAND/OTHER ABSORBENT MATERIAL & PLACE INTO CONTAINER.LARGE
SPILLS:DIKE FAR AHEAD OF SPILL FOR LATER DISPOSAL.NO
SMOKING,FLAMES/FLARES IN HAZARD AREA.
Neutralizing Agent:NOT APPLICABLE.

Handling and Storage Precautions:STORAGE-STORE AWAY FROM INCOMPATIBLE
SUBSTANCES.STORE IN ACCORDANCE WITH 29 CFR 1910.106.
Other Precautions:AVOID CONTACT WITH HEAT,SPARKS,FLAMES OR OTHER
SOURCES OF IGNITION.VAPORS MAY BE EXPLOSIVE AND POISONOUS;DO NOT
ALLOW UNNECESSARY PERSONNEL IN AREA.DO NOT OVERHEAT
CONTAINERS;CONTAINERS MAY VIOLENTLY RUPTURE IN HEAT OF FIRE.

Respiratory Protection:NIOSH-MSHA APPROVED TYPE "C" SUPPLIED-AIR
RESPIRATOR WITH A FULL FACEPIECE OPERATED IN PRESSURE-DEMAND OR
SELF-CONTAINED BREATHING APPARATUS OR ANY SUPPLIED-AIR RESPIRATOR
(WITH FULL FACEPIECE AND OPE RATED IN POSITIVE PRESSURE MODE).
Ventilation:MECHANICAL (GENERAL) ROOM VENTILATION AND LOCAL EXHAUST
BOTH REQUIRED.
Protective Gloves:APPROPRIATE PROTECTIVE GLOVES
Eye Protection:DUST-RESISTANT SAFETY GOGGLES&FACESHIELD
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING, APRON, AND BOOTS IF SPILLS OR
SPLASHING CAN OCCUR.
Work Hygienic Practices:WASH THOROUGHLY WITH SOAP AND WATER AFTER
HANDLING. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR.
Supplemental Safety and Health
FORMULATION CHANGED. SEE PART A FOR PREVIOUS FORMULATION.

HCC:F5
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=115.C, 239.F
Melt/Freeze Pt:=-60.C, -76.F
Decomp Temp:Decomp Text:NOT PROVIDED
Spec Gravity:1.16
Evaporation Rate & Reference:> 1 (N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:DARK BROWN LIQUID

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS,CAUSTICS,ACIDS,CCL4,CHROMIC
TRIOXIDE,ACETYLENE,ALUMINUM,NH3,ACROLEIN,BRF5,CESIUM AZIDE,PLASTICS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES
Hazardous Decomposition Products:THERMAL DECOMPOSITION INCLUDE TOXIC
AND HAZARDOUS IODINE AND IODINE COMPOUNDS,AND OXIDES OF
CARBON,NITROGEN AND SULFUR.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH STANDARDS
APPLICABLE TO GENERATORS OF HAZARDOUS WASTE, 40 CFR 262, EPA
HAZARDOUS WASTE NUMBER D001. 100 POUND CERCLA SECTION 103
REPORTABLE QUANTITY.PYRIDINE-REGULA TORY LEVEL:5 MG/L.EPA HAZARDOUS
WASTE NUMBER D038.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.