Product ID:GASOLINE UNLEADED
MSDS Date:05/31/1989
FSC:9130
NIIN:01-272-0983
MSDS Number: BKSYC

ASHLAND PETROLEUM CO DIV OF ASHLAND OIL INC

1409 WINCHESTER AVE
ASHLAND, KY 41114
US

Emergency Phone: 800-274-5263

Info Phone: 606-329-3333

Cage: 81355

ASHLAND INC

391 ASHLAND, KY 41114 US

Telephone: 800-622-6846

Cage: 81355

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: >95%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9192

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 1-5%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 3-7%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 3.8-9.0%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

P-XYLENE (P-DIMETHYLBENZENE) (SARA III)

CAS: 106-42-3

RTECS: ZE2625000

Fraction By Weight: 0.8-2.0%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 1-4%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9293

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE-INHALATION:CNS DEPRESSION,
IRRITATION OF RESPIRATORY TRACT. EYE:IRRITATION. SKIN:IRRITATION.
INGESTION:GI DISTURBANCES, ASPIRATION PNEUMONITIS.
CHRONIC:DERMATITIS, PNEUMONITIS, PULMONARY EDEMA, ANEMIA, LIVER &
KIDNEY DAMAGE.
Explanation of Carcinogenicity:CONTAINS B [71-43-2] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:EYE:SEVERE IRITATION, REDNESS, TEARING, BLURRED
VISION; SKIN:IRRITATION, DEFATTING, DERMATITIS; INHALE: NASAL AND
RESPIRATORY IRRITATION, DIZZINESS, WEAKNESS, FATIQUE, NAUSEA, ETC.;
INGEST: GASTROINTE STINAL IRRITATION, NAUSEA, VOMITING, DIARRHEA.
Medical Cond Aggravated by Exposure:RESPIRATORY DISORDERS.

First Aid:INHALATION:REMOVE TO FRESH AIR, PROVIDE CPR/OXYGEN IF NEEDED.
EYE CONTACT:FLUSH WITH WATER FOR 15 MINUTES. GET MEDICAL HELP. SKIN
CONTACT:WASH WITH SOAP AND WATER. GET MED ATTENTION IF SYMPTOMS
PERSIS T. INGESTION:DO NOT INDUCE VOMITING, DRINK 1-2 GLASSES OF
WATER. GET MEDICAL HELP IMMEDIATELY.

Flash Point Method:TCC
Flash Point:-40F/-40C
Lower Limits:1.5
Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WITH A
FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WHEN
FIGHTING FIRES.
Unusual Fire/Explosion Hazard:MATERIAL IS HIGHLY VOLATILE & READILY
GIVES OFF VAPORS WHICH MAY TRAVEL ALONG THE GROUND OR BE MOVED BY
VENTILATION & IGNITED BY PILOT LIGHTS, SPARKS, ETC.

Spill Release Procedures:SMALL SPILL: ELEMINATE ALL SOURCES OF IGNITION
AND ABSORB LIQUID ON VERMICULITE, INERT ABSORBENT, ETC, AND
TRANSFER TO HOOD. LARGE SPILL: ELEMINATE IGNITION SOURCES. DIKE
AREA TO CONTAIN. PUMP LIQUID TO SALVAGE TANK FOR LATER DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & OPEN
FLAME. KEEP CONTAINERS CLOSED WHEN NOT IN USE. USE OR STORE ONLY
WITH ADEQUATE VENTILATION.
Other Precautions:DO NOT TRANSFER TO UNLABELED CONTAINERS. DO NOT USE
CUTTING OR WELDING TORCH ON THIS CONTAINER. KEEP OUT OF REACH OF
THE CHILDREN.

Respiratory Protection:USE A NIOSH APPROVED AIR SUPPLIED RESPIRATOR IF
TLV IS EXCEEDED.
Ventilation:PROVIDE SUFFICIENT MECHANICAL VENTILATION AND/OR LOCAL
EXHAUST TO KEEP BELOW TLV.
Protective Gloves:NEOPRENE, NITRILE, RUBBER TYPES.
Eye Protection:CHEMICAL SPLASH GOGGLES.
Other Protective Equipment:CLOTHING AND BOOTS.
Work Hygienic Practices:DO NOT EAT, DRINK OR SMOKE WHILE WORKING WITH
THIS PRODUCT.
Supplemental Safety and Health

HCC:F2
Boiling Pt:B.P. Text:70F/21C
Vapor Pres:325 MMHG
Spec Gravity:0.74
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:CLEAR LIQUID, GASOLINE ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.

Waste Disposal Methods:RECLAIM, INCENERATE OR DISPOSE OF IN ACCORDANCE
WITH LOCAL, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.