Product ID:83241 SHELL SOL BT-67 EC
MSDS Date:08/08/1989
FSC:6850
NIIN:00F018526
MSDS Number: BKYCZ

SHELL OIL COMPANY

HOUSTON, TX 77210

Emergency Phone: (713) 473-9461

Info Phone: (713) 241-4819

Preparer: J. C. WILLETT

Cage: 54527

SHELL OIL COMPANY

2463 HOUSTON, TX 77210 US

Telephone: 800-231-6950

Cage: 54527

LIGHT ALIPHATIC NAPHTHA, VM & P NAPHTHA

CAS: 64742-89-8

Fraction By Weight: 91%

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 9%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

HEXANE (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: 2.8%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LD50 LC50 Mixture:ORAL (RAT) LD50: >25 ML/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: NOSE/THROAT/RESPIRATORY
TRACT IRRITATION/CNS DEPRESSION/PERIPHERAL NERVE
DAMAGE/GIDDINESS/HEADACHE/DIZZINESS/NAUSEA/UNCONSCIOUSNESS/COUGHING
/LABORED BREATHING/CYANOSIS/MUSCULAR WEAKNESS/SE NSATION LOSS IN
ARMS & LEGS/DEATH. SKIN: IRRITATION/DERMATITIS/DEFATTING/DRYING.
EYES: IRRITATION. INGESTION: VOMITING.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: CNS
DEPRESSION/GIDDINESS/HEADACHE/DIZZINESS/NAUSEA/COUGHING/LABORED
BREATHING/CYANOSIS/PERIPHERAL NERVE DAMAGE/MUSCULAR WEAKNESS/LOSS
OF SENSATION IN ARMS & LEGS/NOSE/THROAT/RESPIRATORY TR ACT
IRRITATION/CARDIAC EFFECTS. SKIN: DERMATITIS/BLUISH COLOR. EYES:
IRRITATION. INGESTION: PNEUMONITIS.
Medical Cond Aggravated by Exposure:EYE, SKIN, & RESPIRATORY DISORDERS,
IMPAIRED PERIPHERAL NERVE FUNCTION

First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN:
WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR.
GIVE CPR OR OXYGEN IF NEEDED. INGESTION: DON'T INDUCE VOMITING. IF
VOMITING O CCURS SPONTANEOUSLY, KEEP HEAD BELOW HIPS TO PREVENT
ASPIRATION OF LIQUID INTO LUNGS. OBTAIN MEDICAL ATTENTION IN ALL
CASES. (SEE SUPP).

Flash Point Method:TCC
Flash Point:<20F
Lower Limits:1%
Upper Limits:8%
Extinguishing Media:WATER FOG, FOAM, DRY CHEMICAL, CO2. DON'T USE A
DIRECT STREAM OF WATER.
Fire Fighting Procedures:EVACUATE AREA. WEAR FULL BUNKER GEAR (HELMET
W/FACE SHIELD/BUNKER COATS/GLOVES/BOOTS), INCLUDING POSITIVE
PRESSURE SCBA. COOL FIRE-EXPOSED CONTAINERS W/WATER.
Unusual Fire/Explosion Hazard:PRODUCT MAY FLOAT/REIGNITE ON WATER
SURFACE. VAPORS TRAVEL TO IGNITION SOURCE/FLASH-FIRE RESULTS.
CONTAINERS BUILDUP PRESSURE/RUPTURE/WEAKEN. FLAMMABLE.

Spill Release Procedures:ELIMINATE IGNITION SOURCES. EVACUATE AREA/WEAR
PROTECTIVE CLOTHING. SHUT OFF LEAK SOURCE SAFELY. DIKE/CONTAIN
W/CLAY/SAND. USE WATER FOG TO SUPPRESS VAPOR CLOUD. REMOVE W/VACUUM
TRUCK/PUMP TO VESSEL. PLACE IN NON-LEAKING SEALED CONTAINERS.

Handling and Storage Precautions:EMPTY CONTAINERS MAY CONTAIN EXPLOSIVE
VAPORS. PREVENT VAPOR ACCUMULATION. AVOID BREATHING VAPORS. AVOID
STATIC ELECTRICITY, WHICH CREATES HAZARD.
Other Precautions:GROUND FIXED EQUIPMENT. BOND/GROUND TRANSFER
CONTAINERS/EQUIPMENT. DON'T CUT/DRILL/GRIND/WELD NEAR CONTAINERS.
AVOID CONTACT W/SKIN & EYES. KEEP CONTAINERS CLOSED WHEN NOT IN
USE. USE W/ADEQUATE VENTI LATION.

Respiratory Protection:IF >TLV, USE A NIOSH-APPROVED RESPIRATOR TO
PREVENT OVEREXPOSURE. USE AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN
AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPORS.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:CHEMICAL-RESISTANT
Eye Protection:SAFETY GLASSES, GOGGLES
Other Protective Equipment:CHEMICAL-RESISTANT CLOTHING
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING/SHOES
BEFORE REUSE. AIR-DRY CONTAMINATED CLOTHING IN A WELL VENTILATED
AREA.
Supplemental Safety and Health
INTENTIONAL ABUSE, MISUSE OR OTHER MASSIVE EXPOSURE TO TOLUENE MAY
CAUSE MULTIPLE ORGAN DAMAGE OR DEATH. THIS PRODUCT IS LISTED ON THE
EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES IN ACCORDANCE W/SARA TI
TLE III, SECTIN 313.

Boiling Pt:B.P. Text:190-246F
Vapor Pres:90
Vapor Density:3.5
Spec Gravity:0.75
Evaporation Rate & Reference:(N-BU AC = 1): 3.85
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS LIQUID W/HYDROCARBON ODOR

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, SPARKS, DIRECT FLAME, PILOT LIGHTS,
CIGARETTES, & OTHER SOURCES OF IGNITION
Hazardous Decomposition Products:CO, UNIDENTIFIED ORGANIC COMPOUNDS

Waste Disposal Methods:DISPOSE OF FLUSH SOLUTIONS IN ACCORDANCE
W/FEDERAL, STATE, & LOCAL REGULATIONS. EXTREMELY FLAMMABLE. UN
1255.

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