Product ID:OIL OF VITRIOL, SX1242
MSDS Date:10/27/1988
FSC:6810
NIIN:00N018589
MSDS Number: BKZVD

E M SCIENCE

111 WOODCREST
CHERRY HILL, NJ 08034-0395
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 609-354-9200

Cage: 0SK29

E M SCIENCE DIV OF E M INDUSTRIES INC

70 GIBBSTOWN, NJ 08027 US

Telephone: 800-222-0342/609-423-6300

Cage: 63612

SULFURIC ACID (SARA III)

CAS: 7664-93-9

RTECS: WS5600000

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD50: (ORAL,RAT) 2140 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CAUSES SEVERE BURNS ON CONTACT WITH
ANY BODY TISSUE. POSSIBLY FATAL BY INHALATION OR INGESTION.
INHALATION OF MIST MAY DAMAGE RESPIRATORY TRACT AND LUNGS.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS
Medical Cond Aggravated by Exposure:RESPIRATORY CONDITIONS

First Aid:GET MED ASSISTANCE FOR ALL CASES OF OVEREXP. INGEST: DO NOT
INDUCE VOMITING; DILUTE BY GIVING MILK OR WATER IF CONSCIOUS; GET
MED ATTN IMMED. SKIN: FLUSH THOROUGHLY W/WATER; REMOVE ALL CONTAM
CLTHG/SH OES; GET IMMED MED ATTN. EYES: FLUSH W/WATER FOR AT LEAST
15 MIN, LIFT UPPER/LOWER LIDS OCCASNLY, CONTINUE FLUSHING WHILE
WAITING FOR MED HELP. INHAL: REMOVE TO FRESH AIR; GET IMMED MED
ASSISTANCE.

Flash Point:NON-COMBUSTIBLE
Extinguishing Media:DRY CHEMICAL OR SAND; DO NOT USE WATER OR FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:REACTS WITH MOST METALS TO FORM EXPLOSIVE
HYDROGEN GAS WHICH CAN FORM EXPLOSIVE MIXTURES WITH AIR. MAY IGNITE
COMBUSTIBLE MATERIAL ON CONTACT.

Spill Release Procedures:COVER WITH SAND; NEUTRALIZE WITH SODA ASH OR
LIME. TAKE UP AND CONTAINERIZE FOR PROPER DISPOSAL.
Neutralizing Agent:SEE SPILL PROCEDURES.

Handling and Storage Precautions:KEEP CNTNR CLOSED & PROTECTED AGAINST
PHYSICAL DMG. KEEP UPRIGHT; SEPARATE FROM ALL INCOMPAT MATLS,
COMBUST MATLS & OXIDIZING AGENTS. (SEE SUPP DATA)
Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE VAPOR. DO NOT
GET IN EYES, ON SKIN, OR ON CLOTHING. RETAINED RESIDUE MAY MAKE
EMPTY CONTAINERS HAZARDOUS; USE CAUTION!

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR SHOULD BE WORN IN
THE ABSENCE OF ADEQUATE VENTILATION.
Ventilation:MATERIAL MUST BE HANDLED OR TRANSFERRED IN A NIOSH/MSHA
APPROVED FUME HOOD OR WITH ADEQUATE VENTILATION.
Protective Gloves:NATURAL RUBBER, NEOPRENE OR EQUIVALENT.
Eye Protection:CHEMICAL WORKERS GOGGLES.(SEE SUPP DATA)
Other Protective Equipment:PROT CLTHG (NATURAL RUBBER, NEOPRENE OR
EQUIV) SHOULD BE WORN WHEN HNDLG MATL. EYE WASH & SAFETY EQUIP (SEE
SUPP DATA)
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
HNDLG/STOR PREC: WHEN DILUTING: ADD ACID TO WATER; NEVER ADD WATER TO
ACID. EYE PROT: ADD FULL LENGTH FACESHIELD TO GOGGLES . OTHER PROT
EQUIP: SHOULD BE READILY AVAILABLE. DELUGE SHOWER .

HCC:C1
Boiling Pt:B.P. Text:554F,290C
Melt/Freeze Pt:M.P/F.P Text:14F,-10C
Vapor Pres:1 @ 146C
Spec Gravity:1.844
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:MISCIBLE
Appearance and Odor:CLEAR, COLORLESS VISCOUS LIQUID; SHARP ODOR.

Stability Indicator/Materials to Avoid:YES
WATER, BASES, OXIDIZERS, REDUCING AGENTS, METAL POWDERS, CARBIDES,
ACETIC ACID, COMBUSTIBLE MATERIAL.
Stability Condition to Avoid:ADDING WATER TO ACID CAN CAUSE VIOLENT,
EXOTHERMIC REACTION, POSSIBLY CAUSING FIRE. CAN REACT VIOLENTLY
WITH ALKALIES.
Hazardous Decomposition Products:SOX, H (IN PRESENCE OF METALS)

Waste Disposal Methods:TO BE PERFORMED IN COMPLIANCE WITH ALL CURRENT
LOCAL, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.