Product ID:SUPELPREME-HC PHENOLS MIX 1 ML, 48904
MSDS Date:02/29/1988
FSC:6850
NIIN:00N019177
MSDS Number: BLDVG

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

2,4-DINITROPHENOL (SARA III)

CAS: 51-28-5

RTECS: SL2800000

Fraction By Weight: 0.2%

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

PHENOL, 2,4,6-TRICHLORO-; (2,4,6-TRICHLOROPHENOL),

CAS: 88-06-2

RTECS: SN1575000

Fraction By Weight: 0.2%

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

P-CHLORO-M-CRESOL (SARA III)

CAS: 59-50-7

RTECS: GO7100000

Fraction By Weight: 0.2%

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2-CHLOROPHENOL (SARA III)

CAS: 95-57-8

RTECS: SK2625000

Fraction By Weight: 0.2%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

2-NITROPHENOL (SARA III)

CAS: 88-75-5

RTECS: SM2100000

Fraction By Weight: 0.2%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

4-NITROPHENOL (P-NITROPHENOL) (SARA III)

CAS: 100-02-7

RTECS: SM2275000

Fraction By Weight: 0.2%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

DINITRO-O-CRESOL (SARA III)

CAS: 534-52-1

RTECS: GO9625000

Fraction By Weight: 0.2%

OSHA PEL S, 0.2 MG/M3

ACGIH TLV: S, 0.2 MG/M3; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

PENTACHLOROPHENOL (SARA III)

CAS: 87-86-5

RTECS: SM6300000

Fraction By Weight: 0.2%

OSHA PEL S, 0.5 MG/M3

ACGIH TLV: S, 0.5 MG/M3; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ORAL(RAT)384 MG/KG.

CAS: 108-95-2

RTECS: SJ3325000

Fraction By Weight: 0.2%

OSHA PEL 5 PPM, S

ACGIH TLV: 5 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYLENE CHLORIDE (SARA III)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 98%

OSHA PEL 500 PPM/C,1000; Z2

ACGIH TLV: 50 PPM, A2; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

2,4-DICHLOROPHENOL (SARA III)

CAS: 120-83-2

RTECS: SK8575000

Fraction By Weight: 0.2%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

2,4-DIMETHYLPHENOL (SARA III)

CAS: 105-67-9

RTECS: ZE5600000

Fraction By Weight: 0.2%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYE & SKIN IRRIT. NAUS, DIZZ. SEVERAL
CHRONIC INHAL STUDIES REPORTED BY NIOSH REVEALED THAT TEST ANIMALS
EXPOSED TO METHYLENE CHLORIDE CONC AS HIGH AS 10,000 PPM SHOWED
SLIGHT LIVER & KIDNEY CHANGES. METHYLENE CHLORIDE HAS BEEN SHOWN
TO INCR RATE OF SPONTANEOUSLY OCCURING MALIGNANT TUMORS IN ONE
STRAIN (EFT OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE:IARC GRP 2B, NTP GRP
2;2, 4,6-TRICHLOROPHENOL, NTP-2
Effects of Overexposure:HLTH HAZ:OF LAB MICE & BENIGN TUMORS IN LAB
RATS. CHLOROCARBON MATLS HAVE PRDCED SENSIT OF MYOCARDIUM TO
EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFT IN HUMANS.
ADRENOMIMETICS (E.G., EPINEPHRIN E) MAY BE CONTRAINDICATED EXCEPT
FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY/CHRONICALLY EXPOSED TO
CHLOROCARBONS .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:IMMED FLUSH W/POTABLE H20 FOR MINIMUM OF 15 MIN, SEEK
ASSIST FROM MD . SKIN:PROMPTLY WASH W/MILD SOAP & LG VOLS OF H20.
CALL MD. INHAL:IMMED MOVE TO FRESH AIR. GIVE O2 IF BRTHG LABORED.
IF BRTHG STOPS, GIVE ARTF RESP. CALL MD. INGEST:NEVER GIVE
ANYTHING BY MOUTH TO UNCON PERS. NEVER TRY TO MAKE UNCON PERS
VOMIT. GIVE SYRUP OF IPECAC. IMMED CALL MD.

Lower Limits:12%
Upper Limits:19%
Extinguishing Media:MATERIAL IS NOT FLAMMABLE. USE MEDIA SUITABLE FOR
SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THE FOLLOWING TOX VAPS ARE FORMED WHEN
MATL IS HEATED TO DECOMP:HCL, NOX. MAY INCLUDE PHOSGENE .

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. FLUSH AREA WITH WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFRIGERATE IN SEALED CNTNRS. KEEP
AWAY FROM OXIDIZERS & BASES. SOLN CONTAINS ONE/MORE CANCER SUSPECT
SUBSTANCES AT 0.2% LEVEL.
Other Precautions:AVOID EYE/SKIN CNTCT & BRTHG VAPS. NO SMOKING IN AREA
OF USE. DO NOT USE IN GEN VICIN OF ARC WELDING, OPEN FLAMES/HOT
SURF. HEAT &/OR UV RADIA MAY CAUSE FORMATION OF HCL &/OR PHOSGENE .

Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATORY PROTECTION.
Ventilation:USE ONLY IN EXHAUST HOOD.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEM WRKRS GOG &MAY ADD (SEE SUPPL DATA
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER. EYE PROT: FULL LENGTH FACESHIELD TO
GOGGLES .

HCC:T4
Boiling Pt:B.P. Text:104F,40C
Vapor Pres:350C
Solubility in Water:1.3
Appearance and Odor:CLEAR LIQUID, CHLOROFORM-LIKE ODOR.
Percent Volatiles by Volume:98

Stability Indicator/Materials to Avoid:YES
STRONG BASES, OXIDIZING AGENTS, CHEMICALLY ACTIVE METALS SUCH AS
ALUMINUM OR MAGNESIUM POWDERS POTASSIUM, SODIUM.
Hazardous Decomposition Products:HCL, NOX. PHOSGENE .

Waste Disposal Methods:COMPLY W/ALL APPLICABLE FEDERAL, STATE & LOCAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.