Product ID:4-BROMOFLUOROBENZENE 1ML, 48800
MSDS Date:01/01/1988
FSC:6810
NIIN:00N019121
MSDS Number: BLGKG

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

BENZENE, 1-BROM-4-FLUORO; (-1-BROMO-4-FLUORBENZENE)

CAS: 460-00-4

Fraction By Weight: 2.5%

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 97.5%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:SEE INGREDIENT.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INHALED. MAY BE FATAL IF
SWALLOWED. HEADACHE. NAUSEA. GASTROINTESTINAL DISTURBANCES.
BLINDNESS.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MIN. CONTACT PHYS.
SKIN: FLUSH WITH LARGE VOLUMES OF WATER. INHAL: IMMED MOVE TO FRESH
AIR. IF BREATHING STOPS, GIVE ARTF RESP. CONTACT PHYS. INGEST:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON. NEVER TRY TO MAKE
AN UNCON PERSON VOMIT. PRESS FINGERS TO BACK OF TONGUE TO INDUCE
VOMIT. IMMED CONT PHYS. GIVE 2 TABLESPOONS OF BAKING SODA IN A
GLASS OF H2O.

Flash Point:50.0F,10.0C
Lower Limits:6.0%
Upper Limits:36.5%
Extinguishing Media:CO2, DRY CHEMICAL. ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT WHEN FIGHTING A CHEMICAL FIRE.

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN SEALED CONTAINER IN COOL, DRY
LOCATION. KEEP AWAY FROM OXIDIZERS. KEEP AWAY FROM IGINTION
SOURCES.
Other Precautions:AVOID EYE/SKIN CONTACT. AVOID BREATHING VAPORS.

Respiratory Protection:WEAR NIOSH/MSHA APPROVED MASK WITH ORGANIC VAPOR
CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:RUBBER GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

HCC:F3
Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:100C
Vapor Density:1.10
Spec Gravity:.790
Evaporation Rate & Reference:>1(ETHER=1)
Solubility in Water:100
Appearance and Odor:COLORLESS LIQUID.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS. CHROMIC ANHYDRIDE, LEAD PERCHLORATE, PERCHLORIC
ACIDS.

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE, OR
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.