Product ID:PURGEABLES INTERNAL STD MIX 1ML CLP,
MSDS Date:10/18/1988
FSC:6850
NIIN:00N019165
MSDS Number: BLKBT

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

CHLOROBROMOMETHANE

CAS: 74-97-5

RTECS: PA5250000

Fraction By Weight: 0.1%

OSHA PEL 200 PPM

ACGIH TLV: 200PPM; 9192

BENZENE, 1,4-DIFLUORO

CAS: 540-36-3

RTECS: CZ5658000

Fraction By Weight: 0.1%

O-DICHLOROBENZENE (SARA III)

CAS: 95-50-1

RTECS: CZ4500000

Fraction By Weight: 0.1%

OSHA PEL C 50 PPM

ACGIH TLV: S, 25PPM/50 STEL9394

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99.7%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INHALED. MAY BE FATAL IF
SWALLOWED. HEADACHE, NAUSEA, GASTROINTESTINAL DISTURBANCES,
BLINDNESS.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: FLUSH EYES W/H2O FOR AT LEAST 15 MIN. CONT PHYS. SKIN:
FLUSH W/LRG VOL OF H2O. INHAL: IMMED MOVE TO FRESH AIR. IF BRTHG
STOPS, GIVE ARTF RESP. CONTACT PHYS. INGEST: NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. NEVER TRY TO MAKE AN UNCONSCIOUS
PERSON VOMIT. GIVE 2 TABLESPOONS OF BAKING SODA IN A GLASS OF H2O.
PRESS FINGERS TO BACK OF TONGUE TO INDUCE VOMIT. IMMED CONT PHYS.

Flash Point:50.0F,10.0C
Lower Limits:6.0%
Upper Limits:36.5%
Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER. KEEP
AWAY FROM OXIDIZERS. KEEP AWAY FROM IGNITION SOURCES.
Other Precautions:AVOID EYE OR SKIN CONTACT. AVOID BREATHING VAPORS.

Respiratory Protection:WEAR NIOSH/MSHA APPROVED FACE MASK WITH ORGANIC
VAPOR CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:RUBBER GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

HCC:F5
Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:100
Vapor Density:1.10
Spec Gravity:0.79
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:100
Appearance and Odor:CLEAR COLORLESS LIQUID, NO ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE, PERCHLORIC
ACIDS.

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE, OR
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.