Product ID:2-3-DIPHOSPHOGLYCERIC ACID KIT, 35-A
MSDS Date:11/22/1988
FSC:6810
NIIN:00N020452
MSDS Number: BLKHJ

SIGMA CHEMICAL COMPANY

ST. LOUIS, MO 63178

Emergency Phone: 314-771-5765

Info Phone: 800-325-3010; 314-771-5750

Cage: 21076

SIGMA CHEMICAL COMPANY

14508 ST LOUIS, MO 63178 US

Telephone: 314-771-5765

Cage: 21076

GLYCERALDEHYDE-3-PHOSPHATE DEHYDROGENASE/3-PHOSPHOGLYCERIC

PHOSPHOGLYCERATE MUTASE

CAS: 9032-62-6

ETHANOL, 2,2',2"-NITRILOTRI-; (TRIETHANOLAMINE BUFFER- 30%

CAS: 102-71-6

RTECS: KL9275000

TRICHLOROACETIC ACID

CAS: 76-03-9

RTECS: AJ7875000

OSHA PEL 1 PPM

ACGIH TLV: 1 PPM; 9192

B-NICOTINAMIDE ADENINE DINOCLEOTIDE; (B-NAD REDUCED FORM

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 4%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9192

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:MAY BE HARMFUL BY INHALATION,
INGESTION, OR SKIN ABSORPTION. MAY CAUSE IRRITATION. PROLONGED OR
REPEATED EXPOSURE MAY CAUSE ALLERGIC REACTIONS IN CERTAIN SENSITIVE
INDIVIDUALS. TOXICOLOGICAL PROPERTIE S HAVE NOT BEEN THOROUGHLY
INVESTIGATED.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST: WASH OUT MOUTH WITH WATER PROVIDED PERSON IS
CONSCIOUS. CALL MD. SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR
AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND SHOES AND
CALL MD. INHAL: R EMOVE TO FRESH AIR. IF BREATHING BECOMES
DIFFICULT, CALL MD. EYES: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR
AT LEAST 15 MINUTES. ASSURE ADEQUATE FLUSHING BY SEPARATING EYELIDS
WITH FINGERS. CALL MD.

Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER,
ALCOHOL OR POLYMER FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ABSORB ON SAND OR
VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE
AREA AND WASH SPILL SITE AFTER MATERIALS PICKUP IS COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:CAUTION - AVOID CONTACT AND INHALATION.

Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:CHEMICAL RESISTANT GLOVES
Eye Protection:CHEMICAL WORKERS GOGGLES
Other Protective Equipment:OTHER PROTECTIVE CLOTHING AS NEEDED.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

HCC:N1
Appearance and Odor:SUSPENSION.

Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:HEAT.
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE AND
CARBON DIOXIDE.

Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE, AND LOCAL
LAWS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.