Product ID:NO 5023 SAFETY SOLVENT AERO
MSDS Date:01/29/1990
FSC:6850
NIIN:00N020168
MSDS Number: BLLJH

HILL MANUFACTURING CO INC

1500 JONESBORO RD
ATLANTA, GA 30315
US

Emergency Phone: 404-522-8364

Info Phone: 404-522-8364

Preparer: RICK GLISSON

Cage: 66086

HILL MANUFACTURING CO INC

ATLANTA, GA 30315 US

Telephone: 404-522-8364

Cage: 66086

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 95%

OSHA PEL 350 PPM/450 STEL

ACGIH TLV: 350 PPM/450STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

Fraction By Weight: 4-5%

OSHA PEL 5000 PPM

ACGIH TLV: 5000PPM/30000STEL;93

ABSORBENT MATERIAL & SHOVELED INTO CONTAINERS.

RTECS: 9999999ZZ

ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: CAN CAUSE SEVERE IRRIT, REDNESS,
TEARING, BLURRED VISION. SKIN: PRLNG/RPTD CONT CAN CAUSE MODERATE
IRRIT, DEFAT, DERMAT. INHAL: EXCESSIVE INHAL OF VAPS CAN CAUSE
NASAL & RESPIRATORY IRRIT, DIZZ, WEAK, FATG, NAUS, HDACH, POSS
UNCON & EVEN ASPHY. INGEST: CAN CAUSE GI IRRIT, NAUS, VOMIT &
DIARR. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:CHLOROCARBON MATLS HAVE PRDCED SENSITIZATION OF
THE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & MAY HAVE A SIMILAR
EFFECT IN HUMANS. ADRENOMIMETICS (E.G. EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY
OR CHRONICALLY EXPOSED TO CHLOROCARBONS .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:SKIN: THORO WASH EXPOSED AREA W/SOAP & WATER. REMOVE CONTAM
CLTHG. LAUNDER CONTAM CLTHG BEFORE RE-USE. EYES: FLUSH W/LARGE AMTS
OF WATER, LIFTING UPPER/LOWER LIDS OCCAS, FOR A MINIMUM OF 15 MIN.
GET M EDICAL ATTN. INGEST: DO NOT INDUCE VOMIT. CALL MD OR
TRANSPORT TO AN EMER FACILITY. INHAL: REMOVE TO FRESH AIR. IF BRTHG
IS DFCLT, ADMIN O2. IF BRTHG HAS STOPPED, GIVE ARTF RESP. KEEP
(SUPP DATA)

Lower Limits:6%
Extinguishing Media:WATER FOG.
Fire Fighting Procedures:WATER MAY BE USED TO KEEP FIRE-EXPOSED CONTRS
COOL UNTIL FIRE IS OUT. WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND
SCBA & FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:TEMPERATURES OVER 120F. MAY CAUSE CAN TO
BURST. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL & PHOSGENE .

Spill Release Procedures:SMALL SPILL: ABSORB LIQUID ON PAPER,
VERMICULITE, FLOOR ABSORBENT OR OTHER ABSORBENT MATL. LARGE SPILL:
PERSONS NOT WEARING PROT EQUIP SHLD BE EXCLUDED FROM AREA OF SPILL
UNTIL CLEAN-UP HAS BEEN COMPL ETED. STOP SPILL AT SOURCE, DIKE AREA
(SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL DRY PLACE. NEVER STORE
IN UNLABELED OR IMPROPERLY LABELED CONTAINER.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. FOR COMMERCIAL/
INDUSTRIAL USE ONLY. NO SMKNG IN AREA OF USE. DO NOT USE IN THE GEN
VICIN OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV
RADIA MAY CAUSE THE F ORMATION OF HCL &/OR PHOSGENE .

Respiratory Protection:IF TLV OF THE PROD OR ANY COMPONENT IS EXCEEDED,
A NIOSH/MSHA JOINTLY APPRVD AIR SUPPLIED RESPIRATOR IS ADVISED IN
ABSENCE OF PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT OTHER
NIOSH/MSHA RESP UNDER SPEC IFIED CNDTNS. ENGINEERING OR (ING 4)
Ventilation:PROVIDE SUFFICIENT MECH (GENERAL) VENT &/OR LOCAL EXHAUST
TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:TO PREVENT REPEATED/PROLONGED SKIN CONTACT,
WEAR IMPERVIOUS CLOTHING & BOOTS.
Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE.
Supplemental Safety and Health
MATLS TO AVOID: WHICH CAN RSLT IN THERMAL DECOMP RELEASING HYDROGEN
CHLORIDE & SMALL AMTS OF PHOSGENE & CHLORINE. FIRST AID PROC:
PERSON WARM/QUIET & GET MED ATTN. SPILL PROC: OF SPILL TO PVNT
SPREADI NG, PUMP LIQUID TO SALVAGE TANK. REMAINING LIQUID MAY BE
TAKEN UP ON SAND, CLAY, EARTH, FLOOR ABSORB OR OTHER (ING 3)

HCC:T4
Boiling Pt:B.P. Text:165F,74C
Vapor Pres:100 @ 68F
Vapor Density:4.5
Spec Gravity:1.293-1.303
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NIL
Appearance and Odor:CLEAR COLORLESS THIN LIQUID WITH CHLORINATED
SOLVENT ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
WATER, REACTIVE METALS SUCH AS ALUMINUM & MAGNESIUM, OPEN FLAME,
WELDING ARCS, RESISTANCE HEATERS, ETC., (SUPP DATA)
Stability Condition to Avoid:TEMPERATURES OVER 120F. MAY CAUSE CAN TO
BURST.
Hazardous Decomposition Products:CO2 & CO, HYDROGEN CHLORIDE, PHOSGENE,
VARIOUS HYDROCARBONS, ETC.

Waste Disposal Methods:WRAP CAN IN SEVERAL LAYERS OF NEWSPAPER &
DISPOSE OF IN TRASH I/A/W STATE, FEDERAL, AND LOCAL REGULATIONS. DO
NOT INCINERATE OR THROW IN FIRE.

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of Defense. The United States of America in no manner whatsoever,
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disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.