Product ID:SPRAY GLOSS BLACK, 46-0860060
MSDS Date:11/09/1988
FSC:8010
NIIN:00N020969
MSDS Number: BLLNK

VALSPAR CORP

1101 THIRD ST SOUTH
MINNEAPOLIS, MN 55415
US

Emergency Phone: 800-228-5635

Info Phone: 612-332-7371

Cage: 13374

VALSPAR CORPORATION

MINNEAPOLIS, MN 55415 US

Telephone: 612-332-7371/888-345-5732

Cage: 23526

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 15 - 20%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ACETONE (SARA III)

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 30%

OSHA PEL 1000PPM

ACGIH TLV: 750PPM/1000STEL;9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

SOLVENT NAPHTHA (PETROLEUM), MEDIUM ALIPHATIC; (ALIPHATIC

CAS: 64742-88-7

Fraction By Weight: 1%

OSHA PEL 500 PPM (MFR)

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 1 - 10%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

2-BUTOXYETHANOL

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: 1 - 7%

OSHA PEL S, 50 PPM

ACGIH TLV: S, 25 PPM; 9293

PROPANE

CAS: 74-98-6

RTECS: TX2275000

Fraction By Weight: 20%

OSHA PEL 1000 PPM

ACGIH TLV: ASPHYXIANT; 9192

PROPANE, 2-METHYL-; (ISOBUTANE)

CAS: 75-28-5

RTECS: TZ4300000

Fraction By Weight: 15%

(EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:CAN BE ABSORBED THRU THE SKIN.
HARMFUL IF INHALED. MAY AFFECT THE BRAIN, NERV SYS OR RESP SYS,
CAUSING DIZZ, HDCH, NAUS OR RESP IRRIT. OVEREXPOS TO INGREDS IN
THIS PROD MAY CAUSE NOSE, THROAT, E YE & SKIN IRRIT, CNS DEPRESS,
MUC MEMB IRRIT, CORNEAL INJURY & EYE DAM. CHRONIC:CONTAINS GLYCOL
(SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:ETHER WHICH HAS BEEN SHOWN TO CAUSE
BLOOD EFTS DAM IN LAB ANIMALS. NOTICE:RPTS HAVE ASSOC RPTD/PRLNGD
OCCUP OVEREXPOS TO SOLV W/PERM BRAIN & NERV SYS DAM. INTENTIONAL
MISUE BY DELIBERATELY CO NCENTRATING & INHALING THE CONTENTS MAYBE
HARMFUL OR FATAL. CONTAINS INGREDS WHICH MAY CAUSE LIVER OR (SEE
SUPP DATA)
Medical Cond Aggravated by Exposure:ANY RESPIRATORY OR SKIN CONDITION.

First Aid:INHAL:REMOVE PERSON FROM EXPOSURE AREA. IF BREATHING HAS
STOPPED, USE MOUTH-TO-MOUTH RESUSCITATION & GET MD. EYE:FLUSH
W/WATER FOR AT LEAST 15 MINS. SKIN:WASH W/SOAP & WATER.

Flash Point Method:TCC
Flash Point:-10F,-23C
Lower Limits:0.7%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM &/OR WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . CONTAINERS EXPOSED TO FIRE SHOULD BE KEPT
COOL W/WATER SPRAY.
Unusual Fire/Explosion Hazard:CONTAINS OXIDIZING MATLS. CONTAMD RAGS,
WIPES, SAWDUST, ETC MAY CATCH FIRE SPONT. STORE WASTE UNDER WATER
IN CLSD METAL CONTRS UNTIL DISPOSED OF (SEE SUPP DATA)

Spill Release Procedures:VENTILATE AREA. AVOID BREATHING OF VAPORS.
ELIMINATE IGNITION SOURCES. REMOVE W/INERT ABSORBENT & NON-SPARKING
TOOLS. AVOID CONTACT W/EYES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE ABOVE 120F BASED ON PROD
FL PT & VP SUITABLE STOR SHOULD BE I/A/W OSHA REG 1910.106. KEEP
AWAY FROM HEAT, SPARKS & OPEN FLAMES.
Other Precautions:KEEP CONTR CLOSED WHEN NOT IN USE. EMPTY CONTRS MAY
CONTAIN PROD RESIDUE, INCLUDING FLAM OR EXPLOS VAPORS. DO NOT CUT,
PUNCTURE OR WELD ON OR NEAR CONTR. ALL LABEL WARNINGS MUST BE
OBSERVED UNTIL THE CONTR HAS BEEN CLEANED OR RECONDITIONED,

Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED FITTED RESP
DURING & AFTER APPLICATION UNLESS AIR MONITORING VAPOR/MIST LEVELS
ARE BELOW APPLICABLE LIMITS. FOLLOW RESP MANUFACTURERS DIRECTIONS
FOR RESP USE.
Ventilation:REQUIRED FOR SPRAYING OR IN A CONFINED AREA. VENTILATION
EQUIPMENT SHOULD BE EXPLOSION PROOF. ELIMINATE IGNIT SOURCES.
Protective Gloves:USUAL HAND PROT FOR PAINT APPLICATION.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:USUAL CLOTHING FOR PAINTING OPERATIONS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ:IN COMPLIANCE W/ALL APPLIC REGS. EFTS OF OVEREXP:KIDNEY DAM.
ANIMAL STUDIES HAVE CLEARLY DEMONSTRATED DOSE- RELATED ADVERSE EFTS
ON THE CNS, HEMATOPOIETIC TISS, BLOOD, KIDNEYS & THE LIVER AS SOC
W/THE ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER (EGBE) & ETHYLENE
GLYCOL MONOBUTYL ETHER ACETATE (EGBEA). (SEE ING 8)

HCC:V3
Vapor Pres:40PSIA@70F
Vapor Density:<1
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:NO
Appearance and Odor:NORMAL FOR A COATINGS PRODUCT.
Percent Volatiles by Volume:85

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE &
METAL OXIDES.

Waste Disposal Methods:DISPOSE IN CHEMICAL DISPOSAL AREA OR IN A MANNER
THAT COMPLIES W/LOCAL, STATE & FEDERAL REGULATIONS. DO NOT
INCINERATE CLOSED CONTAINERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.