Product ID:50-363 BLACK STENCIL
MSDS Date:06/04/1990
FSC:7510
NIIN:00-969-7910
MSDS Number: BLRFJ

NILES CHEMICAL PAINT COMPANY

225 FORT STREET
NILES, MI 49120

Emergency Phone: (219) 236-5856

Info Phone: (616) 683-3377

Preparer: MICHAEL LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

HYDROCARBON PROPELLANT, PETROLEUM GASES LIQUEFIED

CAS: 68476-86-8

Fraction By Weight: 30%

OSHA PEL 1000 PPM

ACETONE (SARA III)

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 26 - 32%

OSHA PEL 1000PPM

ACGIH TLV: 750PPM/1000STEL;9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 10 - 30%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 9%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

RESIN

Fraction By Weight: 6%

STODDARD SOLVENT

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 2%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM; 9293

METHYL ISOBUTYL KETONE (SARA III)

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 2%

OSHA PEL 100 PPM/75 STEL

ACGIH TLV: 50 PPM/75 STEL; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

COBALT (SARA III)

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: <1%

OSHA PEL 0.1 MG/M3;AS CO

ACGIH TLV: 0.05 MG/M3;DUST 9293

PROPRIETARY INGREDIENTS

Fraction By Weight: <15%

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SKIN: REDNESS, IRRITATION, DEFATTING,
& DERMATITIS. INHALATION: NASAL & RESPIRATORY IRRITATION, CNS
DEPRESSION, DIZZINESS, NAUSEA, HEADACHE, VERTIGO, UNCONSCIOUSNESS,
& ASPHYXIATION. EYES: IRRITATION & WATERING.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SKIN: REDNESS/IRRITATION/DEFATTING/DERMATITIS.
INHALATION: PERMANENT BRAIN & NERVOUS SYSTEM
DAMAGE/DISORIENTATION/FROSTBITE/NARCOSIS/COMA/INCOHERENCE/ANOREXIA/
EUPHORIA/NERVOUSNESS/INSOMNIA/PARESTHESIA /PHOTOPHOBIA/EFFECTS TO
GI TRACT, BLOOD, LIVER, & KIDNEYS. EYES: CORNEAL VACUOLIZATION,
IRRITATION & WATERING.

First Aid:INHALATION: REMOVE TO FRESH AIR. PROVIDE OXYGEN IF BREATHING
IS DIFFICULT. IF BREATHING HAS STOPPED, PERFORM ARTIFICIAL
RESPIRATION. SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/LARGE AMOUNTS
OF WATER FOR AT LEAST 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL
CASES.

Flash Point Method:CC
Flash Point:<-104F
Lower Limits:0.8%
Upper Limits:12%
Extinguishing Media:DRY CHEMICAL, FOAM, CO2.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS W/FULL
FACEPIECE OPERATED IN POSITIVE PRESSURE MODE & FULL PROTECTIVE
CLOTHING.
Unusual Fire/Explosion Hazard:CANS RUPTURE FROM INTERNAL PRESSURE AT
190F/DISCHARGE FLAMMABLE CONTENTS. VAPORS >AIR/TRAVEL ALONG GROUND
TO IGNITION SOURCE. FLAMMABLE. AUTOIGNITION TEMP: 806F

Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. ABSORB W/AN
INERT MATERIAL SUCH AS CLAY, SOIL, OR A COMMERCIALLY AVAILABLE
ABSORBENT. SHOVEL RECLAIMED LIQUID & ABSORBENT INTO RECOVERY OR
SALVAGE DRUMS FOR DISPOSAL.

Handling and Storage Precautions:AVOID INHALATION OF VAPORS & CONTACT
W/SKIN. DON'T STORE >120F. DON'T SPRAY IN EYES. DON'T STICK
PIN/SHARP OBJECT INTO OPENING ON TOP OF CAN.
Other Precautions:FINGER MUSTN'T PROTRUDE OVER FRONT OF SPRAY BUTTON.
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE
CONTENTS MAY BE HARMFUL OR FATAL. DON'T WEAR CONTACT LENSES.

Respiratory Protection:NONE REQUIRED FOR CASUAL USE. USE NIOSH/MSHA TC
23C OR EQUIVALENT, OR EVACUATE AREA IF NECESSARY.
Ventilation:IN VOLUME & PATTERN TO KEEP Protective Gloves:AS REQUIRED
Eye Protection:AS REQUIRED
Other Protective Equipment:AS REQUIRED
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS AFTER USE & BEFORE EATING, SMOKING, OR USING
RESTROOM.
Supplemental Safety and Health
EVAPORATION RATE: SLOWER THAN ETHER (SOLVENT); FASTER THAN ETHER
(PROPELLANT).

Boiling Pt:B.P. Text:<0F
Vapor Density:>AIR
Evaporation Rate & Reference:SEE SUPP
Appearance and Odor:VAPOR, ODOR OF SOLVENTS
Percent Volatiles by Volume:90.76%

Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:ELECTRICAL EQUIPMENT/OPEN FLAME/HOT
SURFACES/ELECTRICAL, STATIC, OR FRICTIONAL SPARKS/TEMPS >120F/OTHER
IGNITION SOURCES
Hazardous Decomposition Products:TOXIC FUMES, HYDROGEN CHLORIDE, CO, &
PHOSGENE

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS. DON'T PUNCTURE OR INCINERATE CAN. FLAMMABLE.
UN 1950. D001 (IGNITABLE).

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.