Product ID:MINERAL SPIRITS-66, PD 680 II
MSDS Date:10/14/1987
FSC:8010
NIIN:00N019808
MSDS Number: BLVJF

SHELL OIL CO

PRODUCT SAFETY & COMPLIANCE
HOUSTON, TX 77210
US

Emergency Phone: 713-473-9461;800-424-9300(CHEMTREC)

Info Phone: 713-241-4819

Preparer: JOHN P SEPESI

Cage: SHELO

SHELL OIL COMPANY

4320 HOUSTON, TX 77210 US

Telephone: 800-231-6950

Cage: 54527

IF MORE THAN 2.0 ML PER KG HAS BEEN

RTECS: 9999999ZZ

W/SUPERVISION. KEEP VICTIM'S HEAD BELOW HIPS TO

RTECS: 9999999ZZ

CONVULSIONS/UNCON OCCUR BEFORE EMESIS, GASTRIC

RTECS: 9999999ZZ

SOAK UP RESIDUE W/ABSORB SUCH AS CLAY, SAND OR

RTECS: 9999999ZZ

& SEAL TIGHTLY FOR PROPER DISP. FLUSH AREA W/H*2O TO

RTECS: 9999999ZZ

TAKE UP WITH ABSORBENT MATERIAL AND

RTECS: 9999999ZZ

USE WITH ADEQUATE VENTILATION.

RTECS: 9999999ZZ

MINERAL SPIRITS (MIX OF C8-C12 HYDROCARBONS); (MINERAL

Fraction By Weight: 100%

OSHA PEL 500 PPM (STOD SOLV)

ACGIH TLV: 100 PPM (STOD SOLV)

(ORAL,RAT) >25 ML/KG.

CAS: 64742-88-7

Fraction By Weight: >90%

(ORAL,RAT) 4.7 G/KG.

CAS: 64742-95-6

Fraction By Weight: <10%

VOMIT OCCURS SPONT, KEEP HEAD BELOW HIPS TO

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS 2 & 3.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: LIQ IS MIN IRRIT TO EYES. HIGH
VAP CONC MAY CAUSE IRRIT. SKIN: LIQ IS SLIGHTLY IRRIT TO SKIN.
PRLNGD/RPTD LIQ CONT CAN RSLT IN DEFAT & DRYING OF SKIN WHICH MAY
RSLT IN SKIN IRRIT & DERM. INHAL: V APS MAY BE IRRIT TO NOSE,
THROAT & RESPTRACT. HIGH VAP CONC MAY CAUSE CNS DEPRESSION. INGEST:
(SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: INGEST OF PROD MAY RSLT IN VOMIT;
ASPIR (BRTHG) OF VOMIT INTO LUNGS MUST BE AVOIDED AS EVEN SMALL
QTYS MAY RSLT IN ASPIR PNEUM. SIGNS & SYMP: IRRIT AS NOTED ABOVE.
EARLY TO MODERATE CNS DEPR ESSION MAY BE EVIDENCED BY GIDDINESS,
HDCH, DIZZ & NAUS; IN EXTREME CASES, UNCON & DEATH MAY OCCUR. ASPIR
(SUPP DATA)
Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN AND
RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS
PRODUCT.

First Aid:EYE: FLUSH EYES W/PLENTY OF H2O FOR AT LEAST 15 MIN WHILE
HOLDING EYELIDS OPEN. GET MED ATTN. SKIN: REMOVE CONTAM
CLTHG/SHOES. FLUSH SKIN W/H2O. FOLLOW BY WASHING W/SOAP & H2O. IF
IRRIT OCCURS, GET ME D ATTN. DO NOT REUSE CLTHG UNTIL CLEANED.
INHAL: REMOVE VICTIM TO FRESH AIR & PROVIDE O2 IF BRTHG IS DFCLT.
GIVE ARTF RESP IF NOT BRTHG. GET MED ATTN. INGEST: DO NOT INDUCE
VOMIT. IF (SEE ING 4)

Flash Point Method:TCC
Flash Point:112F,44C
Lower Limits:1%
Upper Limits:6%
Extinguishing Media:USE H2O FOG, FOAM, DRY CHEM/CO2. DO NOT USE DIRECT
STREAM OF H2O. PROD WILL FLOAT & CAN BE REIGNITED ON SURF OF H2O.
Fire Fighting Procedures:CAUTION. COMBUST. DO NOT ENTER CONFINED FIRE
SPACE W/OUT FULL BUNKER GEAR (HELMET W/FACESHIELD, BUNKER COATS,
GLOVES & RUB BOOTS), INCLUDING A NIOSH/ (SUP DAT)
Unusual Fire/Explosion Hazard:CNTNRS EXP TO INTENSE HEAT FROM FIRES SHD
BE COOLED W/H2O TO PVNT VAP PRESS BUILDUP WHICH COULD RSLT IN CNTNR
RUPTURE. CNTNR AREAS EXP TO DIRECT (SUPP DATA)

Spill Release Procedures:CAUTION. COMBUST. LRG SPILLS: ELIMINATE
POTENTIAL SOURCES OF IGNIT. WEAR APPROP NIOSH/MSHA APPRVD RESP &
OTHER PROT CLTHG. SHUT OFF SOURCES OF LEAK ONLY IF SAFE TO DO SO.
DIKE & CONT. REMOVE W/VACUUM TRUCKS/PUMP TO STORAGE/SALVAGE
VESSELS.(ING 8)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP LIQ & VAP AWAY FROM HEAT, SPARKS
& FLAME. SURFS THAT ARE SUFFICIENTLY HOT MAY IGNIT EVEN LIQ PROD IN
ABSENCE OF SPARKS OF FLAME.
Other Precautions:EXTING PILOT LIGHTS,CIGARETTES & TURN OFF OTHER
SOURCES OF IGNIT PRIOR TO USE & UNTIL ALL VAPS ARE GONE.VAPS MAY
ACCUMULATE & TRAVEL TO IGNIT SOURCES DISTANT FROM HNDLG SITE;
FLASH-FIRE CAN RSLT. KEEP CNTNRS CLSD WHEN NOT IN USE. (ING 11)

Respiratory Protection:AVOID PRLNGD/RPTD BRTHG OF VAPS. IF EXPOS
MAY/DOES EXCEED OCCUPATIONAL EXPOS LIMITS(SEE INGREDS).USE A
NIOSH/MSHA APPRVD RESP TO PREVENT OVEREXP. IN ACCORD W/29 CFR
1910.134 USE EITHER AN ATMOSPHERE- SUP RESP/AIR-PURIFYING RESP FOR
ORG VAPS
Ventilation:USE EXPLO-PROOF VENT AS REQD TO CNTRL VAP CONC. AIR-DRY
CONTAM CLOTHING IN WELL VENT AREA, THEN LAUNDER BEFORE REUSING.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING.
Work Hygienic Practices:LAUNDER CLOTHING BEFORE REUSE.
Supplemental Safety and Health
FIRE FIGHT PROC: MSHA APPRVD POS PRESS SCBA. COOL FIRE EXPOSED CNTNRS
W/H2O. EXPLO HAZ: FLAME CONT SHOULD BE COOLED W/ LRG QTYS OF WATER
AS NEEDED TO PVNT WEAK OF CNTNR STRUCTURE. EFTS OF OVEREXP: PNE
UMONITIS MAY BE EVIDENCED BY COUGHING, LABORED BRTHG & CYANOSIS
(BLUISH SKIN); IN SEVERE CASES DEATH MAY OCCUR.

HCC:F4
Boiling Pt:B.P. Text:317F,158C
Vapor Pres:<5 @ 100 F
Vapor Density:4.8
Spec Gravity:0.78
Evaporation Rate & Reference:<0.1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIGHT COLORED LIQUID. HYDROCARBON ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE AND UNIDENTIFIED
ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION.

Waste Disposal Methods:UDER EPA-RCRA (40 CFR 261.21), IF PROD BECOMES
WASTE MATL, IT WOULD BE IGNITABLE HAZ WASTE, HAZ WASTE NUMBER D001.
REFER TO LATEST EPA, FEDERAL, STATE OR LOCAL REGULATIONS REGARDING
PROPER DISPOSAL.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.