Product ID:1,1,2-TRICHLOROTRIFLUOROETHANE
MSDS Date:07/01/1989
FSC:6850
NIIN:00-984-5853
MSDS Number: BMCDT

Emergency Phone: 616-726-3171/800-424-9300(CHEMTREC)

Info Phone: 616-726-3171

Cage: 2H215

Telephone: 800-368-0050/800-707-4555

Cage: 2H215

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: CA 100%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE-EYE:CAN BE
IRRITATING.SKIN:PROLONGED/REPEATED CONTACT CAN CAUSE
IRRITATION,DEFATTING & DERMATITIS.INHALE:CAN CAUSE
DIZZINESS,EXCITEMENT & INTOXICATION.HIGH CONCENTRATIONS CAN CAUSE
CARDIAC ARRHY THMIAS.ORAL:CAN CAUSE GASTROINTESTINAL TRACT
DISCOMFORT.CHRONIC-INHALATION CAUSES CARDIAC ARRHYTHMIAS.
Effects of Overexposure:1,1,2-TRICHLOROTRIFLUOROETHANE IS A MILD EYE
AND MUCOUS MEMBRANE IRRITANT AND PRIMARY SKIN IRRITANT. ACUTE
EXPOSURE CAUSES IRRITATION, DIZZINESS AND GASTROINTESTINAL TRACT
DISCOMFORT.
Medical Cond Aggravated by Exposure:PRECLUDE FROM EXPOSURE THOSE
INDIVIDUALS SUSCEPTIBLE TO DERMATITIS.

First Aid:SEEK MEDICAL HELP IN ALL CASES.EYES:FLUSH WITH WATER FOR AT
LEAST 15 MINUTES.SKIN:WASH WITH SOAP & WATER.INHALED:REMOVE TO
FRESH AIR.PROVIDE CPR/OXYGEN IF NEEDED.ORAL:DO NOT INDUCE
VOMITING.CALL A PHY SICIAN OR LOCAL POISON CONTROL CENTER.

Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:680C
Extinguishing Media:CARBON DIOXIDE, FOAM OR DRY CHEMICAL. WATER SPRAY
MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL & FLUSH SPILLS
AWAY.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:CONCENTRATED VAPORS CAN BE IGNITED BY
HIGH INTENSITY HEAT SOURCE OR FLAME. TOXIC AND CORROSIVE GASES ARE
FORMED ON CONTACT WITH FLAMES OR HOT GLOWING SURFACES.

Spill Release Procedures:VENTILATE AREA - ESPECIALLY LOW PLACES WHERE
HEAVY VAPOR MIGHT COLLECT.REMOVE OPEN FLAMES. USE SELF-CONTAINED
BREATHING APPARATUS FOR LARGE SPILLS OR RELEASES. DIKE SPILLS. PICK
UP LIQUID ON SUITABLE ABSORBENT AND STORE IN SEALED CONTAINERS.
Neutralizing Agent:NONE

Handling and Storage Precautions:STORAGE-STORE IN A DRY,WELL VENTILATED
AREA AWAY FROM HIGH HEAT & DIRECT SUNLIGHT.
Other Precautions:KEEP THIS AND ALL CHEMICALS OUT OF REACH OF CHILDREN.
THIS PRODUCT FOR INDUSTRIAL USE ONLY. AVOID BREATHING VAPORS/MISTS.
AVOID CONTACT WITH EYES AND SKIN.

Respiratory Protection:USE APPROVED RESPIRATOR EQUIPMENT. FOLLOW NIOSH
AND EQUIPMENT MANUFACTURER'S RECOMMENDATIONS TO DETERMINE
APPROPRIATE EQUIPMENT (AIR-PURIFYING, AIR-SUPPLIED OR
SELF-CONTAINED BREATHING APPARATUS).
Ventilation:LOCAL EXHAUST WHEN LARGE AMOUNTS ARE RELEASED. FOR LOW
PLACES, USE MECHANICAL VENTILATION.
Protective Gloves:NEOPRENE OR NITRILE RUBBER
Eye Protection:CHEMICAL SPLASH GOGGLES/FACE SHIELD
Other Protective Equipment:APRON AND WORK CLOTHING TO MINIMIZE
EXPOSURE. EYE WASH STATION & SAFETY SHOWER RECOMMENDED.
Work Hygienic Practices:WASH THOROUGHLY AFTER USE AND BEFORE EATING,
DRINKING OR USING TOILET FACILITIES.
Supplemental Safety and Health

HCC:N1
Boiling Pt:B.P. Text:117F,47C
Melt/Freeze Pt:M.P/F.P Text:-34F,-36C
Vapor Pres:284 @ 20C
Vapor Density:6.5
Spec Gravity:1.564
Evaporation Rate & Reference:>1 (N-BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID WITH A SLIGHT ETHER-LIKE
ODOR
Percent Volatiles by Volume:CA 100

Stability Indicator/Materials to Avoid:YES
ACTIVE METALS
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES, OPEN CONTAINERS
AND POOR VENTILATION
Hazardous Decomposition Products:HYDROCHLORIC AND HYDROFLUORIC ACIDS,
PHOSGENE AND CHLORINE

Waste Disposal Methods:MATERIAL MAY BE DISPOSED OF BY A LICENSED
RECLAIMER OR INCINERATION FACILITY. COMPLY WITH LOCAL, STATE AND
FEDERAL REGULATIONS. EPA HAZARDOUS WASTE NOS. F001 AND F002 MAY
APPLY TO WASTE MATERIALS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.