Product ID:STAFOAM 406 COMBONENT 2 PART B
MSDS Date:02/20/1992
FSC:9330
NIIN:01-029-8294
Kit Part:Y
MSDS Number: BMDTV

EXPANDED RUBBER AND PLASTIC CORP

14000 S WESTERN AVE
GARDENA, CA 90249-3008
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 213-324-6692 OR 213-321-4260

Cage: 25598

EXPANDED RUBBER AND PLASTIC CORP

GARDENA, CA 90249-3008 US

Telephone: 310-321-4260

Cage: 25598

TOLUENE-2,4-DIISOCYANATE (TDI) (SARA III)

CAS: 584-84-9

RTECS: CZ6300000

Fraction By Weight: 70%

OSHA PEL C,0.02 PPM/0.02 STEL

ACGIH TLV: 0.005PPM/0.02STEL;93

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

POLYESTER POLYOL

Fraction By Weight: 30%

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION- IRRITATION OF
RESPIRATORY TRACT, LUNG IMPAIRMENT, PULMONARY EDEMA. EYES- BURNS,
IRRITATION. SKIN- BURNS, IRRITATION. INGESTION- ABDOMINAL DISTRESS.
CHRONIC: LUNG DAMAGE, POSSIBLE CA NCER.
Explanation of Carcinogenicity:NTP LISTS TOLUENE DIISOCYANATE AS A
POSSIBLE CARCINOGEN, IARC AS A SUSPECTED CARCINOGEN (ANIMAL).
Effects of Overexposure:INHALATION: COUGHING, SHORTNESS OF BREATH,
WEAKNESS, BURNING SENSATION IN LUNGS. EYES: BURNS, TEARING, PAIN.
SKIN: BURNS, BLISTERING, REDNESS, RASH. INGESTION: NAUSEA,
VOMITING.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN AND RESPIRATORY
CONDITIONS MAY BE AGGRAVATED.

First Aid:INHALATION: REMOVE TO FRESH AIR. RESUSCITATE IF NEEDED. GET
IMMEDIATE MEDICAL ATTENTION. EYES: FLUSH WITH LOTS OF WATER UNTIL
ALL MATERIAL GONE. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED
CLOTHI NG. WASH WITH SOAP AND WATER. INGESTION: GIVE PLENTY OF
WATER. DO NOT INDUCE VOMITING! GET IMMEDIATE MEDICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:260F,127C
Lower Limits:0.9 %
Upper Limits:9.5 %
Extinguishing Media:WATER FOG, CARBON DIOXIDE, OR FOAM
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:WATER CONTAMINATED MATERIAL WILL GENERATE
CARBON DIOXIDE WHICH MAY PRODUCE EXPLOSIVE RUPTURE OF THE
CONTAINERS WHEN EXPOSED TO FIRE CONDITIONS.

Spill Release Procedures:SHUT OFF/REMOVE SOURCES OF IGNITION. CONTAIN
SPILL. WEAR PROPER PROTECTIVE CLOTHING INCLUDING RESPIRATORY
PROTECTION. ABSORB WITH SAWDUST OR SWEEPING COMPOUND AND PLACE IN A
CLEAN, DRY CONTAINER. DECO NTAMINATE SPILL AREA.
Neutralizing Agent:DECON SOLUTION: 90 % WATER, 8 % AMMONIA, AND 2 %
DETERGENT.

Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS IN
A DRY, COOL AREA WHERE TEMPERATURE IS 70-90F.
Other Precautions:THIS MATERIAL REACTS WITH WATER AND OTHER MATERIALS;
PRODUCING CARBON DIOXIDE GAS. THIS MAY CAUSE AN EXPLOSIVE RUPTURE
IN TIGHTLY SEALED CONTAINERS. DO NOT RESEAL CONTAINERS IF
CONTAMINATION IS SUSPEC TED.

Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR WITH ORGANIC
VAPOR CARTRIDGE.
Ventilation:USE ADEQUATE MECHANICAL VENTILATION.
Protective Gloves:NITRILE
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. CLOTHING
TO PREVENT PROLONGED OR REPEATED CONTACT.
Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CLOTHING/CLEAN FOOTWEAR BEFORE REUSE.
Supplemental Safety and Health
DO NOT EAT, DRINK, OR SMOKE IN WORK AREA. EXPOSURE TO VAPORS OR HOT
MATERIAL CAN BE EXTREMELY DANGEROUS.

HCC:V4
Boiling Pt:B.P. Text:480F,249C
Vapor Pres:0.01
Vapor Density:6.0
Spec Gravity:1.2
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1)
Solubility in Water:APPRECIABLE
Appearance and Odor:LIGHT YELLOW, MEDIUM VISCOSITY LIQUID WITH A STRONG
PUNGENT ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG ALKALIS, TERTIARY AMINES, WATER
Stability Condition to Avoid:TEMPERATURES ABOVE 40F FOR EXTENDED
PERIODS OF TIME. SOURCES OF IGNITION.
Hazardous Decomposition Products:ISOCYANATES, HYDROGEN CYANIDE, OXIDES
OF CARBON AND NITROGEN.
Conditions to Avoid Polymerization:WATER AND OTHER PRODUCTS WHICH REACT
WITH ISOCYANATES.

Waste Disposal Methods:CONTACT LOCAL ENVIRONMENTAL MANAGER. DISPOSE OF
IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.