Product ID:EPA VOLATILE ORGANIC COMPOUNDS MIX 4, 48804
MSDS Date:10/05/1993
FSC:6850
NIIN:00N017783
MSDS Number: BMDYZ

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

METHANE, TRIBROMO-; (BROMOFORM) (SARA 313) (CERCLA).

CAS: 75-25-2

RTECS: PB5600000

Fraction By Weight: 0.2%

OSHA PEL S, 0.5 PPM

ACGIH TLV: S, 0.5 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYLENE, TETRACHLORO-; (TETRACHLOROETHYLENE) (SARA 313)

CAS: 127-18-4

RTECS: KX3850000

Fraction By Weight: 0.2%

OSHA PEL 100 PPM, Z-2

ACGIH TLV: 25 PPM/100 STEL, A3

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHANE, BROMOCHLORO-; (CHLOROBROMOMETHANE) (CERCLA).

CAS: 74-97-5

RTECS: PA5250000

Fraction By Weight: 0.2%

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM

METHANE, DIBROMO-; (DIBROMOMETHANE) (SARA 313)

CAS: 74-95-3

RTECS: PA7350000

Fraction By Weight: 0.2%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

2,2-DICHLOROPROPANE

CAS: 594-20-7

Fraction By Weight: 0.2%

OSHA PEL N/K

ACGIH TLV: N/K

METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA).

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 98.2%

OSHA PEL S, 200 PPM

ACGIH TLV: S,200 PPM/250 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

CARBON TETRACHLORIDE (SARA 313) (CERCLA).

CAS: 56-23-5

RTECS: FG4900000

Fraction By Weight: 0.2%

OSHA PEL 10 PPM Z-2

ACGIH TLV: S,5PPM/10 STEL,A3

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

(ORAL,RAT)800MG/KG

CAS: 67-66-3

RTECS: FS9100000

Fraction By Weight: 0.2%

OSHA PEL C 50 PPM

ACGIH TLV: 10 PPM; A2

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ETHANE, 1,1-DICHLORO-; (1,1-DICHLOROETHANE) (SARA 313)

CAS: 75-34-3

RTECS: KI0175000

Fraction By Weight: 0.2%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHANE, 1,1,1-TRICHLORO-; (1,1,1-TRICHLOROETHANE) (SARA

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 0.2%

OSHA PEL 350 PPM

ACGIH TLV: 350 PPM/450 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRDCED SENSIT
OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE A SIMILAR
EFT IN HUMANS. ADRENOMIMETICS (E.G. EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT FOR LIFE-SUSTAIN ING USES IN HUMANS ACUTELY
OR CHRONICALLY EXPOSED TO CHLOROCARBONS . ACUTE:HARMUFL IF INHALED.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:TETRACHLOROETHYLENE:IARC MONO, SUPP, VOL
7, PG 355, 1987:GROUP 2B. NTP 7TH ANNUAL RPT ON CARCIN, 1994:ANTIC
TO (SUPDAT)
Effects of Overexposure:HLTH HAZ:MAY BE FATAL IF SWALLOWED. CONTAINS
MATERIAL(S) KNOWN TO ST OF CALIFORNIA TO CAUSE CANCER. HEADACHE,
NAUSEA, GASTROINTESTINAL DISTURBANCES. LIVER DAMAGE. KIDNEY DAMAGE.
BLINDNESS. CHRONIC:REP ORTED ANIMAL CARCINOGEN.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:FLUSH W/WATER FOR @ LEAST 15 MINS. CONT PHYS. SKIN:FLUSH
W/LG VOLUMES OF WATER. INHAL:IMMED MOVE TO FRESH AIR. GIVE OXYG IF
BRTHG IS LABORED. IF BRTHG STOPS, GIVE ARTF RESP. CONT PHYS.
INGEST:NEV ER GIVE ANYTHING BY MOUTH TO UNCON PERSON. NEVER TRY TO
MAKE UNCON PERSON VOMIT. GIVE 2 TABLESPOONS OF BAKING SODA IN GLASS
OF WATER. PRESS FINGERS TO BACK OF TONGUE TO INDUCE VOMIT. IMMED
(SUPDAT)

Flash Point:50.0F,10.0C
Lower Limits:6.0%
Upper Limits:36.5%
Extinguishing Media:CO*2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT APPLICABLE. THERMAL DECOMPOSITION
PRODUCTS MAY INCLUDE HCL & PHOSGENE .

Spill Release Procedures:TAKE UP W/ABSORBENT MATERIAL. VENTILATE AREA.
ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFRIGERATE IN SEALED CNTNR. KEEP AWAY
FROM OXIDIZERS. KEEP AWAY FROM IGNIT SOURCES. RPTD CANCER HAZ.
AVOID EYE/SKIN CONT. AVOID BREATHING VAPORS.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICINITY
OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV RADIA MAY
CAUSE FORMATION OF HCL &/OR PHOSGENE .

Respiratory Protection:WEAR NIOSH/MSHA APPRVD FACE MASK WITH ORGANIC
VAPOR CANISTER RESPIRATOR.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN:CARCIN. ANIMAL:LIVER TUMORS. FIRST AID PROC:CONT PHYS.
CARBON TETRACHLORIDE:IARC MONO, SUPP, VOL 7, PG 143, 1987:GROUP 2B.
NTP 7TH ANNUAL RPT ON CARCIN, 1994:ANTIC TO BE CARCIN. HUMAN
:LIVER, KIDNEYS, LUNG DMG. CHLOROFORM:IARC MONO, SUPP, VOL 7, PG
152, 1987:GROUP 2B. NTP 7TH ANNUAL RPT ON (ING 11)

Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:100
Vapor Density:1.10
Spec Gravity:0.790
Evaporation Rate & Reference:>1 (ETHER =1)
Solubility in Water:100
Appearance and Odor:CLEAR COLORLESS LIQUID

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS. CHROMIC ANHYDRIDE, LEAD PERCHLORATE, PERCHLORIC
ACIDS.
Hazardous Decomposition Products:HCL & PHOSGENE .

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE, OR
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.