Product ID:WATER STANDARD KIT-A PURGEABLE A, 48807
MSDS Date:02/01/1990
FSC:6850
NIIN:00N018228
Kit Part:Y
MSDS Number: BMDZN

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

ETHYLENE, 1,1-DICHLORO-; (1,1-DICHLOROETHYLENE).

CAS: 75-35-4

RTECS: KV9275000

Fraction By Weight: 0.02%

OSHA PEL 1 PPM

ACGIH TLV: 5 PPM; 20 PPM STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

PROPANE, 1,2-DICHLORO-; (1,2-DICHLOROPROPANE).

CAS: 78-87-5

RTECS: TX9625000

Fraction By Weight: 0.02%

OSHA PEL 75 PPM; 110 PPM STEL

ACGIH TLV: 75 PPM; 110 PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHANE, TRICHLOROFLUORO-; (TRICHLOROFLUOROMETHANE)

CAS: 75-69-4

RTECS: PB6125000

Fraction By Weight: 0.02%

OSHA PEL 1000 PPM

ACGIH TLV: C, 1000 PPM; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHANE, CHLORODIBROMO-; (METHANE, DIBROMOCHLORO-)

CAS: 124-48-1

RTECS: PA6360000

Fraction By Weight: 0.02%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYLENE, TETRACHLORO-; (TETRACHLOROETHYLENE).

CAS: 127-18-4

RTECS: KX3850000

Fraction By Weight: 0.02%

OSHA PEL 100 PPM

ACGIH TLV: 25PPM/100,A3 STEL;94

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ETHYLENE, TRICHLORO-; (ETHENE, TRICHLORO-).

CAS: 79-01-6

RTECS: KX4550000

Fraction By Weight: 0.02%

OSHA PEL 100 PPM/100 STEL

ACGIH TLV: 50 PPM/100,A5STEL;93

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

(ORAL,RAT)5628 MG/KG.

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99-100%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

(ORAL,RAT)2800 MG/KG.

CAS: 56-23-5

RTECS: FG4900000

Fraction By Weight: 0.02%

OSHA PEL 10 PPM

ACGIH TLV: S,5PPM/10 STEL,A3 93

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

(ORAL,RAT)800 MG/KG

CAS: 67-66-3

RTECS: FS9100000

Fraction By Weight: 0.02%

OSHA PEL (C) 50 PPM

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

METHANE, DICHLORO-; (METHYLENE CHLORIDE).

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 0.02%

OSHA PEL 500 PPM; 1000 PPM, C

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHER, 2-CHLOROETHYL VINYL; (ETHENE, (2-CHLOROETHOXY)-)

CAS: 110-75-8

RTECS: KN6300000

Fraction By Weight: 0.02%

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

(ORAL,RAT)2190

CAS: 108-90-7

RTECS: CZ0175000

Fraction By Weight: 0.02%

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

1,1-DICHLOROETHANE (SARA III)

CAS: 75-34-3

RTECS: KI0175000

Fraction By Weight: 0.02%

OSHA PEL 100 PPM; 9293

ACGIH TLV: 100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHANE, 1,1,2-TRICHLORO-; (1,1,2-TRICHLOROETHANE).

CAS: 79-00-5

RTECS: KJ3150000

Fraction By Weight: 0.02%

OSHA PEL 10 PPM, S

ACGIH TLV: 10 PPM, S

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATERIALS HAVE PRODUCED
SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS &
COULD HAVE A SIMILAR EFFECT IN HUMANS. ADRENOMIMETICS (E.G.,
EPINEPHRINE) MAY BE CONTRAINDICATED EX CEPT FOR LIFE-SUSTAINING
USES IN HUMANSACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS .
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:INGS 9/12/13/14:GROUP 2(NTP); INGS
2/12/13/14:GROUP 2B(IARC).
Effects of Overexposure:HLTH HAZ:HARMFUL IF INHALED. MAY BE FATAL IF
SWALLOWED. CONTAINS LOW CONCS OF MATLS KNOWN TO STATE OF CAL TO
CAUSE CANCER. SUCH CONCS SUBSTANTIALLY BELOW OSHA-HCS THRESHOLDS
WHICH WOULD REQ LISTING HE REIN AS COMPONENT OF MIXT. HEADACHE,
NAUSEA, GASTROINTESTINAL DISTURBANCES, BLINDNESS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE:FLUSH W/WATER FOR AT LEAST 15 MIN. CALL MD. SKIN:FLUSH
W/LG VOLS OF WATER. INHAL:IMMED MOVE TO FRESH AIR. IF BRTHG STOPS,
GIVE ARTF RESP. CALL MD. INGEST:NEVER GIVE ANYTHING BY MOUTH TO
UNCON PERS ON. NEVER TRY TO MAKE UNCON PERSON VOMIT. GIVE 2 TBLS OF
BAKING SODA IN GLASS OF WATER. PRESS FINGERS TO BACK OF TONGUE TO
INDUCE VOMITING. IMMED CALL MD.

Flash Point:N/A (SUPP DATA)
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE-DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL & PHOSGENE .

Spill Release Procedures:TAKE UP W/ABSORBENT MATERIAL. VENTILATE AREA.
ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN SEALED CONTAINER IN FREEZER.
KEEP AWAY FROM OXIDIZERS. KEEP AWAY FROM IGNITION SOURCES. AVOID
EYE/SKIN CONTACT. AVOID BREATHING VAPORS.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV
RADIATION MAY CAUSE THE FORMATION OF HCL &/OR PHOSGENE .

Respiratory Protection:WEAR NIOSH/MSHA APPROVED FACE MASK W/ORGANIC
VAPOR CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:RUBBER GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER. FLASH POINT:(UNTESTED MIXTURE PER BETH
MILLER, SUPELCO)

HCC:T4
Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:100
Vapor Density:1.10
Spec Gravity:0.790 G/ML
Evaporation Rate & Reference:>1 (ETHER = 1).
Solubility in Water:100%
Appearance and Odor:CLEAR, COLORLESS LIQUID.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE, PERCHLORIC
ACIDS.
Hazardous Decomposition Products:HCL, PHOSGENE .

Waste Disposal Methods:COMPLY W/ALL APPLICABLE FEDERAL, STATE, AND
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.