Product ID:ACETONE/BUTANOL
MSDS Date:12/01/1987
FSC:6810
NIIN:00N024659
MSDS Number: BMGFB

GAF CHEMICALS CORP

1361 ALPS RD
WAYNE, NJ 07470
US

Emergency Phone: 800-228-5635;800-424-9300(CHEMTREC)

Info Phone: 201-628-3000

Cage: 46575

GAF CORP

WAYNE, NJ 07470 US

Telephone: 201-628-3000

Cage: 24299

-95C. EVAP

CAS: 67-64-1

RTECS: AL3150000

OSHA PEL 1000PPM

ACGIH TLV: 750PPM/1000STEL;9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

BUTYL ALCOHOL; (1-BUTANOL)

CAS: 71-36-3

RTECS: EO1400000

OSHA PEL 100 PPM

ACGIH TLV: S, C 50 PPM; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

BENZENE

CAS: 71-43-2

RTECS: CY1400000

OSHA PEL 1 PPM; 5 PPM STEL

ACGIH TLV: 10 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

LD50 LC50 Mixture:LD50:(ORAL,RAT) 9750 MG/KG (FOR ACETONE)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INGEST: NO EFTS OF EXPOS EXPECTED.
INHAL: BRTHG HIGH VAP CONCS OR PRLNG EXPOS TO ACETONE VAPS CAN
CAUSE IRRIT OF EYES/NOSE/THROAT & MAY CAUSE HDACH/DIZZ/NAUS/UNCON.
ACETONE VAPS DEADEN SENSE OF SMELL AFTER SHORT TIME OF EXPOS.
SKIN: PRLNG/RPTD CONT OF LIQ ACETONE CAN CAUSE DRYNESS/IRRIT DUE TO
DEFAT ACTION.
Explanation of Carcinogenicity:BENZENE: GROUP 1 (NTP); GROUP 1
(IARC);OSHA REGULATED
Effects of Overexposure:EYES: VAPS SLIGHTLY UNCOMFORTABLE. SPLASHES
IRRITATING. WILL CAUSE PAINFUL BURNING/STINGING OF EYES/LIDS,
WATERING OF EYES/INFLAMMATION OF CONJUNCTIVA.
Medical Cond Aggravated by Exposure:NO DATA FOUND.

First Aid:INGEST: INDUCE VOMIT IMMED BY GIVING 2 GLASSES OF H2O &
STICKING FINGER DOWN THROAT. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCON PERSON. CALL MD. INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG,
GIVE ARTF RESP, PREFERABLY MOUTH-TO-MOUTH. IF BRTHG ISDFCLT, GIVE
O2. CALL MD. SKIN: FLUSH W/WATER. EYES: IMMED FLUSH W/PLENTY OF H2O
FOR AT LEAST 15 MIN. CALL MD.

Flash Point:SEE ING 1
Lower Limits:SEE ING 1
Upper Limits:SEE ING 1
Extinguishing Media:H2O SPRAY/ALCOHOL FOAM/DRY CHEM/CO2. H2O MAY BE
INEFTIVE BUT SHLD BE USED TO KEEP FIRE-EXPOS CONTRS COOL. (SUPP
DATA)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DANGEROUS FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME OR OXIDIZERS. MODERATE EXPLOSION HAZARD WHEN VAPOR IS
EXPOSED TO FLAME.

Spill Release Procedures:IMMED ELIM SOURCES OF IGNIT. EVACUATE AREA.
WEAR APPROP PROT CLTHG/RESP EQUIP. SHUT OFF LEAK IF POSS. VENT
AREA. DIKE/ PUMP OFF LGE SPILLS INTO STOR/SALVAGE CONTRS. ABSORB
SML SPILLS W/INERT ABSORB MA TL & DISPOSE. FLUSH SPILL AREA
W/WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID CONT W/EYES & SKIN. WASH THORO
AFTER HNDLG. AVOID BRTHG VAP. USE W/ADEQ VENT. CAUTION! THIS PROD
CONTAINS RESIDUAL BENZENE. PRLNG (SUPP DATA)
Other Precautions:DURING EQUIP REPAIR/MAINT: WASH EQUIP THORO W/STEAM/
WARM WATER UNTIL CLEAN. CHECK FOR FLAMM W/AN "EXPLOSION METER".
ALSO CHECK O2 LEVEL W/AN OXYGEN METER. IN ALL CASES, FOLLOW GOOD
INDUSTRIAL SAFETY PRAC BEFORE ENTERING EQUIP.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR WHERE TLV OR PEL
MAY BE EXCEEDED.
Ventilation:USE WITH ADEQUATE VENTILATION.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES.
Other Protective Equipment:RUBBER APRON, LONG-SLEEVED SHIRT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXTING MEDIA: ALCOHOL FOAM IS RECOMMENDED. HNDLG/STOR PREC:
OVEREXPOSURE MAY CREATE CANCER RISK. KEEP THIS CONTR & VAPORS FROM
THE CONTR AWAY FROM HEAT, SPARKS, AND FLAME. KEEP CONTAINER CLOSED.

HCC:F2
Boiling Pt:B.P. Text:SEE ING 1
Melt/Freeze Pt:M.P/F.P Text:SEE ING 1
Vapor Pres:SEE ING 1
Vapor Density:SEE ING 1
Evaporation Rate & Reference:SEE ING 1
Solubility in Water:SOLUBLE
Appearance and Odor:LIQUID.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:CARBON MONOXIDE CAN FORM UPON
INCOMPLETE COMBUSTION.

Waste Disposal Methods:DISPOSE OF WITH LIQUID/SOLID WASTE ACCORDING TO
FEDERAL, STATE, AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.