Product ID:CARBON DISULFIDE, 9176
MSDS Date:09/08/1986
FSC:6810
NIIN:00N025152
MSDS Number: BMPFQ

J T BAKER INC

222 RED SCHOOL LANE
PHILLIPSBURG, NJ 08865-2219
US

Emergency Phone: 800-424-8802;800-424-9300(CHEMTREC)

Info Phone: 201-859-2151

Cage: DO803

MALLINCKRODT BAKER, INC.

PHILLIPSBURG, NJ 08865 US

Telephone: 800-582-2537

Cage: 70829

CARBON DISULFIDE

CAS: 75-15-0

RTECS: FF6650000

Fraction By Weight: 90-100%

OSHA PEL 20 PPM

ACGIH TLV: S, 10 PPM; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

FLUSH AREA W/WATER. J.T. BAKER SOLUSORB*R

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL OF VAPS MAY CAUSE HDACH,
NAUS, VOMIT, DIZZ, GI IRRIT, UNCON. CONTACT W/LIQ OR VAP MAY CAUSE
SEV IRRIT/ BURNS OF SKIN/EYES/MUC MEMB. BOTH LIQ & VAP ARE READILY
ABSORBED THRU SKIN. SKIN ABS ORPTION MAY CAUSE HDACH, NAUS, VOMIT,
DIZZ, GI IRRIT, DISTURB OF CARDIAC RHYTHM, UNCON. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: INGEST MAY CAUSE HDACH, NAUS, VOMIT,
DIZZ, GI IRRIT, CONVL, UNCON. ACUTE POISONING VIA ALL ROUTES OF
EXPOS MAY BE SEVERE ENOUGH TO BE FATAL. CHRONIC EFFECTS OF EXPOSURE
MAY INCLUDE SERIOUS D AMAGE TO CNS SYSTEM, IMPAIRED VISION,
LIVER/KIDNEY DAMAGE, ANEMIA, LUNG IRRITATION.
Medical Cond Aggravated by Exposure:NONE IDENTIFIED.

First Aid:CALL MD.--- INGEST: IF CONSCIOUS, IMMED INDUCE VOMIT. INHAL:
REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS
DFCLT, GIVE O2. EYES/SKIN: IMMED FLUSH W/PLENTY OF WATER FOR AT
LEAST 15 MIN WHILE REMOVING CONTAMD CLTHG/SHOES. WASH CLTHG BEFORE
RE-USE. ACCEPTABLE MAXIMUM PEAK ABOVE THE ACCEPTANCE CEILING
CONCENTRATION FOR AN EIGHT-HOUR SHIFT = 100 PPM FOR 30 MIN. (PEL)
CEILING - 30 PPM.

Flash Point Method:CC
Flash Point:-22F,-30C
Lower Limits:1%
Upper Limits:50%
Extinguishing Media:USE DRY CHEMICAL OR CARBON DIOXIDE. DO NOT USE
WATER.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA/FULL PROT EQUIP .
MOVE CONTRS FROM FIRE AREA IF IT CAN BE DONE W/O RISK. USE WATER TO
KEEP FIRE-EXPOS CONTRS COOL. (SUPP DATA)
Unusual Fire/Explosion Hazard:VAPORS MAY FLOW ALONG SURFACES TO DISTANT
IGNIT SOURCES/FLASH BACK. CLOSED CONTRS EXPOS TO HEAT MAY EXPLODE.
CONT W/ STRONG OXIDIZERS MAY CAUSE FIRE. (SUPP DATA

Spill Release Procedures:WEAR SCBA/FULL PROT CLTHG. SHUT OFF IGNITION
SOURCES; NO FLARES/SMKG/FLAMES IN AREA. STOP LEAK IF YOU CAN DO SO
W/O RISK. USE WATER SPRAY TO REDUCE VAPS. TAKE UP W/SAND OR OTHER
NON-COMBUST ABSORB MAT L/PLACE INTO CONTR FOR LATER DISPOSAL. (ING
2)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:BOND/GROUND CONTRS WHEN TRANSFERRING
LIQUID. KEEP CONTR TIGHTLY CLOSED. STORE IN A COOL, DRY,
WELL-VENTILATED, FLAMMABLE LIQUID STORAGE AREA.
Other Precautions:POISON! EXTREMELY FLAMM - HIGHLY VOLAT. CAUSES BURNS.
MAY BE FATAL IF SWALLOWED/INHAL. KEEP AWAY FROM STEAM PIPES/OTHER
HEAT SOURCES/SPARKS/FLAME. DO NOT GET IN EYES/SKIN/CLTHG. DO NOT
BREATHE VAP. US E W/ADEQ VENT. WASH THORO AFTER HNDLG.

Respiratory Protection:RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS UP TO 500 PPM,
NIOSH/MSHA APPRVD CHEM CARTRIDGE RESP W/ORGANIC VAP CARTRIDGE IS
RECOMMENDED. ABOVE THIS LEVEL, NIOSH/MSHA APPRVD SCBA IS
RECOMMENDED.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS.
Protective Gloves:POLYVINYL ALCOHOL GLOVES.
Eye Protection:CHEM WORK GOGG/FULL LENGTH FSHLD .
Other Protective Equipment:UNIFORM, PROTECTIVE SUIT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. WASH
CONTAMINATED CLOTHING BEFORE RE-USE.
Supplemental Safety and Health
FIRE FIGHT PROC: FLUSH AREA W/WATER UNTIL COOL SO REIGNITION WILL NOT
OCCUR. EXPLO HAZ: LOW AUTOIGNIT TEMP (212F) MAY CAUSE CARBON
DISULFIDE TO IGNITE UPON CONT W/HOT SURF SUCH AS LIGHT BULBS/ STEAM
P IPES/AUTO EXHST PIPES. TOXIC GASES PRODUCED: SULFUR DIOXIDE.
MATLS TO AVOID: METALS, CHLORINE, FLUORINE, HYPOCHLORITE.

HCC:F5
Boiling Pt:B.P. Text:115F,46C
Melt/Freeze Pt:M.P/F.P Text:-170F,-112C
Vapor Pres:300
Vapor Density:2.67
Spec Gravity:1.26
Evaporation Rate & Reference:22.6 (BUTYL ACETATE = 1)
Solubility in Water:SLIGHT (0.1 TO 1%)
Appearance and Odor:CLEAR, COLORLESS TO YELLOW LIQUID WITH AN
UNPLEASANT ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, AZIDES, ZINC, ALUMINUM, SODIUM, POTASSIUM,
AMINES, OXIDES OF NITROGEN, MOST COMMON (SUPP DATA)
Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION,
AIR, FRICTION, SHOCK, SUNLIGHT.
Hazardous Decomposition Products:OXIDES OF SULFUR.

Waste Disposal Methods:DISPOSE I/A/W ALL APPLICABLE FEDERAL, STATE, AND
LOCAL ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.