Product ID:PHENOL, CARBOLIC ACID
MSDS Date:10/01/1984
FSC:6505
NIIN:00-133-9920
MSDS Number: BMPXY

MALLINCKRODT INC

675 MCDONNELL BLVD
ST. LOUIS, MO 63134
US

Emergency Phone: 314-895-2000

Info Phone: 314-895-2000

Cage: 37940

MALLINCKRODT INC

5840 ST. LOUIS, MO 63134 US

Telephone: 314-539-1600

Cage: 37940

PHENOL (SARA III) (SARA III)

CAS: 108-95-2

RTECS: SJ3327000

Fraction By Weight: 100%

OSHA PEL 5 PPM;SKIN

ACGIH TLV: 5 PPM;SKIN; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD50 (ORAL RAT) IS 414 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALE-IRRITANT. INGEST-SEVERE
BURNS, SYSTEMIC POISONING. SKIN-SEVERE BURNS, SYSTEMIC POISONING AS
WITH INGESTION, ANESTHETIC EFFECT. EYE-SEVERE BURNS. CHRONIC:
INHALE-DIGESTIVE DISTURBANCES, N ERVOUS DISORDERS & SKIN ERUPTIONS.
SKIN-DERMATITIS.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:INHALE-MAY CAUSE SEVERE DAMAGE TO MUCOUS
MEMBRANES, POSSIBLE KIDNEY & LIVER EFFECTS, MAY BE FATAL.
INGEST-MUSCULAR WEAKNESSM TERMORS, CONVULSIONS, COLLAPSE,
UNCONSCIOUSNESS & DEATH. SKIN-NO PAIN WITH WHITENING OF SKIN,
ABSORPTION RAPID. EYEMAY CAUSE CORNEAL DAMAGE OR BLINDNESS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES-FLUSH WITH WATER FOR 15 MIN. WHILE HOLDING EYELIDS OPEN.
SKIN-FLUSH WITH WATER FOR 15 MIN. WHILE REMOVING SOILED CLOTHES.
INHALATION-APPLY ARTIFICIAL RESPIRATION IF NOT BREATHING. IF
BREATHING, G IVE OXYGEN WITH TRAINED PERSONNEL. INGESTION-DRINK
LARGE AMOUNTS OF WATER. INDUCE VOMITING. IN ALL CASES OBTAIN
MEDICAL ATTENTION.

Flash Point Method:TCC
Flash Point:174F,79C
Autoignition Temp:Autoignition Temp Text:1319F
Lower Limits:1.7
Upper Limits:8.6
Extinguishing Media:DRY CHEMICAL - ALCOHOL FOAM - CARBON DIOXIDE -
WATER SPRAY. AVOID SKIN CONTACT WITH PHENOLS.
Fire Fighting Procedures:FULL PROTECTIVE CLOTHING & SELF CONTAINED
BREATHING APPARATUS SHOULD BE WORN. COOL FIRE EXPOSED CONTAINERS
WITH WATER SPRAY. APPLY WATER GENTLY.
Unusual Fire/Explosion Hazard:YIELDS FLAMMABLE VAPORS WHEN HEATED WHICH
CAN FORM EXPLOSIVE MIXTURES WITH AIR.

Spill Release Procedures:ELIMINATE IGNITION SOURCES. VAPOR
CONCENTRATIONS MAY BE REDUCED BY COVERING WITH ALCOHOL TYPE FOAM.
CLEAN UP & DRAIN OR PUMP TO APPROPIATE STORAGE VESSEL FOR EPA
APPROVED DISPOSAL. IF SOLID, HANDLE AC CORDINGLY & STORE FOR EPA
APPROVED DISPOSAL.

Handling and Storage Precautions:STORE AWAY FROM IGNITION SOURCES.
AVOID PROLONGED OR REPEATED CONTACT.
Other Precautions:NONE

Respiratory Protection:USE CHEMICAL CARTRIDGE OR AIR SUPPLIED DEPENDING
ON CONCENTRATION. USE SCBA FOR EMERGENCY CONDITIONS.
Ventilation:LOCAL AND MECHANICAL(GENERAL) EXHAUST RECOMMENDED. USE LAB
HOODS INDOORS. WORK UP-WOND OUTDOORS. INSURE ADEQUATE VENT.
Protective Gloves:IMPERVIOUS GLOVES
Eye Protection:GOGGLES & FACE SHIELD
Other Protective Equipment:WEAR IMPERVIOUS CLOTHING TO PREVENT SKIN
CONTACT. HAVE EMERGENCY EYE WASH AND SAFETY SHOWER AVAILABLE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING, DRINKING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO
NOT BREATHE VAPORS OR MIST.

HCC:F8
Boiling Pt:B.P. Text:359F,182C
Melt/Freeze Pt:M.P/F.P Text:104F,40C
Vapor Pres:0.36 MMHG
Vapor Density:3.24
Spec Gravity:1.049
Evaporation Rate & Reference:<0.01
Solubility in Water:8.4 G/100G
Appearance and Odor:COLORLESS OR WHITE CRYSTALS, CHARACTERISTIC TARRY
ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, CALCIUM HYPOCHLORITE, ALUMINUM CHLORIDE,
NITROBENZENE, STRONG ALKALIES, STRONG MINERAL ACIDS.
Stability Condition to Avoid:OVERHEATING.
Hazardous Decomposition Products:COMPLETE COMBUSTION YIELDS CARBON
DIOXIDE & WATER VAPOR. INCOMPLETE COMBUSTION MAY YIELD CARBON
MONOXIDE.

Waste Disposal Methods:DISPOSAL MUST BE MADE IN ACCORDANCE WITH
APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.