Product ID:3689, SODIUM FLUORIDE
MSDS Date:10/15/1987
FSC:6810
NIIN:00N028514
MSDS Number: BMYBG

J T BAKER INC

222 RED SCHOOL LANE
PHILLIPSBURG, NJ 08865-2219
US

Emergency Phone: 908-859-2151;800-424-9300(CHEMTREC)

Info Phone: 800-582-2537

Cage: DO803

MALLINCKRODT BAKER, INC.

PHILLIPSBURG, NJ 08865 US

Telephone: 800-582-2537

Cage: 70829

SODIUM FLUORIDE (SARA III)

CAS: 7681-49-4

RTECS: WB0350000

Fraction By Weight: 99-100%

OSHA PEL 2.5 MG/M3 (F)

ACGIH TLV: 2.5 MG/M3 (F)

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD50:(ORAL RAT)64 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL & INGEST ARE HARMFUL & MAY BE
FATAL. INHAL MAY CAUSE NAUSEA, VOMIT, DIFF BRTHG. ACUTE:INHALATION
OF DUST MAY CAUSE SEVERE IRRITATION OF RESPIRATORY SYSTEM. CONTACT
WITH SKIN OR EYES MAY CAUSE SE VERE IRRITATION OR BURNS. INGESTION
MAYCAUSE HEADACHE, NAUSEA, VOMITING, GI IRRITATION, CONVULSIONS,
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:AND BURNS TO MOUTH, THROAT AND
STOMACH. CHRONIC:INCREASED BONE DENSITY, CALCIUM DEPOSITS IN
LIGAMENTS AND MOTTLED TOOTH ENAMEL.
Medical Cond Aggravated by Exposure:NONE IDENTIFIED.

First Aid:INGEST:IF CONSCIOUS, IMMED INDUCE VOMIT. INHAL:REMOVE TO
FRESH AIR. IF NOT BRTHG, GIVE ARTIF RESP. IF BRTHG IS DFCLT, GIVE
O2. SKIN:IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN WHILE
REMOVING CON TAM CLTHG & SHOES. WASH CLTHG BEFORE REUSE. EYES:IMMED
FLUSH W/WATER FOR AT LEAST 15 MIN. NOTE TO MD:URINARY FLUORIDE
EXCRETION LEV HAVE BEEN USEFUL IN EVALUATING INDUSTRIAL EXPOS TO
FLOURIDE DUST.

Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING
FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS EXPOSED TO HEAT MAY
EXPLODE. HYDROGEN FLUORIDE PRODUCED.

Spill Release Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE CLOTHING. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL
INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL
AREA WITH WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CONTR TIGHTLY CLSD. STORE IN
SECURE POISON AREA. DO NOT STORE IN GLASS. USE WITH ADEQUATE
VENTILATION.
Other Precautions:SODIUM FLUORIDE REACTS W/ACIDS TO FORM HYDROGEN
FLUORIDE, WHICH IS HIGHLY CORROSIVE & POISONOUS - KEEP AWAY FROM
STRONG ACIDS. POISON! CAUSES SEV IRRIT. MAY BE FATAL IF
INGEST/INHALED. DO NOT GET IN E YES, ON SKIN/CLTHG. STORE AWAY
(SUPDAT)

Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION EXCEEDS TLV, A
NIOSH/MSHA APPROVED DUST/MIST RESPIRATOR IS RECOMMENDED. IF
CONCENTRATION EXCEEDS CAPACITY OF RESP, A NIOSH/MSHA APPROVED SCBA
IS ADVISED.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:UNIFORM AND APRON ARE RECOMMENDED. VENT
HOOD. EMERGANCY EYE WASH AND DELUGE SHOWER .
Work Hygienic Practices:WASH CLOTHING BEFORE REUSE. WASH THOROUGHLY
AFTER HANDLING.
Supplemental Safety and Health
OTHER PREC:FROM FOOD STUFFS. DO NOT BREATHE DUST.

HCC:T4
Boiling Pt:B.P. Text:3099F,1704C
Melt/Freeze Pt:M.P/F.P Text:1819F,993C
Vapor Density:1.4
Spec Gravity:2.78 (H2O = 1)
Solubility in Water:APPRECIABLE (>10%)
Appearance and Odor:WHITE ODORLESS POWDER OR CRYSTAL.
Percent Volatiles by Volume:0

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, GLASS
Stability Condition to Avoid:HEAT
Hazardous Decomposition Products:HYDROGEN FLUORIDE

Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE LOCAL,
STATE AND FEDERAL ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.