Product ID:AVIATION GASOLINE, 100 LL
MSDS Date:12/02/1991
FSC:9130
NIIN:00-221-0678
MSDS Number: BMZRR

EXXON CHEMICAL CO DIV OF EXXON CHEMICAL AMERICAS

HOUSTON, TX 77001
US

Emergency Phone: 713-870-6000/MEDICAL 713-656-3424

Info Phone: 713-870-6000

Cage: 4H542

EXXONMOBIL CHEMICAL CO, DIV OF EXXON MOBILCORP.

3272 HOUSTON, TX 77253-3272 US

Telephone: 281-870-6000 / 800-726-2015

Cage: 72190

GASOLINE (WHICH MAY INCLUDE THE FOLLOWING INGREDIENTS)

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 100% %

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9192

HEXANE (N-HEXANE) (TYPICALLY 1 %)

CAS: 110-54-3

RTECS: MN9275000

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LEAD ALKYL ADDITIVE

OSHA PEL NOT ESTALISHED

ACGIH TLV: NOT ESTALBISHED

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III) (TYPICALLY 5 - 50%

CAS: 1330-20-7

RTECS: ZE2100000

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENE (SARA III) (MAXIMUM OF 4.9 %)

CAS: 71-43-2

RTECS: CY1400000

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

LD50 LC50 Mixture:ORAL RAT LD50 18,800 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:PRODUCT IS IRRITATING TO EYES, SKIN,
RESPIRATORY TRACT AND DEPRESSES THE CENTRAL NERVOUS SYSTEM. CHRONIC
OVER EXPOSURE MAY CAUSE LIVER, KIDNEY, OR CENTRAL NERVOUS SYSTEM
DAMAGE.
Explanation of Carcinogenicity:CONTAINS BENZENE, LISTED BY ALL THREE.
ALSO, AN API STUDY FOUND LIVER CANCER IN MICE EXPOSED TO GASOLINE
VAPORS.
Effects of Overexposure:EYE/SKIN CONTACT: TRANSITORY IRRITATION.
INHALED: RESPIRATORY IRRITATION, EUPHORIA, HEADACHE, DIZZINESS,
DROWINESS, FATIGUE TREMORS, CONVULSIONS, NAUSEA, VOMITING,
DIARRHEA, LOSS OF CONSCIOUSNESS, AND FINALLY DEATH. INGESTED: G/I
IRRITATION, PLUS SYMPTOMS SIMILAR TO THOSE UNDER "INHALATION".
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN CONDITIONS
OR IMPAIRED LIVER, KIDNEY FUNCTION MAY BE AGGRAVATED BY THIS
PRODUCT.

First Aid:EYES: FLUSH WITH WATER 15 MINUTES. SKIN: WASH WITH SOAP &
WATER. REMOVE CONTAMINATED CLOTHING. LAUNDER BEFORE REUSE. INHALED:
REMOVE TO FRESH AIR. RESUSCITATE OR GIVE OXYGEN AS NEEDED. GET
MEDICAL CAR E. INGESTED: GET IMMEDIATE MEDICAL ATTENTION. DO NOT
INDUCE VOMITING. IF VOMITING OCCURS, MINIMIZE ASPIRATION HAZARD BY
PLACING HEAD BELOW HIPS.

Flash Point Method:TCC
Flash Point:-49F,-45C
Lower Limits:1.4 %
Upper Limits:7.6 %
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM, WATER FOG.
WATER MAY BE INEFFECTIVE, AS PRODUCT WILL FLOAT AND MAY SPREAD
FIRE.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS IN
ENCLOSED AREAS. WATER SPRAY MY BE USED TO COOL FIRE EXPOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR, ACCUMULATING
IN LOW AREAS, TRAVELING ALONG GROUND AND MAY FLASH BACK FROM
DISTANT IGNITION SOURCE.

Spill Release Procedures:ELIMINATE IGNITION SOURCES. ISOLATE AREA. USE
PROTECTIVE EQUIPMENT AS NECESSARY. STOP LEAK AND CONTAIN SPILL.
DIKE AS NEEDED TO KEEP SPILL FROM DRAINS, WATER WAYS ETC. WATER FOG
MAY BE USED TO REDUCE VAPOR & PERSONAL HAZARD. REPORT SPILL PER
LAW.
Neutralizing Agent:NONE

Handling and Storage Precautions:STORE IN A COOL, DRY, ISOLATED, WELL
VENTILATED AREA. KEEP IGNITION SOURCES AWAY. GROUND CONTAINERS TO
PREVENT STATIC DISCHARGE DURING TRANSFERS.
Other Precautions:FIRE AND EXPLOSIVE ARE THE ACUTE HAZARDS OF THIS
PRODUCT. TAKE EXTRAORDINARY STEP TO PREVENT THEM.

Respiratory Protection:IF NEEDED, USE NIOSH/MSHA RESPIRATOR WITH
ORGANIC VAPOR CARTRIDGE OR PREFERRABLY, A POSITIVE PRESSURE AIR
SUPPLIED RESPIRATOR OR SELF CONTAINED BREATHING APPARATUS.
Ventilation:USE EXPLOSION PROOF VENTILATION EQUIPMENT TO MAINTAIN
EXPOSURE BELOW PEL/TLV.
Protective Gloves:IMPERVIOUS RUBBER OR POLYMER,
Eye Protection:SAFETY GLASSES, OR SPLASH GOGGLES.
Other Protective Equipment:SAFETY SHOWER/EYE WASH. WASH CLOTHING AS
NEEDED TO PROTECT FROM PROLONGED/REPEATED CONTACT.
Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID
UNNECESSARY CONTACT. MINIMIZE ALL CONTACT.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

HCC:F2
Boiling Pt:B.P. Text:70-170C
Melt/Freeze Pt:M.P/F.P Text:-72F,-58C
Vapor Pres:5.5 - 7.0
Vapor Density:4
Spec Gravity:0.71
pH:7
Evaporation Rate & Reference:10-11 (BUTYL ACETATE = 1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, BLUE LIQUID; GASOLINE ODOR.
Percent Volatiles by Volume:100 %

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:HEAT, SPARKS AND OTHER IGNITION SOURCES,
VAPOR ACCUMULATIONS.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE

Waste Disposal Methods:DISPOSE I/A/W FEDERAL, STATE, LOCAL REGULATIONS.
PRODUCT QUALIFYS AS IGNITABLE WASTE AND CANNOT BE LANDFILLED. IF
RECOVERY OR RECYCLE ARE UNACCEPTABLE, INCINERATION MAY BE
ACCEPTABLE DISPOSAL METHOD.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.