Product ID:SUPELPREME-HC KIT PAH MIX, 48909
MSDS Date:05/13/1988
FSC:6850
NIIN:00N018231
Kit Part:Y
MSDS Number: BNCQM

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

METHANE, DICHLORO-; (METHYLENE CHLORIDE).

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 48%

OSHA PEL 500 PPM; 1000, C

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ANTHRACENE

CAS: 120-12-7

RTECS: CA9350000

Fraction By Weight: 0.2%

OSHA PEL 0.2 MG/M3

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ORAL(RAT)2000 MG/KG.

CAS: 206-44-0

RTECS: LL4025000

Fraction By Weight: 0.2%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ORAL(RAT)1780 MG/KG.

CAS: 91-20-3

RTECS: QJ0525000

Fraction By Weight: 0.2%

OSHA PEL 10 PPM;15 PPM STEL

ACGIH TLV: 10 PPM;15 PPM STEL

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ACENAPHTHYLENE

CAS: 83-32-9

RTECS: AB1000000

Fraction By Weight: 0.2%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BENZ(A)ANTHRACENE

CAS: 56-55-3

RTECS: CV9275000

Fraction By Weight: 0.2%

ACGIH TLV: A2 ; 9394

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

BENZO(A)PYRENE

CAS: 50-32-8

RTECS: DJ3675000

Fraction By Weight: 0.2%

OSHA PEL 0.2 MG/M3

ACGIH TLV: A2, MG/M3;9394

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

BENZO[B]FLUORANTHANE (SARA III)

CAS: 205-99-2

RTECS: CU1400000

OSHA PEL A2; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

BENZO(K)FLUORANTHENE

CAS: 207-08-9

RTECS: DF6350000

Fraction By Weight: 0.2%

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

CHRYSENE

CAS: 218-01-9

RTECS: GC0700000

Fraction By Weight: 0.2%

OSHA PEL 0.2 PPM

ACGIH TLV: A2 9394

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ACENAPHTHYLENE

CAS: 208-96-8

RTECS: AB1254000

Fraction By Weight: 0.2%

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PYRENE

CAS: 129-00-0

RTECS: UR2450000

Fraction By Weight: 0.2%

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

BENZO(GHI)PERYLENE

CAS: 191-24-2

RTECS: DI6200500

Fraction By Weight: 0.2%

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

FLUORENE; (9H-FLUORENE)

CAS: 86-73-7

RTECS: LL5670000

Fraction By Weight: 0.2%

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PHENANTHRENE

CAS: 85-01-8

RTECS: SF7175000

Fraction By Weight: 0.2%

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

(A,H)ANTHRACENE; (DIBENZO(A,H)ANTHRACENE)

CAS: 53-70-3

RTECS: HN2625000

Fraction By Weight: 0.2%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

INDENO(1,2,3-CD)PYRENE

CAS: 193-39-5

RTECS: NK9300000

Fraction By Weight: 0.2%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ORAL(RAT)4894 MG/KG.

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 48%

OSHA PEL 1PPM;5PPM STEL

ACGIH TLV: 10 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:IRRITATES/EYES/SKIN/NOSE/THROAT.
HDCH/NAUS. SEVERAL CHRONIC INHAL STUDIES RPTD BY NIOSH REVEALED
THAT TEST ANIMALS EXPOSED TO METHYLENE CHLORIDE CONC AS HIGH
10,000PPM SHOWED SLIGHT LIVER/ KIDNEY CHAN GES. CHLOROCARBON MATLS
HAVE PRDCD SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS &
COULD HAVE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:ING 5:IARC 2A, NTP2. ING 6:IARC 2A NTP2.
ING 7:IARC 2B, NTP 2. ING 8:IARC 2B, NTP. ING 9:ACGIH GRP A2. (SUPP
DATA)
Effects of Overexposure:HLTH HAZ:SIMILAR EFFECT IN HUMANS.
ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT
FOR LIFE- SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED
CHLOROCARBONS .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:CONT PHYS. SKIN: PROMPTLY WASH W/MILD SOAP & LG VOL OF
H2O. CONT PHYS. INHAL:IMMED MOVE TO FRESH AIR. GIVE O2 IF BRTHG IS
LABORED. IF BRTHG STOPS, GIVE ARTF RESP. CONT PHYS. INGEST: NEVER
GIVE AN YTING BY MOUTH TO AN UNCON PERSON. NEVER TRY TO MAKE AN
UNCON PERSON VOMIT. DO NOT INDUCE VOMIT. IMMED CONT PHYS.

Flash Point:12F,-11C
Lower Limits:1.3%
Upper Limits:7.1%
Extinguishing Media:CO2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT WHEN FIGHTING A CHEMICAL FIRE.
Unusual Fire/Explosion Hazard:THE FOLLOWING TOXIC VAPORS ARE FORMED
WHEN THIS MATERIAL IS HEATED TO DECOMPOSITION: HCL. PHOSGENE .

Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:OSHA-REGULATED CARCINOGEN. SEE CFR
TITLE 29 PART 1910. REFRIGERATE IN SEALED CONTAINER. KEEP AWAY FROM
OXIDIZERS. KEEP AWAY FROM BASES.
Other Precautions:RPTD CANCER HAZARD. AVOID EYE & SKIN CONT. AVOID
BRTHG VAP. NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE FO RMATION OF HCL &/OR PHOSGENE .

Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATORY PROTECTION.
Ventilation:USE ONLY IN EXHAUST HOOD.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEMIAL WORKERS GOGGLES .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN:ING 15:IARC 2A, NTP. ING 16:IARC 2B, NTP. ING 17:IARC
1, NTP 1, ACGIH A2, OSHA REGS. ING 18:IARC GRP 2B, NTP GRP 2, ACGIH
GRP A2.

HCC:F5
Boiling Pt:B.P. Text:104F,40C
Vapor Pres:350MM
Solubility in Water:1.3
Appearance and Odor:CLEAR LIQUID WITH CHLOROFORM-LIKE ODOR.
Percent Volatiles by Volume:97

Stability Indicator/Materials to Avoid:YES
STRONG BASES, OXIDIZING AGENTS. CHEMICAL ACTIVE METALS SUCH AS ALUMINUM
OR MAGNESIUM POWDERS.
Hazardous Decomposition Products:HCL. PHOSGENE .

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE, OR
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.