Product ID:208-10, ALKYD EGGSHELL ENAMEL WHITE & PASTE
MSDS Date:03/20/1992
FSC:8010
NIIN:00N027782
MSDS Number: BNCZD

O BRIEN CORP

450 EAST GRAND AVE
SOUTH SAN FRANCISCO, CA 94080
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 415-761-2300

Cage: 30806

O BRIEN CORPORATION

SOUTH SAN FRANCISCO, CA 94080-6207 US

Cage: 72556

CAN CAUSE

RTECS: 9999999ZZ

PRLNGD/RPTD CONTACT MAY RESULT IN DERM.

RTECS: 9999999ZZ

LIVER & LUNG DMG.

RTECS: 9999999ZZ

WIPE OFF WITH A RAG

RTECS: 9999999ZZ

CAREFULLY FOLLOW RESPIRATOR MFR'S RECOMMENDATIONS

RTECS: 9999999ZZ

FOR BAKING FINISHES, VENT VAPORS EMITTED ON HEATING.

RTECS: 9999999ZZ

ANESTHETIC. IRRIT OF RESP TRACT & ACUTE

RTECS: 9999999ZZ

5.00

CAS: 64742-88-7

Fraction By Weight: 25%

OSHA PEL 100 PPM (MFR)

ACGIH TLV: 100 PPM (MFR)

1.00

CAS: 64742-88-7

Fraction By Weight: 5%

OSHA PEL 200 PPM (MFR)

SILICA, CRYSTALLINE - CRISTOBALITE

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: <5%

OSHA PEL SEE TABLE Z3

ACGIH TLV: 0.05 MG/M3 RDUST9293

15300 MG/KG

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: <1%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM; 9293

9500

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 15%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

1)

CAS: 1302-76-7

RTECS: BD1450000

Fraction By Weight: 10%

OSHA PEL 15 MG/M3 (MFR)

ACGIH TLV: 10 MG/M3 (MFR)

6450 MG/KG

CAS: 1317-65-3

RTECS: EV9580000

Fraction By Weight: 15%

OSHA PEL 15 MG/M3 TDUST;5RESP

ACGIH TLV: 10 MG/M3 TDUST

REPORTS HAVE ASSOC RPTD/PRLNGD OCCUP

RTECS: 9999999ZZ

LAB STUDIES SHOW INHAL EXPOS TO HIGH LEV (250 MG/KG)

RTECS: 9999999ZZ

RESPONSE OCCUR AT LOWER EXPOS LEV & MAY BE DUE TO

RTECS: 9999999ZZ

REPORTS HAVE ASSOC PRLNGD/RPTD

RTECS: 9999999ZZ

MISUSE BY DELIBERATLEY CONC & INHAL CONTENTS MAY BE

RTECS: 9999999ZZ

SHOWN TO CAUSE DMG TO KIDNEYS/LIVER/BLOOD

RTECS: 9999999ZZ

(SPLEEN)/PERIPHERAL NERVOUS SYS.

RTECS: 9999999ZZ

DEPRESS. SYMPT MAY INCLUDE

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:ING 1:INGEST:ASPIR OF MATL INTO
LUNGS DUE TO VOMIT CAN CAUSE CHEM PNEUM WHICH CAN BE FATAL. ING
2:FATAL DOSE VIA INGEST FOR HUMANS IS EST AT 3-4 OZ. ASPIR INTO
LUNGS CAN CAUSE EDEMA; 1 OZ ASPIR CAN BE FATAL. INHAL CAUSES CNS
DEPRESS & IRRIT MUCOUS MEMBRANES. IRRIT TO EYES. PRLNGD/RPTD
CONTACT (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CRYSTALLINE SILICA CRISTOBALITE:IARC
GROUP 2A, NTP ANTICIPATED TO BE A CARCINOGEN.
Effects of Overexposure:HLTH HAZ:WILL CAUSE DEFATTING & DERM. ING 3:
HUMAN SYSTEMIC EFTS BY INHAL. MAY CAUSE EYE IRRIT. ING 4:IF INGEST
MAY CAUSE DIGEST TRACT IRRIT. ASPIR HAZ. INHAL MAY IRRIT
NOSE/THROAT/RESP TRACT, MAY CAU SE CNS DEPRESS. IRRIT TO EYES.
PRLNGD/RPTD CONTACT MAY CAUSE SKIN IRRIT. ING 5:INGEST:LOW ORAL
TOX. INHAL:IRRIT (SUPDAT)
Medical Cond Aggravated by Exposure:O'BRIEN KNOWS OF NONE LISTED IN
LITERATURE. PREPLACEMENT AND PERIODIC EXAMS SHOULD BE GIVEN TO
THOSE EXPOSED REGULARLY.

First Aid:INGEST:DRINK 1-2 GLASSES OF WATER TO DILUTE. KEEP WARM, QUIET
& GET MD ATTN IMMED. DECISION TO INDUCE VOMIT MUST BE BASED ON
ADVISE OF MD/POIS CTL CTR. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONC PERSON . INHAL:REMOVE FROM AREA TO FRESH AIR. RESTORE BRTHG.
CONSULT MD. EYE:IMMED BEGIN FLUSHING W/COOL, WATER, OCCAS LIFTING
LIDS TO ENSURE THOROUGH RINSING. CONTINUE FOR 15 MIN. WHILE FLUSH
EYES (ING 20)

Flash Point:105F,41C
Lower Limits:0.90%
Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
H2O MAY BE USED TO COOL CLSD CONTR TO PREV PRESS BUILD-UP/POSS
AUTOIGNIT/EXPLOS WHEN EXPOS TO EXTREME HEAT
Unusual Fire/Explosion Hazard:KEEP CONTR TIGHTLY CLSD. ISOLATE FROM
HEAT/ SPARKS/FLAME/ELECT EQUIP. CLSD CONTR MAY EXPLODE WHEN EXPOS
TO EXTREME HEAT. APPLICATION TO HOT SURF REQ (SUPDAT)

Spill Release Procedures:REMOVE SOURCES OF IGNITION. SOAK UP AND REMOVE
WITH INERT ABSORBENT MATERIAL WITH NON-SPARKING TOOLS. PROVIDE
ADEQUATE VENTILATION. USE NIOSH/MSHA APPROVED VAPOR RESPIRATOR.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE UPRIGHT IN SEALED CONTAINERS AND
USE AWAY FROM HIGH TEMPERATURE, SPARKS AND FLAME. AVOID PROLONGED
CONTACT WITH SKIN.
Other Precautions:DO NOT INGEST. KEEP CONTAINER TIGHTLY SEALED WHEN NOT
IN USE. KEEP OUT OF REACH OF CHILDREN.

Respiratory Protection:USE NIOSH/MSHA APPRVD PROP FITTED MECH RESP/MASK
TO AVOID BRTHG VAP/SPRAY MIST DURING
MIXING/SPRAYING/APPLICATION/CURING. USE NIOSH/MSHA APPRVD TC 19C
PROPERLY FITTED POS AIRSUPPLIED RESP IN CONFINED AREAS/WHEN
OVERSPRAY IS PRESENT.(ING 21)
Ventilation:PROVIDE SUFF VENT IN VOL/PAT TO KEEP AIR CONTAM CONC BELOW
APPLIC OSHA PERMISSIBLE EXPOS LEV/ACGIH'S TLV LIM. (ING 22)
Protective Gloves:SYNTHETIC RUBBER GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:PROTECTIVE OVERALLS RECOMMENDED.
Work Hygienic Practices:REMOVE AND WASH CONTAMINATED CLOTHING. DISCARD
CONTAMINATED SHOES.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:TINT BASE. EXPLOS HAZ:SPECIAL PRECAUTIONS.
DURING EMERG CONDTNS, OVEREXPOS TO DECOMP PROD MAY CAUSE HLTH HAZ.
OBTAIN MD ATTN. EFTS OF OVEREXPOS:TO UPPER RESP TRACT. EYE: IRRIT .
ING 6:IRRIT TO EYES & UPPER RESP TRACT. ING 7:IRRIT TO EYES AND
SKIN. CHRONIC:ING 3:POSS RESP & LIVER DMG COULD (ING 8

HCC:F4
Boiling Pt:B.P. Text:>149F,>65C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:1.28
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:51.73

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ACIDS, BASES.
Stability Condition to Avoid:HIGH TEMPERATURES.
Hazardous Decomposition Products:MAY PRODUCE FUMES WHEN HEATED TO
DECOMPOSITION. FUMES MAY CONTAIN CO, CO2 AND NO2.

Waste Disposal Methods:DISPOSE IN SEALED METAL CONTAINER AWAY FROM HEAT
AND FLAME IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
DO NOT INCINERATE CLOSED CONTAINERS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.