Product ID:32401, ALLYL CHLORIDE
MSDS Date:01/10/1991
FSC:6850
NIIN:00N017195
MSDS Number: BNMTQ

SHELL OIL CO

HOUSTON, TX 77210
US

Emergency Phone: 713-473-9461;800-424-9300(CHEMTREC)

Info Phone: 713-241-4819

Preparer: J. C. WILLET

Cage: SHELO

SHELL OIL COMPANY

4320 HOUSTON, TX 77210 US

Telephone: 800-231-6950

Cage: 54527

PLACE IN NON-LEAKING CNTNRS FOR PROPER DISP. FLUSH

RTECS: 9999999ZZ

TAKE UP W/ABSORB MATL &

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DISTANT FROM HANDLING SITE. FLASH-FIRE CAN RSLT.

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VENT. CNTNRS, EVEN THOSE THAT HAVE BEEN EMPTIED, CAN

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PERFORM SIMILAR OPER ON/NEAR CNTNRS. STATIC ELEC

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BOND & GROUND TRANSFER CNTNRS & EQUIP. ALLYL

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HYDROLYSIS IN H*2O TO FORM ALLYL ALCOHOL & HCL.WASH

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TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHING

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PROPENE, 3-CHLORO-; (ALLYL CHLORIDE) (SARA III)

CAS: 107-05-1

RTECS: UC7350000

Fraction By Weight: 100%

OSHA PEL 1 PPM/2 STEL

ACGIH TLV: 1 PPM/2 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BY MUSCULAR WEAKNESS AND LOSS OF SENSATION IN

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LUNG ALLERGIES MAY INCREASE CHANCE OF

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REMOVE VICTIM TO

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DO NOT GIVE LIQ

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THAN 2 GLASSES OF H*2O & INDUCE VOMIT BY GIVING 30CC

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GIVE 2 GLASSES OF H*2O & INDUCE VOMIT BY TOUCHING

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BELOW HIPS WHILE VOMIT. GET MED ATTN. NOTE TO PHYS

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& 15CC (1 TABLESPOON) SYRUP OF IPECAC. IF SYMP SUCH

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EMESIS, GASTRIC LAVAGE SHOULD BE CONSIDERED

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CONTAIN. H*2O FOG MAY BE USEFUL IF SUPPRESSING

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PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE

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LD50 LC50 Mixture:LD50: (ORAL,RAT) 0.7 G/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: SEV IRRIT. SKIN: SEV IRRIT. MAY
CAUSE SKIN SENSIT. SKIN ABSORP LEADS TO DEEP SEATED PAIN IN AREA
SOMETIMES DESCRIBED AS "DEEP BONE" ACHE. INHAL: MAY CAUSE SEV IRRIT
TO NOSE, THROAT & RESP TRACT. PROD IS MOD TOX & MAY BE HARMFUL IF
INHALED; MAY PRDC LIVER, KIDNEY, LUNG, & PERIPHERAL NERV DMG. HIGH
CONC (SUPP DATA)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:EARLY TO MOD CNS DEPRESS MAY BE EVIDENCED BY
GIDDINESS, HDCH, DIZZ & NAUS; IN EXTREME CASES, UNCON/DEATH MAY
OCCUR. KIDNEY DMG MAY BE EVIDENCED BY CHANGES IN URINE OUTPUT,
URINE APPEARANCE/EDEMA (SWEL LING FROM FLUID RETENTION). LUNG DMG
(SCARRING, BRONCH, EMPHYSEMA MAY BE EVIDENCED BY SHORT OF BRTH,
ESPEC ON(SUPP DATA)
Medical Cond Aggravated by Exposure:PREEXISTING SKIN, EYE & RESP
DISORDERS MAY BE AGGRAVATED BY EXPOS TO PROD. IMPAIRED LIVER,KIDNEY
& LUNG FUNC FROM PREEXISTING DISORDERS MAY BE AGGRAVATED BY EXPOS
TO PROD. PREEXISTING SKIN/ (ING 3)

First Aid:EYE:IMMED FLUSH EYES W/PLENTY OF H*2O FOR AT LEAST 15 MIN
WHILE HOLDING EYELIDS OPEN.GET MED ATTN. SKIN: IMMED REMOVE CONTAM
CLTHG/SHOES. WIPE EXCESS FROM SKIN & FLUSH W/PLENTY OF H*2O FOR AT
LEAST 15 MIN.USE SOAP IF AVAIL/FOLLOW BY WASHING W/SOAP & H*2O.DO
NOT REUSE CLTHG UNTIL THORO CLEANED. GET MED ATTN. CONTAM LEATHER
ARTICLES, INCLUDING SHOES, CANNOT BE DECONTAM & SHOULD BE DESTROYED
(ING 4)

Flash Point Method:TCC
Flash Point:-25F,-32C
Lower Limits:3.2%
Upper Limits:11.2%
Extinguishing Media:WATER FOG, FOAM, DRY CHEM/CO*2. DO NOT USE DIRECT
STREAM OF WATER. PROD WILL FLOAT & CAN BE REIGNITED ON SURF OF
H*2O.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD POS PRESS SCBA & FULL
PROT EQUIP.DANGER. EXTREM FLAM. CLEAR FIRE AREA OF UNPROT PERS &
ISOLATE. COOL FIRE EXPOSED CNTNRS W/H*2O.
Unusual Fire/Explosion Hazard:HANDLE AS EXTREM FLAM LIQ. VAPS CAN FORM
FLAM MIX AT ORDINARY TEMPS. ALLYL CHLORIDE PRODUCES TOX HYDROGEN
CHLORIDE &/OR PHOSGENE & CO ON COMBUST. (SUPP DATA)

Spill Release Procedures:ELIMINATE ALL IGNIT SOURCES. HANDLING EQUIP
MUST BE GROUNDED TO PVNT SPARKING. LRG SPILLS: ISOLATE HAZ AREA &
DENY ENTRY TO UNNEC PERS. WEAR APPROP NIOSH/MSHA APPRVD RESP & PROT
CLTHG. SHUT OFF SOURCE OF LEAK ONLY IF SAFE TO DO SO. DIKE & (ING
11)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL, DRY PLACE WITH ADEQUATE
VENTILATION. KEEP LIQUID AND VAPOR AWAY FROM HEAT, SPARKS AND
FLAME.
Other Precautions:SURFS THAT ARE SUFF HOT MAY IGNITE EVEN LIQ PROD IN
ABSENCE OF SPARKS/FLAME. EXTING PILOT LIGHTS, CIGARETTES & TURN OFF
OTHER SOURCES OF IGNIT PRIOR TO USE & UNTIL ALL VAPS ARE GONE. VAPS
MAY ACCUMULA TE & TRAVEL TO IGNIT SOURCES (ING 15)

Respiratory Protection:USE NIOSH/MSHA APPROVED RESP TO PVNT
OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134 USE EITHER NIOSH/MSHA
APPROVED FULL-FACE, ATMOSPHERE-SUPPLYING RESPIRATOR OR
AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPO RS.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD
BE AVAILABLE FOR EMERGENCY USE.
Work Hygienic Practices:AVOID CONTACT WITH EYES. AVOID CONTACT WITH
SKIN AND CLOTHING.
Supplemental Safety and Health
EXPLO HAZ: VAPS ARE DENSER THAN AIR & CAN TRAVEL CONSIDERABLE DISTANCES
ALONG GROUND TO IGNIT SOURCE. HLTH HAZ: MAY PRDC CNS DEPRESS.
INGEST: HIGHLY TOX & MAY BE FATAL IF SWALLOWED. MAY PRDC LIVER & K
IDNEY DMG. SIGNS & SYMP: EXERTION, & MAY BE ACCOMPANIED BY CHRONIC
COUGH. PERIPHERAL NERV DMG MAY BE EVIDENCED (ING 2)

Boiling Pt:B.P. Text:113F,45C
Vapor Pres:294 @ 68F
Vapor Density:2.6
Spec Gravity:0.93 (H*2O=1)
Evaporation Rate & Reference:7 (N-BUTYL ACETATE=1)
Solubility in Water:0.36%
Appearance and Odor:COLORLESS TO YELLOW, MOBILE LIQUID, PUNGENT
IRRITATING ODOR.

Stability Indicator/Materials to Avoid:YES
CONTACT WITH CAUSTICS, AMINES, AMMONIA, FERRIC CHLORIDE, MAGNESIUM,
ALUMINUM, STRONG ACIDS & GALVANIZED STEEL.
Stability Condition to Avoid:HEAT, SPARKS, FLAME.AT ELEVATED
TEMPERATURES, AS IN FIRE CONDITIONS, POLYMERIZATION MAY TAKE PLACE
W/POSS CNTNR RUPTURE.
Hazardous Decomposition Products:CO, HYDROGEN CHLORIDE (CORROSIVE &
POISONOUS) & UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED DURING
COMBUSTION.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE,
AND LOCAL REGULATIONS .

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of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
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assume responsibility for the suitability of this information to their
particular situation.