Product ID:32405, ALLYL CHLORIDE
MSDS Date:01/10/1991
FSC:6850
NIIN:00N017196
MSDS Number: BNMTR

SHELL OIL CO

HOUSTON, TX 77210
US

Emergency Phone: 713-473-9461;800-424-9300(CHEMTREC)

Info Phone: 713-241-4819

Preparer: J. C. WILLET

Cage: SHELO

SHELL OIL COMPANY

4320 HOUSTON, TX 77210 US

Telephone: 800-231-6950

Cage: 54527

GIVE 2 GLASSES OF H*2O & INDUCE VOMIT BY TOUCHING

RTECS: 9999999ZZ

BELOW HIPS WHILE VOMIT. GET MED ATTN. NOTE TO PHYS

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& 15CC (1 TABLESPOON) SYRUP OF IPECAC. IF SYMP SUCH

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EMESIS, GASTRIC LAVAGE SHOULD BE CONSIDERED

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CONTAIN. H*2O FOG MAY BE USEFUL IF SUPPRESSING

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PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE

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PLACE IN NON-LEAKING CNTNRS FOR PROPER DISP. FLUSH

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TAKE UP W/ABSORB MATL &

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DISTANT FROM HANDLING SITE. FLASH-FIRE CAN RSLT.

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VENT. CNTNRS, EVEN THOSE THAT HAVE BEEN EMPTIED, CAN

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PERFORM SIMILAR OPER ON/NEAR CNTNRS. STATIC ELEC

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BOND & GROUND TRANSFER CNTNRS & EQUIP. ALLYL

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HYDROLYSIS IN H*2O TO FORM ALLYL ALCOHOL & HCL.WASH

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TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHING

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PROPENE, 3-CHLORO-; (ALLYL CHLORIDE) (SARA III)

CAS: 107-05-1

RTECS: UC7350000

Fraction By Weight: 100%

OSHA PEL 1 PPM/2 STEL

ACGIH TLV: 1 PPM/2 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BY MUSCULAR WEAKNESS AND LOSS OF SENSATION IN

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LUNG ALLERGIES MAY INCREASE CHANCE OF

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REMOVE VICTIM TO

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DO NOT GIVE LIQ

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THAN 2 GLASSES OF H*2O & INDUCE VOMIT BY GIVING 30CC

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LD50 LC50 Mixture:LD50: (ORAL,RAT) 0.7 G/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: SEV IRRIT. SKIN: SEV IRRIT. MAY
CAUSE SKIN SENSIT. SKIN ABSORP LEADS TO DEEP SEATED PAIN IN AREA
SOMETIMES DESCRIBED AS "DEEP BONE" ACHE. INHAL: MAY CAUSE SEV IRRIT
TO NOSE, THROAT & RESP TRACT. PROD IS MOD TOX & MAY BE HARMFUL IF
INHALED; MAY PRDC LIVER, KIDNEY, LUNG, & PERIPHERAL NERV DMG. HIGH
CONC (SUPP DATA)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:EARLY TO MOD CNS DEPRESS MAY BE EVIDENCED BY
GIDDINESS, HDCH, DIZZ & NAUS; IN EXTREME CASES, UNCON/DEATH MAY
OCCUR. KIDNEY DMG MAY BE EVIDENCED BY CHANGES IN URINE OUTPUT,
URINE APPEARANCE/EDEMA (SWEL LING FROM FLUID RETENTION). LUNG DMG
(SCARRING, BRONCH, EMPHYSEMA MAY BE EVIDENCED BY SHORT OF BRTH,
ESPEC ON(SUPP DATA)
Medical Cond Aggravated by Exposure:PREEXISTING SKIN, EYE & RESP
DISORDERS MAY BE AGGRAVATED BY EXPOS TO PROD. IMPAIRED LIVER,KIDNEY
& LUNG FUNC FROM PREEXISTING DISORDERS MAY BE AGGRAVATED BY EXPOS
TO PROD. PREEXISTING SKIN/ (ING 3)

First Aid:EYE:IMMED FLUSH EYES W/PLENTY OF H*2O FOR AT LEAST 15 MIN
WHILE HOLDING EYELIDS OPEN.GET MED ATTN. SKIN: IMMED REMOVE CONTAM
CLTHG/SHOES. WIPE EXCESS FROM SKIN & FLUSH W/PLENTY OF H*2O FOR AT
LEAST 15 MIN.USE SOAP IF AVAIL/FOLLOW BY WASHING W/SOAP & H*2O.DO
NOT REUSE CLTHG UNTIL THORO CLEANED. GET MED ATTN. CONTAM LEATHER
ARTICLES, INCLUDING SHOES, CANNOT BE DECONTAM & SHOULD BE DESTROYED
(ING 4)

Flash Point Method:TCC
Flash Point:-25F,-32C
Lower Limits:3.2%
Upper Limits:11.2%
Extinguishing Media:WATER FOG, FOAM, DRY CHEM/CO*2. DO NOT USE DIRECT
STREAM OF WATER. PROD WILL FLOAT & CAN BE REIGNITED ON SURF OF
H*2O.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD POS PRESS SCBA & FULL
PROT EQUIP.DANGER. EXTREM FLAM. CLEAR FIRE AREA OF UNPROT PERS &
ISOLATE. COOL FIRE EXPOSED CNTNRS W/H*2O.
Unusual Fire/Explosion Hazard:HANDLE AS EXTREM FLAM LIQ. VAPS CAN FORM
FLAM MIX AT ORDINARY TEMPS. ALLYL CHLORIDE PRODUCES TOX HYDROGEN
CHLORIDE &/OR PHOSGENE & CO ON COMBUST. (SUPP DATA)

Spill Release Procedures:ELIMINATE ALL IGNIT SOURCES. HANDLING EQUIP
MUST BE GROUNDED TO PVNT SPARKING. LRG SPILLS: ISOLATE HAZ AREA &
DENY ENTRY TO UNNEC PERS. WEAR APPROP NIOSH/MSHA APPRVD RESP & PROT
CLTHG. SHUT OFF SOURCE OF LEAK ONLY IF SAFE TO DO SO. DIKE & (ING
11)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL, DRY PLACE WITH ADEQUATE
VENTILATION. KEEP LIQUID AND VAPOR AWAY FROM HEAT, SPARKS AND
FLAME.
Other Precautions:SURFS THAT ARE SUFF HOT MAY IGNITE EVEN LIQ PROD IN
ABSENCE OF SPARKS/FLAME. EXTING PILOT LIGHTS, CIGARETTES & TURN OFF
OTHER SOURCES OF IGNIT PRIOR TO USE & UNTIL ALL VAPS ARE GONE. VAPS
MAY ACCUMULA TE & TRAVEL TO IGNIT SOURCES (ING 15)

Respiratory Protection:USE NIOSH/MSHA APPROVED RESP TO PVNT
OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134 USE EITHER NIOSH/MSHA
APPROVED FULL-FACE, ATMOSPHERE-SUPPLYING RESPIRATOR OR
AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPO RS.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD
BE AVAILABLE FOR EMERGENCY USE.
Work Hygienic Practices:AVOID CONTACT WITH EYES. AVOID CONTACT WITH
SKIN AND CLOTHING.
Supplemental Safety and Health
EXPLO HAZ: VAPS ARE DENSER THAN AIR & CAN TRAVEL CONSIDERABLE DISTANCES
ALONG GROUND TO IGNIT SOURCE. HLTH HAZ: MAY PRDC CNS DEPRESS.
INGEST: HIGHLY TOX & MAY BE FATAL IF SWALLOWED. MAY PRDC LIVER & K
IDNEY DMG. SIGNS & SYMP: EXERTION, & MAY BE ACCOMPANIED BY CHRONIC
COUGH. PERIPHERAL NERV DMG MAY BE EVIDENCED (ING 2)

Boiling Pt:B.P. Text:113F,45C
Vapor Pres:294 @ 68F
Vapor Density:2.6
Spec Gravity:0.93 (H*2O=1)
Evaporation Rate & Reference:7 (N-BUTYL ACETATE=1)
Solubility in Water:0.36%
Appearance and Odor:COLORLESS TO YELLOW, MOBILE LIQUID, PUNGENT
IRRITATING ODOR.

Stability Indicator/Materials to Avoid:YES
CONTACT WITH CAUSTICS, AMINES, AMMONIA, FERRIC CHLORIDE, MAGNESIUM,
ALUMINUM, STRONG ACIDS & GALVANIZED STEEL.
Stability Condition to Avoid:HEAT, SPARKS, FLAME.AT ELEVATED
TEMPERATURES, AS IN FIRE CONDITIONS, POLYMERIZATION MAY TAKE PLACE
W/POSS CNTNR RUPTURE.
Hazardous Decomposition Products:CO, HYDROGEN CHLORIDE (CORROSIVE &
POISONOUS) & UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED DURING
COMBUSTION.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE,
AND LOCAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.