Product ID:02100, RU 2000 REGULAR UNLEADED GASOLINE
MSDS Date:09/18/1986
FSC:9130
NIIN:01-089-6745
MSDS Number: BNPVM

SHELL OIL COMPANY

HOUSTON, TX 77210
US

Emergency Phone: 713-473-9461;800-424-9300(CHEMTREC)

Info Phone: 713-241-4819

Preparer: JOHN P. SEPESI

Cage: 54527

SHELL OIL COMPANY

2463 HOUSTON, TX 77210 US

Telephone: 800-231-6950

Cage: 54527

GASOLINE, UNLEADED (ING 2-5 ARE CONSTITUENTS OF INGRED 01)

RTECS: LY3373000

Fraction By Weight: 100%

ALKANES, CYCLOALKANES, ALKENES & AROMATIC HYDROCARBONS

Fraction By Weight: BALANCE

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 0-25%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENE (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 0-25%

OSHA PEL 100 PPM;150 STEL

ACGIH TLV: 100 PPM;150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <5.0%

OSHA PEL 1 PPM;5 STEL

ACGIH TLV: 10 PPM

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

LOSS OF APPETITE, JAUNDICE & SOMETIMES PAIN IN

RTECS: 9999999ZZ

UNLEADED MOTOR GAS, WHICH WAS FULLY VAPORIZED, HAS

RTECS: 9999999ZZ

GASOLINE EXPOS ALSO PRODUCED AN INCR OF LIVER CANCER

RTECS: 9999999ZZ

5 DAYS/WK FOR A TOTAL OF 27 MONTHS. RPTD HIGH LEVEL

RTECS: 9999999ZZ

TISSUES CAUSING BLOOD ABNORMALITIES & POSSIBLY

RTECS: 9999999ZZ

IN GASOLINE VAP DUE TO LOW BENZENE CONTENT. INHAL

RTECS: 9999999ZZ

@ 10,000 PPM. TOLUENE (108-88-3) APPEARS ON THE NAVY

RTECS: 9999999ZZ

FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ

RTECS: 9999999ZZ

OCCURS SPONTANEOUSLY KEEP HEAD BELOW HIPS

RTECS: 9999999ZZ

IF >2.0 ML/KG INGESTED & VOMIT HAS NOT

RTECS: 9999999ZZ

KEEP VICTIM'S HEAD BELOW HIPS TO PVNT ASPIR. IF SYMP

RTECS: 9999999ZZ

BEFORE EMESIS, GASTRIC LAVAGE USING A CUFFED

RTECS: 9999999ZZ

DIKE & CNTN. H*2O FOG MAY BE USEFUL IN

RTECS: 9999999ZZ

OR PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE

RTECS: 9999999ZZ

PLACE IN NON-LEAKING CNTNRS FOR PROPER DISP.FLUSH

RTECS: 9999999ZZ

TAKE UP W/AN ABSORB & PLACE IN

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50: (ORAL,RAT) > 5 G/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYE:MOD IRRIT. SKIN:PRLNGD & RPTD LIQ
CNTCT CAN CAUSE DEFATTING & DRYING RESULTING IN IRRIT & DERMATITIS.
INHAL:IRRIT TO NOSE, THROAT & RESP TRACT & ADDNLY, MAY PRODUCE
LIVER & KIDNEY DMG. INGEST: HAR MFUL/FATAL. MAY RESULT IN VOMIT;
ASPIR (BRTHG) OF VOMITUS INTO LUNGS MAY RSLT IN ASPIR PNEUMONITIS.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:BENZENE: KNOWN CARCINOGEN (NTP), GROUP 1
(IARC), OSHA-REGULATED, GASOLINE, UNLEADED GROUP 2B (IARC)
Effects of Overexposure:HLTH HAZ:EARLY TO MODERATE CNS DEPRESS MAY BE
EVIDENCED BY GIDDINESS, HDCH, DIZZ, & NAUS; IN EXTREME CASES, UNCON
& DEATH MAY OCCUR. ASPIR PNEUMONITIS MAY BE EVIDENCED BY COUGHING,
LABORED BRTHG & CYA NOSIS; IN SEV CASES DEATH MAY OCCUR. KIDNEY DMG
MAY BE EVIDENCED BY CHANGES IN URINE OUTPUT, URINE APPEARANCE(SUPP
DATA)
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN, & RESP
DISORDERS MAY BE AGGRAVATED BY EXPOS TO THIS PROD. IMPAIRED LIVER &
KIDNEY FUNCTION FROM PRE-EXISTING DISORDERS MAY BE AGGRAVATED BY
EXPOS TO THIS PRODUCT.

First Aid:EYE: FLUSH W/H*2O FOR @ LST 15 MIN WHILE HOLDING EYELIDS
OPEN. GET MED ATTN. SKIN: FLUSH W/H*2O WHILE REMOVING CONTAM
CLTHG/SHOES. FOLLOW BY WASHING W/SOAP & H*2O. DO NOT REUSE
CLTHG/SHOES UNTIL CLEAN ED. IF IRRIT PERSISTS, GET MED ATTN. INHAL:
REMOVE VICTIM TO FRESH AIR & PROVIDE O*2 IF BRTHG IS DFCLT. GIVE
ARTF RESP IF NOT BRTHG. GET MED ATTN. INGEST: DO NOT INDUCE
VOMITING. IF VOMIT (ING 14)

Flash Point Method:TCC
Flash Point:-40F,-40C
Lower Limits:1.3%
Upper Limits:7.6%
Extinguishing Media:H*2O FOG, FOAM, DRY CHEM/CO*2. DO NOT USE A DIRECT
STREAM OF H*2O. PROD WILL FLOAT & CAN BE REIGNIT ON SURF OF H*2O.
Fire Fighting Procedures:DANGER. EXTREMELY FLAMM. CLEAR FIRE AREA OF
UNPROT PERSONNEL & ISOLATE. DO NOT ENTER CONFINED FIRE SPACE
WITHOUT NIOSH/MSHA APPRVD SCBA & FULL PROT (SUPP DATA)
Unusual Fire/Explosion Hazard:VAP ARE HVR/AIR ACCUMLATING IN LOW AREAS
TRAVELING ALONG THE GROUND AWAY FROM THE HNDLG SITE. DO NOT WELD,
HEAT/DRILL ON/NEAR CNTNR. IF EMERGENCY (SUPP DATA)

Spill Release Procedures:DANGER. EXTREMELY FLAMM. ELIM ALL IGNIT
SOURCES. GROUND HNDLG EQUIP TO PVNT SPARKING. LRG SPILLS:ISOLATE
HAZ AREA & DENY ENTRY TO UNNEC PERSONNEL. WEAR APPROP NIOSH/MSHA
APPRVD RESP & PROT CLTHG. SHUT OFF SOURCE OF LEAK ONLY IF SAFE TO
DO SO.(ING 18)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DANGER. EXTREMNELY FLAMMABLE. AVOID
HEAT/SPARKS/OPEN FLAMES, INCLUDING PILOT LIGHTS, & STRONG OXIDIZING
AGENTS. USE EXPLO-PROOF VENT TO PVNT ACCUM.
Other Precautions:ALL HNDLG EQUIP MUST BE GROUNDED TO PVNT SPARKING.
HARMFUL/FATAL IF SWALLOWED. DO NOT SIPHON GASOLINE BY MOUTH. FOR
USE AS A MOTOR FUEL ONLY. DO NOT USE AS A CLEANING SOLV/FOR OTHER
NON-MOTOR FUEL USE S.

Respiratory Protection:UNDER CNDTNS OF POTENTIAL HIGH EXPOS, USE
NIOSH/MSHA APPRVD RESP. PER 29 CFR 1910.134 USE EITHER NIOSH/MSHA
APPRVD ATMOSPHERE-SUPPLYING RESP/AIR-PURIFYING RESP FOR ORGANIC
VAPS. FOR SERVICE STATION PE RSONNEL PROT, SEE SPEC FOR HNDLG &
USE.
Ventilation:USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL
VAPOR CONCENTRATIONS.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH W/SOAP & H*2O BEFORE EATING, DRINKING,
SMOKING/USING TOILET FACILITIES. LAUNDER CONTAM CLTHG BEFORE REUSE.
Supplemental Safety and Health
SPEC GRAV:0.72-0.76 (H*2O=1).FIRE FIGHT PROC: EQUIP.COOL FIRE EXPOS
CNTNRS W/H*2O.EXPLO HAZ:SITUATIONS REQUIRE DRILLING, ONLY TRAINED
EMERGENCY PERSONNEL SHOULD DRILL.WASTE DISP METH:RECYCLING R
ECOMMENDED.DISP OF I/A/W FED, STATE, LOC REGS. EFTS OF OVEREXP:OR
EDEMA. LIVER DMG MAY BE EVIDENCED BY (ING 6)

Boiling Pt:B.P. Text:100F,38C
Vapor Pres:7-14.5 PSI
Vapor Density:3.5
Spec Gravity:SUPP DATA
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BRONZE COLOR, CLEAR AND BRIGHT LIQUID. HYDROCARBON
ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, SPARKS, OPEN FLAMES. PREVENT
VAPOR ACCUMULATION.
Hazardous Decomposition Products:CO AND OTHER UNIDENTIFIED ORGANIC
COMPOUNDS CAN BE FORMED UPON COMBUSTION.

Waste Disposal Methods:MATL IS PROD & NOT WASTE. IF DISCARDED/INTENDED
TO BE DISCARDED AS IS, IT IS LIQ IGNIT HAZ WASTE DEFINED IN RCRA
(40 CFR 261.21). EPA HAZ WASTE NO IS D001. FREE LIQ IGNIT WASTES
BANNED FROM DISP BY LA NDFILLING BULK/IN CNTNRS. RECOVER OR (SUPP
DATA)

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of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.