Product ID:#330 DUNCAN SUPER GLOSS AEROSOL SPRAY PAINT
MSDS Date:08/01/1987
FSC:8010
NIIN:00N030918
MSDS Number: BNQTS

DUNCAN ENTERPRISES

5673 E SHIELDS AVE
FRESNO, CA 93727
US

Emergency Phone: 303-623-4884

Info Phone: 209-291-4444

Cage: 21546

DUNCAN ENTERPRISES

FRESNO, CA 93727 US

Telephone: 209-291-4444

Cage: 21546

ACETIC ACID, ETHYL ESTER; (ETHYL ACETATE) (SARA III).

CAS: 141-78-6

RTECS: AH5425000

Fraction By Weight: 5-10%

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

186 @ 20C.

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 35-40%

OSHA PEL 1000PPM

ACGIH TLV: 750PPM/1000STEL;9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PROPELLANT - MIXTURE OF INGRDIENTS 6, 7, & 8

RTECS: 9999999ZZ

Fraction By Weight: 23%

PROPANE

CAS: 74-98-6

RTECS: TX2275000

OSHA PEL 1000 PPM

ACGIH TLV: SIMPLE ASPHYXIANT

PROPANE, 2-METHYL-; (ISOBUTANE)

CAS: 75-28-5

RTECS: TZ4300000

BUTANE; (N-BUTANE)

CAS: 106-97-8

RTECS: EJ4200000

OSHA PEL 800 PPM

ACGIH TLV: 800 PPM

NON HAZARDOUS INGREDIENTS

Fraction By Weight: 8-17%

OTHER FLAMES, SPARKS, HEATERS, SMKG, ELECTRIC

RTECS: 9999999ZZ

FROM MATERIAL HANDLING POINT.

RTECS: 9999999ZZ

WASH W/SOAP & WATER OR VARIOUS HAND

RTECS: 9999999ZZ

(NIOSH/MSHA APPROVED TC23C OR EQUIVALENT), OR

RTECS: 9999999ZZ

IT MIGHT BE HARMFUL WHEN HIGH CONCENTRATIONS OF

RTECS: 9999999ZZ

2-PENTANONE, 4-HYDROXY-4-METHYL-; (DIACETONE ALCOHOL).

CAS: 123-42-2

RTECS: SA9100000

Fraction By Weight: 5-10%

OSHA PEL 50 PPM

ACGIH TLV: 50 PPM

ACETIC ACID, ISOBUTYL ESTER; (ISOBUTYL ACETATE) (SARA

CAS: 110-19-0

RTECS: AI4025000

Fraction By Weight: 10-15%

OSHA PEL 150 PPM

ACGIH TLV: 150 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL:EXCESSIVE INHAL OF VAPORS
CAN CAUSE NASAL & RESPIRATORY IRRIT, DIZZ, WEAK, FATG, NAUS, HDACH,
POSSIBLE UNCON & EVEN ASPHYXIATION. EYE CONT:CAN CAUSE SEVERE
IRRIT, REDNESS, TEARING, BLURRE D VISION. INGEST:CAN CAUSE GI
IRRIT, NAUS, VOMIT, DIARR. SKIN CONT:CAN CAUSE IRRIT FOR SOME
PERSONS. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: CHRONIC: REPORTS HAVE ASSOC RPTD/
PRLNG OCCUP OVEREXP TO SOLVENTS W/PERMANENT BRAIN & NERVS SYS
DAMAGE. SEVERE OVEREXP IN LAB ANIMALS HAS ALSO CAUSED LIVER ABNORM,
DAMAGE TO KIDNEYS/LUNGS/SP LEEN. INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING/ INHALING THE CONTENTS MAY BE HARMFUL OR FATAL.
Medical Cond Aggravated by Exposure:CAN CAUSE ALLERGIC RESPIRATORY
AND/OR SKIN REACTION.

First Aid:INHAL: REMOVE TO FRESH AIR. IF BRTHG IS DIFFICULT, ADMINISTER
O2. IF BRTHG STOPPED, GIVE ARTF RESPIRATION & SEEK MED HELP. EYES:
FLUSH W/WATER FOR A MINIMUM OF 15 MINUTES WHILE OCCASIONALLY
HOLDING LI DS OPEN. GET MED ATTN. INGEST: DO NOT INDUCE VOMIT
(ASPIRATION OF MATL INTO LUNGS CAN CAUSE CHEM PNEUMONITIS, WHICH
CAN BE FATAL). KEEP PERSON WARM & QUIET AND GET MED ATTN/POIS CTL
CTR. (ING 12)

Flash Point:SEE SUPP DATA
Lower Limits:1%
Extinguishing Media:"ALCOHOL" FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFTIVE. WATER MAY BE USED TO COOL CLOSED
CONTRS TO PVNT PRESS BUILD-UP AND (SUPP DATA)
Unusual Fire/Explosion Hazard:EXTREMELY FLAMM LIQ. CLOSED CONTRS MAY
EXPLODE &/OR AUTOIGNITE WHEN EXPOSED TO EXTREME HEAT. VAPS ARE
HEAVIER THAN AIR & MAY TRAVEL ALONG THE GROUND (SUPP DATA)

Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. VENTILATE
AREA. ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBENT OR OTHER
ABSORBENT MATERIAL AND TRANSFER TO A CLOSED CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE IN AREAS ABOVE 120F OR IN
DIRECT SUNLIGHT, OR NEAR HEAT OR OPEN FLAMES. DO NOT PUNCTURE OR
INCINERATE.
Other Precautions:STORE LARGE QUANTITIES IN BUILDINGS PROTECTED FOR
STORAGE OF NFPA CLASS IC FLAMMABLE LIQUIDS.

Respiratory Protection:FOR CASUAL/OCCASIONAL USE - TO AVOID BRTHG VAPS/
SPRAY MIST, OPEN WINDOWS/DOORS OR USE OTHER MEANS TO ENSURE FRESH
AIR ENTRY DURING APPLICATION/ DRYING. IF EXPERIENCE EYE
WATERING/HDACH/DIZZ, INCR FRE SH AIR, WEAR RESPIRATORY PROT (ING
13)
Ventilation:FOR REGULAR/CONTINUOUS USE - PROVIDE SUFFICIENT MECHANICAL
(GEN) &/OR LOCAL EXHAUST VENT TO MAINTAIN EXPOS BELOW TLV'S.
Protective Gloves:CHEMICAL RESISTANT GLOVES (NEOPRENE).
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:WHERE SPECIAL OR UNUSUAL CONDITIONS EXIST,
THE EXPERT ASSISTANCE OF AN INDUSTRIAL HYGIENIST SHOULD BE SOUGHT.
Work Hygienic Practices:WASH HANDS BEFORE EATING OR USING WASHROOM. AS
WITH ALL CHEMICALS, MINIMIZE PERSONAL CONTACT AND BREATHING OF
VAPORS.
Supplemental Safety and Health
EVAP RATE: SLOWER THAN ETHER (PROPELLANT FASTER); (BUTYL ACETATE = 1)
PRODUCTS >1, PROPELLANT <1. FLASH POINT: 0F(- 18C), (PROPELLANT =
-100F). FIRE FIGHT PROC: POSS AUTOIGNIT/EXPLOS WHEN EXPOSED TO E
XTREME HEAT. IF WATER IS USED, FOG NOZZARE PREF. EXPLO HAZ: OR MAY
BE MOVED BY VENT & IGNITED BY PILOT LIGHTS, (ING 10)

HCC:V3
Boiling Pt:B.P. Text:>133F,>56C
Melt/Freeze Pt:M.P/F.P Text:>1500F,>816
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Spec Gravity:<1 (H2O=1)
Evaporation Rate & Reference:SEE SUPP DATA
Solubility in Water:SLIGHT TO MODERATE
Appearance and Odor:TYPICAL SOLVENT PAINT.
Percent Volatiles by Volume:85-90

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS AND HEAT.
Stability Condition to Avoid:HEAT, SPARKS, AND OPEN FLAME.
Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS, CO2/CO,
VARIOUS HYDROCARBONS, NITROGEN COMPOUNDS, ETC., WHEN BURNED.

Waste Disposal Methods:MATERIALS COLLECTED ON ABSORBENT MATERIAL MAY BE
DEPOSITED IN A POSTED TOXIC SUBSTANCE LANDFILL IN ACCORDANCE WITH
LOCAL, STATE, AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.