Product ID:0135, SS-80
MSDS Date:04/11/1986
FSC:6850
NIIN:00N032369
MSDS Number: BNQZT

NATIONAL CHEMSEARCH DIV OF NCH CORP

IRVINE, TX 75015
US

Emergency Phone: 214-438-4144

Info Phone: 214-438-0401

Preparer: DON POKRAS

Cage: DO481

NCH CORP

152170 IRVING, TX 75015-2170 US

Telephone: 972-438-0563

Cage: 20913

INDOTRACHAEL TUBE WILL PREVENT ASPIRATION. CONSULT A

RTECS: 9999999ZZ

LIGROINE; (ALIPHATIC PETROLEUM DISTILLATE)

CAS: 8032-32-4

RTECS: OI6180000

OSHA PEL 500 PPM (MFR)

ACGIH TLV: 100 PPM (MFR)

ETHANE, 1,1,1-TRICHLORO; (1,1,1-TRICHLOROETHANE). MFR CAS

CAS: 71-55-6

RTECS: KJ2975000

OSHA PEL 350 PPM;450 PPM STEL

ACGIH TLV: 350 PPM;450 PPM STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHANE, DICHLORO-; (METHYLENE CHLORIDE)

CAS: 75-09-2

RTECS: PA8050000

OSHA PEL 500 PPM; 1000, C

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

NOT TO INTERFERE W/REPRODUCTION. NEGATIVE/OR

RTECS: 9999999ZZ

/ANIMALS. THIS IS CONSISTENT W/LACK OF INTERACTION

RTECS: 9999999ZZ

TESTS HAVE GENERALLY BEEN POSITIVE, OVERALL DATA

RTECS: 9999999ZZ

SIGNIFICANT FACTOR IN TOX OF METHYLENE CHLORIDE.

RTECS: 9999999ZZ

EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFT

RTECS: 9999999ZZ

CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN

RTECS: 9999999ZZ

DPNDG ON

RTECS: 9999999ZZ

GASTRIC LAVAGE SHOULD BE CONSIDERED. KEEP HEAD BELOW

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: CAN LEAD TO CNS DEPRESS,
CAN PRDCE HDCH, DIZZ, NAUS, & LOSS OF COORD & CONSCIOUSNESS. SKIN:
DEFAT OF SKIN & IRRIT. EYES: IRRIT, TEARS, & RED. INGEST: NAUS,
DIZZ, VOMIT, POSS LOSS OF CONS CIOUSNESS. CHRONIC: CNS DEPRESS,
KIDNEYDAM, DERM, & LIVER DAM. EXCESSIVE EXPOS MAY CAUSE CNS, LIVER
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE: ANTICIPATED TO BE A
CARCINOGEN (NTP), GROUP 2B(IARC).
Effects of Overexposure:HLTH HAZ:/KIDNEY EFTS. METHYLENE CHLORIDE HAS
BEEN SHOWN TO INCR RATE OF SPONT OCCURING MALIGNANT TUMORS IN ONE
STRAIN OF LAB MOUSE & BENIGN TUMORS IN LAB RATS. OTHER ANIMAL
STUDIES, & SEVERAL EPIDEMI OLOGY STUDIES, FILED TO SHOW A
TUMORIGENIC RESPONSE RELATABLE TO METHYLENE CHLORIDE. IT IS NOT
BELIEVED TO (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL: REMOVE TO FRESH AIR & TREAT SYMPTOMATICALLY. GIVE O2
IF BRTHG IS DFCLT. GIVE ARTF RESP IF BRTHG STOPS. GET MED HELP.
EYE: FLUSH W/H2O FOR @ LST 15 MIN. SEE PHYS IF IRRIT PERSISTS.
SKIN: WASH W/ SOAP/H2O. APPLY AN EMOLLIENT RICH CREAM. SEE PHYS IF
IRRIT PERSISTS. INGEST: DO NOT INDUCE VOMIT, EVEN IF VOMIT OCCURS.
IF IT OCCURS, KEEP HEAD BELOW HIPS TO PVNT ASPIR OF LIQ INTO LUNGS.
(ING 10)

Flash Point Method:TOC
Flash Point:185F,85C
Extinguishing Media:FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:PHOSGENE CAN BE PRODUCED. THERMAL
DECOMPOSITION PRODUCTS MAY INCLUDE HCL & PHOSGENE .

Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. PVNT FROM
ENTERING SEWER/H2O SOURCES. VENT ENCLOSED SPACES/WEAR APPROP RESP
FOR PROT. CLEANUP-PUMP UP (EXPLOSION PROOF MOTORS), OR SOAK UP WITH
SAND, COTTON WASTES OR OTHE R ABSORBANT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN ORIGINAL CONTAINER ONLY.
FOLLOW LABEL DIRECTIONS. STORE INDOORS BETWEEN 50&120F.
Other Precautions:KEEP FROM CHILDREN. NO SMOKING IN AREA OF USE. DO NOT
USE IN GENERAL VICINITY OF ARC WELDING, OPEN FLAMES OR HOT
SURFACES. HEAT &/OR UV RADIATION MAY CAUSE FORMATION OF HCL &/OR
PHOSGENE .

Respiratory Protection:NO RESP IS NEEDED IN NORMAL USE. IN EMER
SITUATIONS, HOWEVER THE FOLLOWING ARE RECOMMENDED: NIOSH/MSHA
APPRVD GASMASK W/ORGANIC VAP CANISTER & FULL FACE PLATE/SUPPLIED
AIR W/FULL FACEPLATE/SCBA W/FULL FACE PLATE.
Ventilation:SUFFICIENT VENTILATION TO BE BELOW ALLOWABLE CONCENTRATION.
Protective Gloves:VITON, PVA OR EQUIVALENT.
Eye Protection:CHEM WRKRS GOG & FULL LGTH FSHLD .
Other Protective Equipment:HEADGEAR & APRON WHEN SPRAYING. DO NOT WEAR
CONTACT LENSES. EMERG EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP: POSE A MEASURABLE CARCIN RISK TO MAN WHEN HNDLD AS
RECOM. BIRTH DEFECTS ARE UNLIKELY. EXPOS HAVING NO EFT ON MOTHER
SHOULD HAVE NO EFT ON FETUS. DID NOT CAUSE BIRTH DEFECTS IN ANIMALS
; OTHER EFTS WERE SEEN IN FETUS ONLY @ DOSES WHICH CAUSED TOX EFTS
TO MOTHER. IN ANIMAL STUDIES, HAS BEEN SHOWN (ING 4)

HCC:V4
Boiling Pt:B.P. Text:113F,45C
Vapor Pres:120
Vapor Density:1
Spec Gravity:0.986(H2O=1)
Evaporation Rate & Reference:0.1(BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS, SWEET SOLVENT ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, BASES & SELECTED AMINES. ALSO ALUMINUM.
Stability Condition to Avoid:OPEN FLAMES.
Hazardous Decomposition Products:CAN @ DECOMPOSITION TEMPERATURE
RELEASE CO2 OR CO, PHOSGENE, & HYDROGEN CHLORIDE.

Waste Disposal Methods:WASTE LIQ SHOULD BE SENT TO A LICENSED
RECLAIMER/ INCINERATED @ A LICENSED INCINERATOR. ALSO SPILLED SOLV
& ABSORBANT WIPING MATL SHOULD BE DISPOSED OF IN A WASTE MANAGEMENT
FACILITY LICENSED FOR THIS PURPOSE. DISPOSE OF I/A/W FED/ST &
LOCREGS

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assume responsibility for the suitability of this information to their
particular situation.