Product ID:NA1789, LI'L BROTHER SAM
MSDS Date:12/01/1985
FSC:7930
NIIN:00N032052
MSDS Number: BNSJZ

STATE CHEMICAL MFG CO

3100 HAMILTON AVE
CLEVELAND, OH 44114-3701
US

Emergency Phone: 216-861-7114

Info Phone: 216-861-7114

Cage: 53798

STATE CHEMICAL MANUFACTURING CO.

CLEVELAND, OH 44114-3701 US

Telephone: 216-861-7114

Cage: 53798

HYDROCHLORIC ACID (SARA III)

CAS: 7647-01-0

RTECS: MW4025000

Fraction By Weight: <10%

OSHA PEL 5 PPM, C

ACGIH TLV: 5 PPM, C

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ISOPROPYL ALCOHOL; (ISOPROPANOL) (MFR CAS# 76-63-0)

CAS: 67-63-0

RTECS: NT8050000

Fraction By Weight: <10%

OSHA PEL 400 PPM;500 STEL

ACGIH TLV: 400 PPM;500 STEL

OXALIC ACID

CAS: 144-62-7

RTECS: RO2450000

Fraction By Weight: <2%

OSHA PEL 1 MG/M3;2 PPM STEL

ACGIH TLV: 1 MG/M3;2 PPM STEL

P-TOLUENE SULFONIC ACID; (TOLUENE SULFONIC ACID)

CAS: 104-15-4

RTECS: XT6300000

Fraction By Weight: <5%

PHOSPHORIC ACID

CAS: 7664-38-2

RTECS: TB6300000

Fraction By Weight: <15%

OSHA PEL 1 MG/M3;3 STEL

ACGIH TLV: 1 MG/M3;3 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE FATAL IF SWALLOWED. SKIN
AND EYE CONTACT AND BREATHING OF VAPORS MAY PRODUCE CHEMICAL BURNS.
CHRONIC: NO CHRONIC EFFECTS EXPECTED.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST: PROMPT FIRST AID & TREATMENT IS ESSNTL IF CONT
OCCURS.CALL PHYS IMMED! DRINK LRG VOL OF H2O TO DILUTE ACID. DO NOT
ATTEMPT TO MAKE PERSON VOMIT. INHAL: REMOVE PERSON TO FRESH AIR.
CONT PHYS. E YES: IMMED FLUSH W/PLENTY OF COOL H2O FOR AT LEAST 15
MIN. SEEK PROMPT MED ATTN. CONT LENSES SHOULD NOT BE WORN WHEN
WORKING WITH PRODUCT. SKIN: WIPE OFF GENTLY. IMMED FLOOD SURFACE
W/H2O, (SUPDAT)

Flash Point:NONE TO 200F
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS
.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . AVOID POSSIBLE EXPOSURE TO HYDROGEN CHLORIDE
VAPOR.
Unusual Fire/Explosion Hazard:ACID WILL ATTACK MOST METALS WITH
EVOLUTION OF HYDROGEN.

Spill Release Procedures:VENTILATE AREA. WEARING GLOVES, WIPE OFF
EXCESS LIQUID WITH RAGS OR OIL ABSORBENT. DISPOSE OF CHEMICAL
RECEPTACLE OR DILUTE WITH WATER AND NEUTRALIZE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED. KEEP
FROM FREEZING. WARNING: CORROSIVE. CONTAINS ACID. MAY BE FATAL IF
SWALLOWED. DO NOT BREATH VAPOR OR FUMES.
Other Precautions:DO NOT GET IN EYES,ON SKIN/CLTHG. MAY PRDCE CHEM
BURNS. DO NOT USE IN/ALLOW TO SPLASH ON ENAMEL OR GUARANTEED
ACID-RESISTANT METAL. EMPTY CNTNRS & RINSE W/H2O BEFORE DISP.DO NOT
MIX W/ANY OTHER CHEM.A VOID SPLASHING ON NYLON/COTTON. (SUPDAT

Respiratory Protection:NO SPECIAL PROTECTION NEEDED UNDER NORMAL USE
CONDITIONS. IF NEEDED TO STAY BELOW TLV USE A NIOSH/MSHA APPROVED
RESPIRATOR FITTED WITH ACID (HYDROCHLORIC) CARTRIDGES.
Ventilation:USE IN VENTILATED AREAS.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:A SOURCE OF CLEAN WATER SHOULD BE NEARBY IN
CASE OF ACCIDENTAL EYE CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRST AID PROC: USING SOAP FREELY, THEN COVER W/MAGNESIA OR BAKING
SODA. SEEK MEDICAL ATTENTION. OTHER PREC: READ AND FOLLOW ALL LABEL
DIRECTIONS AND PRECAUTIONS BEFORE USING PRODUCT. THESE PRODUCTS A
RE INTENDED FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY. KEEP OUT OF
REACH OF CHILDREN.

HCC:C1
Boiling Pt:B.P. Text:225F,107C
Spec Gravity:1.152 (H2O=1)
pH:<1.0
Solubility in Water:COMPLETE
Appearance and Odor:A CLEAR, GREEN LIQUID, WITH MINT ODOR.
Percent Volatiles by Volume:80(WT)

Stability Indicator/Materials to Avoid:YES
METALS AND STRONG ALKALI, HYDROGEN CHLORIDE VAPOR.
Stability Condition to Avoid:EXTREMELY HIGH TEMPERATURES. DO NOT MIX
WITH OTHER CHEMICALS.
Hazardous Decomposition Products:BURNING PRODUCT MAY PRODUCE HYDROGEN,
CO2 AND OXIDES OF PHOSPHORUS.

Waste Disposal Methods:FOLLOW ALL FEDERAL, STATE AND LOCAL REGULATIONS
REGARDING WASTE DISPOSAL. LARGE QUANTITIES MUST BE DISPOSED OF AS
HAZARDOUS WASTE BECAUSE PH IS LESS THAN 2.5.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.