Product ID:N-4158 BLACK TREE MARKING
MSDS Date:10/31/1991
FSC:8010
NIIN:01-273-8705
MSDS Number: BNWXF

NILES CHEMICAL PAINT CO

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 219-236-5056

Info Phone: 616-683-3377

Preparer: MIKE LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

MINERAL SPIRITS (VAPOR PRESSURE 2.0 MM HG @ 20 C)

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 56%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM; 9293

ALKYD RESIN

Fraction By Weight: 22%

COBALT COMPOUNDS (AS CO) (SARA 313)

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: <1%

OSHA PEL 0.1 MG/M3;AS CO

ACGIH TLV: 0.05 MG/M3;DUST 9293

MANGANESE COMPOUNDS (AS MN) (SARA 313)

CAS: 7439-96-5

RTECS: OO9275000

Fraction By Weight: <1%

OSHA PEL (C) 5 MG/M3 DUST

ACGIH TLV: 5 MG/M3 DUST 9293

PROPRIETARY INGREDIENTS (MFR STATES UNIDENTIFIED

Fraction By Weight: BALANCE

4.51 LBS/GAL.

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: SEVERE IRRITATION, LACRIMATION,
VISUAL DISTURBANCES, EYE BURNS. SKIN: CAN BE ABSORBED IN TOXIC
AMOUNTS ESPECIALLY ON REPEATED OR PROLONGED EXPOSURE. INHALATION:
NASAL/RESPIRATORY IRRITATION, CNS DEPRESSION, ASPHYXIATION.
INGESTION: GASTROINTESTINAL IRRITATION, BLINDNESS, DEATH.
Explanation of Carcinogenicity:NOT LISTED BY NTP, IARC, OR OSHA.
Effects of Overexposure:EYE: REDNESS, BLURRED VISION. INHALATION: (CNS)
DIZZINESS, DROWSINESS, WEAKNESS, FATIGUE, CONFUSION. NAUSEA,
HEADACHE, VERTIGO, POSSIBLE UNCONSCIOUSNESS. INGESTION: ABDOMINAL
PAIN, NAUSEA, VOMITING, D IARRHEA. TARGET ORGANS SKIN, EYES,
RESPIRATORY SYSTEM, CNS, GI TRACT.
Medical Cond Aggravated by Exposure:NONE KNOWN.

First Aid:INHALATION: MOVE TO FRESH AIR. IF BREATHING HAS STOPPED, GIVE
ARTIF RESPIRATION. GET MED AID ASAP. SKIN: WASH W/SOAP & WATER.
EYE: IMMED FLUSH EYES W/WATER 15 MIN, OCCASIONALLY LIFTING EYELIDS.
GET ME D AID IMMED. CONTACT LENSES SHOULD NOT BE WORN. INGESTION:
INDUCE VOMITING IMMED BY GIVING 2 GLASSES OF WATER & STICKING
FINGER DOWN THROAT. NOTHING BY MOUTH TO UNCONSCIOUS PERSON. GET MED
AID IMMED.

Flash Point Method:TCC
Flash Point:102F,39C
Lower Limits:0.8
Upper Limits:36.0
Extinguishing Media:DRY CHEMICAL, FOAM, CO2.
Fire Fighting Procedures:WEAR SCBA W/FULL FACEPIECE (POS PRESS MODE),
FULL PROTECT CLOTH. WATER MAY BE USED TO COOL CLOSED CNTNRS TO
PREVENT PRESS BLDUP/AUTO IGNIT/EXPLOS W/HEAT.
Unusual Fire/Explosion Hazard:KEEP CNTNRS CLSD. ISOLATE FROM HEAT/IGNIT
SOURCE. CLSD CNTNR MAY EXPLOD W/HEAT. APPLIC TO HOT SRFCS REQUIRE
SPCL PRECAUTION. EXPOS TO DECOMP PROD HEALTH HAZARD.

Spill Release Procedures:ELIMINATE IGNITION SOURCES. MINIMIZE BREATHING
OF VAPORS & AVOID SKIN CONTACT. ABSORB WITH INERT MATERIAL SUCH AS
CLAY, SOIL OR COMMERCIALLY AVAILABLE ABSORBENT. SHOVEL RECLAIMED
LIQUID & ABSORBENT IN TO RECOVERY OR SALVAGE DRUMS FOR DISPOSAL.

Handling and Storage Precautions:CONTAINERS OF THIS MATERIAL MAY BE
HAZARDOUS WHEN EMPTY. DO NOT WELD OR FLAME CUT ON EMPTY DRUMS.
AVOID STORAGE IN HIGH TEMP AREAS OR NEAR FIRE/FLAME.
Other Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN USE. AVOID ROUGH
HANDLING.

Respiratory Protection:WEAR APPROPRIATE (TYPE TC-23C-75) FITTED
HALF-MASK OR FULL FACEPIECE RESPIRATOR (NIOSH/MSHA) DURING & AFTER
APPLICATION UNLESS AIR MONITORING DEMONSTRATES VAPOR/MIST LEVELS
ARE BELOW APPLIC LIMITS. FO LLOW RESPIRATOR MFR DIRECTIONS FOR USE.
Ventilation:SUFF VENT (VOL/PATTRN) TO KEEP AIR CONC BELOW TLV/PEL.
REMOVE DECOMP PROD (WELD/FLAME CUT). BAKING FINISH-VENT VAPORS.
Protective Gloves:NITRILE OR VITON GLOVES (CHEM RESISTANT)
Eye Protection:CHEM GOGGLES, SAFETY GLASSES, FACE SHLDS
Other Protective Equipment:REMOVE ANY CLOTHING THAT BECOMES WET (TO
AVOID FLAMMABILITY HAZARD) AND WASH BEFORE REUSE.
Work Hygienic Practices:WASH PROMPTLY WHEN SKIN BECOMES CONTAMINATED.
WASH HANDS BEFORE EATING, SMOKING OR USING RESTROOM.
Supplemental Safety and Health

HCC:F4
Boiling Pt:B.P. Text:146 TO 330F
Vapor Density:> AIR
Spec Gravity:7.93 LBS/GAL
Viscosity:BROOKFIELD
Evaporation Rate & Reference:SLOWER THAN ETHER.
Solubility in Water:SLIGHT.
Appearance and Odor:LIQUID, ODOR OF SOLVENTS.
Percent Volatiles by Volume:70.94

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Hazardous Decomposition Products:CAN PRODUCE CARBON MONOXIDE AND/OR
CARBON DIOXIDE.
Conditions to Avoid Polymerization:HIGH TEMPERATURES, SHOCK FROM
DROPPING.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL,
STATE AND FEDERAL REGULATIONS. D-001 (IGNITABLE)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.