Product ID:R-12 SHIELD TITE WET SURFACE COATING
MSDS Date:03/22/1990
FSC:6850
NIIN:00F024166
MSDS Number: BNWYZ

PIONEER/RANDUSTRIAL

4529 INDUSTRIAL PARKWAY
CLEVELAND, OH 44135
US

Emergency Phone: 216 671-5500

Info Phone: 216 671-5500

Cage: PINEE

PIONEER/RANDUSTRIAL

CLEVELAND, OH 44135 US

Telephone: 216-671-5500

Cage: PINEE

PERYLENE

CAS: 198-55-0

RTECS: SE3794000

Fraction By Weight: <50%

COAL TAR PITCH

CAS: 65996-93-2

RTECS: GF8655000

Fraction By Weight: <50%

OSHA PEL 200 MG/CUM

ACGIH TLV: 0.2 MG/CUM (A1)

BENZO (A) PYRENE

CAS: 50-32-8

RTECS: DJ3675000

Fraction By Weight: <50%

OSHA PEL 0.2 MG/M3

ACGIH TLV: A2, MG/M3;9394

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

LIGHT CATALYTICALLY CRACKED DISTILLATE

CAS: 64741-59-9

RTECS: JN9385000

Fraction By Weight: <25%

DISTILLATES (PETROLEUM) INTERMEDIATE CATALYTIC CRACKED

CAS: 64741-60-2

Fraction By Weight: <25%

MINERAL OIL, PETROLEUM EXTRACTS, HEAVY PARAFFINIC

CAS: 64742-04-7

RTECS: PY8042500

Fraction By Weight: 17%

MAGNESIUM ALUMINUM SILICATE *92-2*

CAS: 8031-18-3

Fraction By Weight: 3%

ACGIH TLV: 10 MG/CUM

MAGNESIUM ALUMINUM SILICATE

CAS: 1327-43-1

RTECS: VV8880000

Fraction By Weight: <3%

SILICA DIOXIDE, CRYSTALLINE QUARTZ, SAND (SUSPECTED HUMAN

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: <30%

OSHA PEL SEE TABLE Z3

ACGIH TLV: 0.1 MG/M3 RDUST;9293

CELLULOSE

CAS: 9004-34-6

RTECS: FJ5691460

Fraction By Weight: 3-9%

OSHA PEL 5 MG/CUM

ACGIH TLV: 10 MG/CUM (DUST)

CALCIUM CARBONATE, DOMOLITE, LIMESTONE, WHITING

CAS: 1317-65-3

RTECS: EV9580000

Fraction By Weight: 20-25%

OSHA PEL 15 MG/CUM (DUST)

ACGIH TLV: 10 MG/CUM (DUST)

CHRYSENE

CAS: 218-01-9

RTECS: GC0700000

Fraction By Weight: <50%

OSHA PEL 0.2 PPM

ACGIH TLV: A2 9394

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

REFINED COAL TAR *92-2*

CAS: 65996-90-9

Fraction By Weight: <50%

NAPTHALENE; MOTH FLAKES; MOTH BALLS; NAPHTHALIN; CAMPHOR

CAS: 91-20-3

RTECS: QJ0525000

Fraction By Weight: 6.0%

OSHA PEL 50 MG/CUM

ACGIH TLV: 52 MG/CUM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

ACENAPHTHYLENE

CAS: 208-96-8

RTECS: AB1254000

Fraction By Weight: <50%

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

2-METHYLNAPHTHALENE

CAS: 91-57-6

RTECS: QJ9635000

Fraction By Weight: <50%

DIBENZOFURAN

CAS: 132-64-9

RTECS: HP4430000

Fraction By Weight: 1.5%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

FLUORENE

CAS: 86-73-7

RTECS: LL5670000

Fraction By Weight: <50%

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PHENANTHRENE

CAS: 85-01-8

RTECS: SE7175000

Fraction By Weight: <50%

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

1-METHYLPHENANTHRENE

CAS: 832-69-9

RTECS: SF7810000

Fraction By Weight: <50%

FLUORANTHENE

CAS: 206-44-0

RTECS: LL4025000

Fraction By Weight: <50%

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

PYRENE

CAS: 129-00-0

RTECS: UR2450000

Fraction By Weight: <50%

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: RESPIRATORY TRACT
IRRITATION. EYES: IRRITATION, DAMAGE. SKIN: IRRITATION, DERMATITIS,
ACNE, REACTION, BLISTER. INGESTION: GI IRRITATION, NAUSEA, VOMITING
& FATAL.
Explanation of Carcinogenicity:SILICA/COAL TAR/BENZO(A)PYRENE/LIGHTLY
TREATD OR UNTREATED MINERAL OILS HAVE BEEN DETERMINED TO BE
CARCINOGENS.
Effects of Overexposure:INHALATION: IT MAY CAUSE CANCER OF THE LUNG,
KIDNEYS OR BLADDER. SKIN: PIGMENTATION, GROWTHS, CANCER. EYES:
IRRITATION, DAMAGE. INGESTION: GI IRRITATION, NAUSEA, VOMITING &
FATAL.

First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICAL RESPIRATION
IF BREATHING HAS STOPPED. ADMINISTER OXYGEN IF BREATHING IS
DIFFICULT. EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN: CLEAN
AREA W/CORN OI L/WATERLESS CLEANER, THEN FOLLOW W/SOAP& WATER.
DON'T USE SOLVENTS TO CLEAN. USE HYPOCORTISONE CREAM FOR RELIEF.
INGESTION: DON'T INDUCE VOMITING/GIVE ANYTHING BY MOUTH. OBTAIN MED
ATTN IN ALL CASES.

Flash Point: 180F
Extinguishing Media:DRY CHEMICAL, FOAM, CO2, WATER FOG
Fire Fighting Procedures:WEAR MSHA/NIOSH APPROVED RESPIRATOR (PRESSURE
DEMAND, SCBA) & FULL PROTECTIVE GEAR COOL EXPOSED CONTAINERS
W/WATER SPRAY.
Unusual Fire/Explosion Hazard:ELIMINATE IGNITION SOURCES IF HEATED
>180F. IN CLOSED TANKS, WATER/FOAM MAY CAUSE FROTHING/ERUPTION.
COMBUSTIBLE LIQUID. AUTOIGNITION TEM: >410F.

Spill Release Procedures:VENTILATE AREA & CONTAIN BY DIKING W/SAND
EARTH OR OTHER INERT MATERIAL TO PREVENT ENTRY INTO SEWERS OR OPEN
BODIES OF WATER. TRANSFER SPILLAGE TO CONTAINERS SUITABLE FOR
RECOVERY OR DISPOSAL.

Handling and Storage Precautions:COAL TAR IS A PHOTOTOXIC SUBSTANCE.
STORE CONTAINERS SEPERATE FROM OXIDIZERS & IN ACCORDANCE
W/ANSI/NFPA 30.
Other Precautions:EMPTY CONTAINERS MAY CONTAIN HAZARDOUS LIQUID OR
SOLID RESIDUES. DON'T FLAME-CUT/WELD/PUNCTURE. AVOID SKIN CONTACT.
WASH CONTAMINATED CLOTHING BEFORE REUSE. DON'T WEAR CONTACT LENSES.

Respiratory Protection:USE MSHA/NIOSH APPROVED RESPIRATOR
Ventilation:GENERAL OR LOCAL EXHAUST TO KEEP Protective Gloves:PERMEATION RESISTANT ELASTOMERIC
Eye Protection:CHEMICAL SPLASH GOGGLES
Other Protective Equipment:COVERALLS, LONG-SLEEVED SHIRT, LONG PANTS,
ELASTOMERIC BOOTS OR OVERSHOE.
Work Hygienic Practices:WASH HANDS W/SOAP/WATER AFTER HANDLING & BEFORE
EATING/SMOKING. SHOWER AT THE END OF WORK SHIFT.
Supplemental Safety and Health
BOILING RANGE: 302-999F. OBSERVE MSDS & LABEL PRECAUTION UNTIL
CONTAINERS ARE RECONDITIONED.

Boiling Pt:B.P. Text:SEE SUP
Vapor Pres: 2
Vapor Density:1.0
Spec Gravity:1-1.2
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK, SEMI-SOLID PASTE, HYDROCARBON ODOR
Percent Volatiles by Volume: 25%

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, LIQUID CHLORINE, SODIUM, POTASSIUM HYPOCHLORITE,
NITRIC ACID, & PEROXIDES.
Hazardous Decomposition Products:OXIDES OF NITROGEN, CARBON, & SULFUR

Waste Disposal Methods:INCINERATE AT A PERMITTED FACILITY IN ACCORDANCE
W/LOCAL, STATE & FEDERL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.