BNYZV - TRICHLOROETHYLENE

Product Identification

Product ID:TRICHLOROETHYLENE
MSDS Date:11/13/1985
FSC:6810
NIIN:00F025053
MSDS Number: BNYZV

Responsible Party
FISHER SCIENTIFIC CHEMICAL DIV
1 REAGENT LN
FAIR LAWN, NJ 07410-2802
US

Emergency Phone: (201) 796-7100

Info Phone: (201) 796-7100

Preparer: GASTON L PILLORI

Cage: 1B464

Contractor
FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

Ingredients

TRICHLOROETHYLENE, TCE, TRICHLOROETHENE (SUSPECTED HUMAN

CAS: 79-01-6

RTECS: KX4550000

Fraction By Weight: >99%

OSHA PEL 100 PPM/100 STEL

ACGIH TLV: 50 PPM/100,A5STEL;93

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS


ANTIOXIDANT

Fraction By Weight: <1%

Hazards

LD50 LC50 Mixture:ORAL (RAT) LD50: 4920 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: IMMEDIATELY DANGEROUS TO
LIFE'S HEALTH. ADDICTION, IRRITATION, NARCOTIC, COMA. SKIN:
IRRITATION, TOXIC ABSORPTION UNLIKELY & CAUSES CNS DEPRESSION
W/SYMPTOMS OF INHALATION. EYES: IRRITATIO N, PAIN, LACRIMATION.
INGESTION: DIARRHEA, INEBRIATION, COLLAPSE, COMA, DEATH.
Explanation of Carcinogenicity:TRICHLOROETHYLENE IS A SUSPECTED HUMAN
CARCINOGEN BY ACGIH.
Effects of Overexposure:INHALATION: DRUNKENNESS, ANORIXIA, LOSS OF
SENSE OF SMELL & TASTE. DOUBLE VISION, BLINDNESS, MUSCLE PAIN.
LIVER/KIDNEY, LUNG & BRAIN DAMAGE. SKIN: DERMATITIS & VESICULATION.
HARMFUL ABSORPTION. EYES: OPTIC NEURITIS; CHANGE IN VISION,
COLORPERCEPTION & BLINDNESS. INGESTION:
DIARRHEA/INEBRIATION/COLLAPSE/COMA/DEATH.

First Aid

First Aid:INHALATION: REMOVE TO FRESH AIR. ADMINISTER ARTIFICIAL
RESPIRATION IF NOT BREATHING. KEEP PERSON WARM & AT REST. SKIN:
WASH W/SOAP OR MILD DETERGENT OR WASH W/PLENTY OF WATER FOR 15-20
MINS. EYES: WAS H W/PLENTY OF WATER FOR 15-20 MIN. INGESTION: IF
CONSCIOUS INDUCE VOMITING. MAINTAIN BLOOD PRESSURE & AIRWAY. DON'T
GIVE STIMULANTS. OBTAIN MEDICAL ATTENTION IN ALL CASES. NO SPECIFIC
ANTIDOTE.

Fire Fighting

Flash Point Method:CC
Flash Point:90F
Lower Limits:8%
Upper Limits:10.5%
Extinguishing Media:DRY CHEMICAL, CO2, WATER SPRAY, FOG OR ALCOHOL
FOAM.
Fire Fighting Procedures:STAY AWAY FROM STORAGE TANK ENDS. COOL
CONTAINERS EXPOSED TO FLAMES W/WATER FROM SIDE UNTIL WELL AFTER
FIRE IS OUT. KEEP UPWIND.
Unusual Fire/Explosion Hazard:LOW FIRE & NEGLIGIBLE EXPLOSION HAZARD
WHEN EXPOSED TO HEAT OR FLAME. HIGH CONCENTRATIONS OF VAPOR CAN BE
MADE TO BURN IF EXPOSED TO A STRONG SOURCE OF IGNITION

Accidental Release

Spill Release Procedures:SHUT OFF IGNITION SOURCES. STOP LEAK IF YOU
CAN DO IT W/OUT RISK. TAKE UP W/SAND, EARTH OR OTHER ABSORBENT
MATERIAL. DIKE FOR LATER DISPOSAL. KEEP UNNECCESSARY PEOPLE AWAY.

Handling

Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED
LOCATION, AWAY FROM ANY AREA WHERE THE FIRE HAZARD MAY BE ACUTE.
Other Precautions:AVOID CONTACT S/SKIN, EYES, & BREATHING OF VAPORS.

Exposure Controls

Respiratory Protection:500 PPM- CHEMICAL CARTRIDGE RESPIRATOR W/AN
ORGANIC VAPOR CARTRIDGE/SUPPLIED-AIR RESPIRATOR/SCBA/1000
PPM-CHEMICAL CARTRIDGE RESPIRATOR W/ORGANIC VAPOR CARTRIDGE W/FULL
FACE PIECE/GAS MASK W/ORGANIC V APOR CANISTER/SCBA.
Ventilation:LOCAL EXHAUST OR GENERAL DILUTION
Protective Gloves:REQUIRED
Eye Protection:SPLASH-PROOF/DUST GOGGLES/FACESHIELD
Other Protective Equipment:EYE-WASH FOUNTAIN & PROTECTIVE
CLOTHING/EQUIPMENT.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
AUTOIGNITION TEMP: 770F. DECOMPOSITION PRODUCTS: PHOSGENE, HYDROGEN
CHLORIDE, DICHLOROACETYL CHLORIDE, CHLORINE. >1292F:
DICHLORETHYLENE, TETRACHLOROETHYLENE, CARBON TETRACHLORIDE,
CHLOROFORM, METHYL CHLORIDE.

Chemical Properties

Boiling Pt:B.P. Text:188F
Melt/Freeze Pt:M.P/F.P Text:-99F
Vapor Pres:58
Vapor Density:4.5
Spec Gravity:1.5
Evaporation Rate & Reference:0.69
Solubility in Water:0.1%
Appearance and Odor:COLORLESS, HEAVY, MOBILE LIQUID W/MILD CHLOROFORM
LIKE ODOR.

Stability

Stability Indicator/Materials to Avoid:YES
OXYGEN, ACIDS, METALS, & BASES
Stability Condition to Avoid:HEAT, FLAME & OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:SEE SUPP
Conditions to Avoid Polymerization:WHEN CATALYED BY ALUMINUM CHLORIDE
IN A SELF-SUSTAINING REACTION WHICH MAY DEVELOP IN TEMPS UP TO
2462F.

Disposal

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.