Product ID:4803, ACETIC ACID GLACIAL
MSDS Date:04/19/1990
FSC:6810
NIIN:00N030148
MSDS Number: BPDRR

J T BAKER INC

222 RED SCHOOL LANE
PHILLIPSBURG, NJ 08865-2219
US

Emergency Phone: 908-859-2151;800-424-9300(CHEMTREC)

Info Phone: 800-582-2537

Cage: DO803

MALLINCKRODT BAKER, INC.

PHILLIPSBURG, NJ 08865 US

Telephone: 800-582-2537

Cage: 70829

ACETIC ACID;(ACETIC ACID, GLACIAL) (SARA III)

CAS: 64-19-7

RTECS: AF1225000

Fraction By Weight: 90-100%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM;15 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

NOT ALLOW TO ENTER DRAINS OR SEWER SYSTEM.

RTECS: 9999999ZZ

2.4 (1.0 M SOLUTION)

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL RAT) 3310 MG/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:SEVERE IRRITATION OR BURNS OF
RESPIRATORY SYSTEM, PULMONARY EDEMA, LUNG INFLAMMATION, HEADACHE,
COUGHING, DIFFICULT BREATHING, DIZZINESS, CHEST PAINS, TEETH
DAMAGE, RESPIRATORY FAILURE. SKIN:SEV ERE BURNS, MAY CAUSE
DERMATITIS. EYE:SEVERE BURNS, PERMANENT EYE DAMAGE. INGEST:BURNS TO
MOUTH & THROAT(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:NAUSEA, VOMITING, GASTROINTESTINAL
IRRITATION, DIARRHEA, SHOCK, MAY BE FATAL. CHRONIC:LUNG DAMAGE,
TEETH DAMAGE. TARGET ORGANS:RESPIRATORY SYSTEM, EYES, SKIN, TEETH,
LUNGS.
Medical Cond Aggravated by Exposure:RESPIRATORY SYSTEM DISEASE, SKIN
DISORDERS.

First Aid:INGEST:CALL MD. DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE
WATER, MILK, OR MILK OF MAGNESIA. INHAL:MOVE TO FRESH AIR. IF NOT
BREATHING, GIVE ARTF RESP. IF BREATHING DIFFICULT, GIVE OXYGEN.
SKIN:IMMEDI ATELY FLUSH WITH PLENTY OF WATER FOR ATLEAST 15 MINUTES
WHILE REMOVING CONTAMINATED CLOTHING & SHOES. WASH CLOTHING BEFORE
REUSE. EYE: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES.

Flash Point Method:CC
Flash Point:103F,39C
Lower Limits:4%
Upper Limits:19.9%
Extinguishing Media:WATER SPRAY, ALCOHOL FOAM, DRY CHEMICAL OR CARBON
DIOXIDE, CLASS B EXTINGUISHER.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROT
EQUIPMENT . MOVE CNTNRS FROM FIRE AREA IF IT CAN BE DONE W/OUT
RISK. USE WATER TO KEEP FIRE-EXPOSED CNTNRS COOL.
Unusual Fire/Explosion Hazard:VAPS MAY FLOW ALONG SURFS TO DISTANT
IGNIT SOURCES & FLASH BACK. CLSD CNTNRS EXPOSED TO HEAT MAY
EXPLODE. CNTCT W/ STRONG OXIDIZERS MAY CAUSE FIRE. (SUPP DATA)

Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT CLTHG.
SHUT OFF IGNIT SOURCES; NO FLARES, SMKNG OR FLAMES IN AREA. STOP
LEAK IF YOU CAN DO SO W/OUT RISK. NEUTRALIZE SPILL W/SODA ASH OR
LIME. WITH CLEAN SHOVEL , CAREFULLY PLACE MATL INTO CLEAN, DRY
(SUPP DATA)
Neutralizing Agent:SODA ASH OR LIME; JT BAKER NEUTRASORB OR TEAM "LOW
NA+" ACID NEUTRALIZERS.

Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLOSED. STORE IN A
COOL, DRY, WELL-VENT FLAMM LIQUID STORAGE AREA OR CABINET. STORE
ABOVE 17C. KEEP AWAY FROM HEAT, SPARKS, FLAME.
Other Precautions:KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE
VENTILATION. HARMFUL IF SWALLOWED OR INHALED. AVOID BREATHING
VAPOR. DO NOT GET IN EYES, ON SKIN OR CLOTHING. KEEP OUT OF REACH
OF CHILDREN.

Respiratory Protection:ALL RESPIRATORS MUST BE NIOSH/MSHA APPROVED.
RESP PROT REQ IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT
CONCENTRATIONS UP TO 500 PPM, A CHEMICAL CARTRIDGE RESPIRATOR
W/ACID/ORGANIC CARTRIDGE IS RECOMMEND ED. ABOVE THIS LEVEL, A SCBA
IS ADVISED.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS. VENT HOOD.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:CHEM WORK GOGG & FULL LGTH FSHLD
Other Protective Equipment:UNIFORM & PROTECTIVE SUIT. LAB COAT & APRON.
EMERGENCY EYEWASH, DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXPLO HAZ:REACTS WITH MOST METALS TO PRODUCE HYDROGEN GAS, WHICH CAN
FORM AN EXPLOSIVE MIXTURE WITH AIR. MATLS TO AVOID: HYDROGEN
PEROXIDE, ALKALIES, CARBONATES, STRONG BASES, AMINES, PHOSPHOROUS
TRIC HLORIDE, PHOSPHORUS PENTACHLORIDE. SPILL PROC:CNTNR & COVER.
REMOVE FROM SPILL AREA. FLUSH SPILL AREA W/WATER. DO (ING 2

HCC:F6
Boiling Pt:B.P. Text:244F,118C
Melt/Freeze Pt:M.P/F.P Text:62.6F,17.0C
Vapor Pres:11 @ 20C
Vapor Density:2.1
Spec Gravity:1.05 (H2O=1)
pH:ING 3
Evaporation Rate & Reference:0.97 (BUTYL ACETATE=1)
Solubility in Water:COMPLETE (100%)
Appearance and Odor:COLORLESS LIQUID WITH VINEGAR LIKE ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, MOST COMMON METALS (EXCEPT ALUMINUM), CHROMIC
ACID, NITRIC ACID, SULFURIC ACID, (SUPP DATA)
Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:CO, CO2.

Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZ WASTE
NO:D001, D002 (IGNITABLE, CORROSIVE WASTE).

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.