Product ID:9501, ACETIC ACID GLACIAL
MSDS Date:04/19/1990
FSC:6810
NIIN:00N030160
MSDS Number: BPDSG

J T BAKER INC

222 RED SCHOOL LANE
PHILLIPSBURG, NJ 08865-2219
US

Emergency Phone: 908-859-2151;800-424-9300(CHEMTREC)

Info Phone: 800-582-2537

Cage: DO803

MALLINCKRODT BAKER, INC.

PHILLIPSBURG, NJ 08865 US

Telephone: 800-582-2537

Cage: 70829

ACETIC ACID; (ACETIC ACID, GLACIAL)

CAS: 64-19-7

RTECS: AF1225000

Fraction By Weight: 90-100%

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM;15 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:LD50:(ORAL,RAT)3310 MG/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:SEVERE IRRIT/BURNS OF
RESPIRATORY SYSTEM, PULMONARY EDEMA, LUNG INFLAMMATION, HEADACHE,
COUGHING, DIFFICULT BREATHING, DIZZINESS, CHEST PAINS, TEETH
DAMAGE, RESPIRATORY FAILURE. SKIN:SEVER E BURNS, MAY CAUSE
DERMATITIS. EYE:SEVERE BURNS, PERMANENT DAMAGE. INGEST:BURNS TO
MOUTH & THROAT, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:EFTS OF OVEREXP:NAUSEA, VOMITING, GI IRRIT,
DIARRHEA, SHOCK, MAY BE FATAL. TARGET ORGANS:RESPIRATORY SYSTEM,
EYES, SKIN, TEETH, LUNGS. CHRONIC:LUNG DAMAGE, TEETH DAMAGE.
Medical Cond Aggravated by Exposure:RESPIRATORY SYSTEM DISEASE, SKIN
DISORDERS.

First Aid:INGEST:CALL MD. DO NOT INDUCE VOMIT. IF CONSCIOUS, GIVE
WATER, MILK OR MILK OF MAGNESIA. INHAL:REMOVE TO FRESH AIR. IF NOT
BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE O2. SKIN:IMMED FLUSH
W/PLENTY OF WATER FOR @ LST 15 MIN WHILE REMOVING CONTAM CLTHG &
SHOES. WASH CLTHG BEFORE RE-USE. EYE:IMMED FLUSH W/PLENTY OF WATER
FOR @ LST 15 MIN.

Flash Point Method:CC
Flash Point:103F,39C
Lower Limits:4%
Upper Limits:19.9%
Extinguishing Media:USE WATER SPRAY, ALCOHOL FOAM, DRY CHEMICAL OR CO2.
USE CLASS B EXTINGUISHER.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. MOVE CNTNRS FROM FIRE AREA IF IT CAN BE DONE W/OUT RISK. USE
WATER TO KEEP FIRE-EXPOSED CNTNRS COOL.
Unusual Fire/Explosion Hazard:VAPS MAY FLOW ALONG SURFS TO DIST IGNIT
SOURCES & FLASH BACK. CLSD CNTNRS EXPOSED TO HEAT MAY EXPLODE. CONT
W/ STRONG OXIDIZERS MAY CAUSE FIRE. REACTS (SUPDAT)

Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT CLTHG.
SHUT OFF IGNIT SOURCES; NO FLARES/SMOKING/FLAMES IN AREA. STOP LEAK
IF YOU CAN DO SO W/OUT RISK. NEUT SPILL W/SODA ASH/LIME. WITH CLEAN
SHOVEL, CAREFULLY PLACE MATL INTO CLEAN, DRY CNTNR &
COVER.(SUPDAT)
Neutralizing Agent:J.T.BAKER NEUTRASORB(R)/TEAM(R)'LOW NA+' ACID NEUTS
ARE FOR SPILLS OF THIS PROD.

Handling and Storage Precautions:COMBUSTIBLE! FLAMMABLE! KEEP CNTNR
TIGHTLY CLSD. STORE IN COOL, DRY, WELL-VENTED, FLAMM LIQ STOR
AREA/CABINET. STORE >17C.
Other Precautions:KEEP AWAY FROM HEAT, SPKS, FLAME. DO NOT GET IN EYES,
ON SKIN, ON CLTHG. AVOID BRTHG VAPOR. USE W/ADEQ VENT. KEEP OUT OF
REACH OF CHILDREN.

Respiratory Protection:RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
CONCS EXCEEDS TLV. AT CONCS UP TO 500 PPM, A NIOSH/MSHA APPRVD CHEM
CARTRIDGE RESP W/ACID/ORGANIC CARTRIDGE IS RECOMMENDED. ABOVE THIS
LEVEL, A NIOSH/ MSHA APPROVED SCBA IS ADVISED.
Ventilation:USE GENERAL/LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS. VENT HOOD.
Protective Gloves:NEOPRENE GLOVES.
Eye Protection:CHEM WORK GOGG & FULL LGTH FCSHLD.
Other Protective Equipment:UNIFORM, PROTECTIVE SUIT. LAB COAT & APRON.
EMERGENCY EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PH:2.4(1M SOLN).% VOLAT:[email protected] HAZ:W/ MOST METALS TO PRDCE
HYDROGEN GAS, WHICH CAN FORM EXPLO MIXT W/AIR.MATLS TO
AVOID:PEROXIDE, ALKALIES, CARBONATES, STRONG BASES, AMINES,
PHOSPHORUS TRICHLOR IDE, PHOSPHORUS PENTACHLORIDE.SPILL PROC:REMOVE
FROM SPILL AREA. FLUSH AREA W/H2O.DO NOT ALLOW TO ENTER DRAIN/SEWER
SYS

HCC:F6
Boiling Pt:B.P. Text:244F,118C
Melt/Freeze Pt:M.P/F.P Text:62.6F,17.0C
Vapor Pres:11 @ 20C
Vapor Density:2.1
Spec Gravity:1.05 (H2O=1)
pH:SUPDAT
Evaporation Rate & Reference:0.97 (BUTYL ACETATE=1)
Solubility in Water:COMPLETE (100%)
Appearance and Odor:COLORLESS LIQUID. VINEGAR-LIKE ODOR.
Percent Volatiles by Volume:SUPDAT

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, MOST COMMON METALS(EXCEPT ALUMINUM), CHROMIC
ACID, NITRIC ACID, SULFURIC ACID, HYDROGEN(SUPDAT)
Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:CO, CO2.

Waste Disposal Methods:DISPOSE OF I/A/W ALL APPLICABLE FEDERAL, STATE &
LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER:D001,
D002 (IGNITABLE, CORROSIVE WASTE).

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particular situation.