Product ID:JP-4
MSDS Date:04/16/1992
FSC:9130
NIIN:00-273-2380
MSDS Number: BPDZZ

SHELL CHEMICAL COMPANY A DIV. OF SHELL OIL CO.

1 SHELL PLAZA
HOUSTON, TX 77001
US

Emergency Phone: 713-473-9461

Info Phone: 713-241-4819

Cage: 86961

SHELL OIL CO

2463 HOUSTON, TX 77001 US

Telephone: 713-473-9461/800-424-9300(CHEMTREC)

Cage: 93508

HYDROTREATED HEAVY NAPHTHA

CAS: 64742-48-9

Fraction By Weight: 88 - 95%

NAPHTHA (PETROLEUM), LIGHT STRAIGHT RUN

CAS: 64741-46-4

RTECS: QK8000300

Fraction By Weight: 5 - 12%

MINOR ADDITIVES

Fraction By Weight: < 0.5%

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: < 2.5%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE- HIGH VAPOR CONCENTRATIONS ARE
IRRITATING TO THE EYES & RESPIRATORY SYSTEM. MAY CAUSE HEADACHE,
DIZZINESS, ANESTHESIA, DROWSINESS, UNCONSCIOUSNESS & DEATH.
PROLONGED/REPEATED SKIN CONTACT LEADS TO IRRITATION & DERMATITIS.
LIQUID CAN IRRITATE EYES. CHRONIC- MAY CAUSE DERMATITIS, CANCER,
LIVER & KIDNEY DAMAGE.
Explanation of Carcinogenicity:THIS PRODUCT CONTAINS BENZENE, A
CARCINOGEN ALSO LINKED TO BLOOD, KIDNEY, AND NERVOUS SYSTEM
DISORDERS.
Effects of Overexposure:HIGH VAPOR CONCENTRATIONS ARE IRRITATING TO THE
EYES & RESPIRATORY SYSTEM. MAY CAUSE HEADACHE, DIZZINESS,
ANESTHESIA, DROWSINESS, UNCONSCIOUSNESS & DEATH. PROLONGED/REPEATED
SKIN CONTACT LEADS TO IRRI TATION & DERMATITIS. LIQUID CAN IRRITATE
EYES.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS OR IMPAIRED LIVER, KIDNEY OR RESPIRATORY FUNCTION MAY BE
MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.

First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN:WASH WITH
SOAP & WATER. EYE:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS
OPEN. INHALED:REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED.
ORAL:DO N OT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION. IF
CONSCIOUS, DRINK WATER TO DILUTE.

Flash Point:-10F,-23C
Lower Limits:1.3 %
Upper Limits:8 %
Extinguishing Media:WATER SPRAY, CO2, FOAM/DRY CHEMICAL. WATER SPRAY
MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL & FLUSH SPILLS
AWAY.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:EVACUATE A RADIUS OF 1500 FEET FOR
UNCONTROLLED FIRE. VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL TO A
FLAME & FLASH BACK. EXTINGUISH ONLY IF FLOW CAN BE STOPPED.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENTS. SHUT OFF & REMOVE
IGNITION SOURCES. VENTILATE AREA. RECOVER FREE PRODUCT. ADD SAND,
EARTH/OTHER SUITABLE ABSORBENT AND REMOVE FOR DISPOSAL. KEEP
PRODUCT OUT OF SEWERS AND W ATERCOURSES. ADVISE AUTHORITIES IF
ENTERED SEWERS.

Handling and Storage Precautions:STORAGE- STORE IN COOL, VENTILATED
AREA, IN TIGHTLY CLOSED CONTAINERS, AWAY FROM HEAT, FLAMES &
OXIDIZERS.
Other Precautions:AVOID BREATHING OF VAPORS. EMPTY CONTAINERS RETAIN
RESIDUE (LIQUID AND/OR VAPOR) AND CAN BE DANGEROUS. DO NOT
PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH
CONTAINERS TO HEAT, FLAM E, SPARKS -- THEY MAY EXPLODE.

Respiratory Protection:WEAR A NIOSH-APPROVED ORGANIC RESPIRATOR IF
VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL/TLV.
WEAR SELF-CONTAINED BREATHING APPARATUS IF REQUIRED FOR HIGH LEVELS
OF CONTAMINATES.
Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:NEOPRENE OR NATURAL RUBBER GLOVES
Eye Protection:SPLASH GOGGLES OR FACE SHIELD
Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND
IMPERVIOUS CLOTHING
Work Hygienic Practices:USE WITH ADEQUATE VENTILATION. AVOID BREATHING
MIST. AVOID CONTACT WITH SKIN & EYES. WASH HANDS AFTER USE.
Supplemental Safety and Health

HCC:F2
Boiling Pt:B.P. Text:>100F,>38C
Melt/Freeze Pt:M.P/F.P Text:-72F,-58C
Vapor Pres:724
Vapor Density:3.5
Spec Gravity:0.7796
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR AND BRIGHT LIQUID-HYDROCARBON ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, PILOT LIGHTS,
STATIC ELECTRICITY, AND OPEN FLAMES
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE

Waste Disposal Methods:INCINERATE IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.