Product ID:CHLOROBENZENE
MSDS Date:05/04/1988
FSC:6810
NIIN:00-264-9000
MSDS Number: BPFTP

J.T. BAKER CHEMICAL CO

222 RED SCHOOL LN
PHILLIPSBURG, NJ 08865-2219
US

Emergency Phone: 201-859-2151

Info Phone: 201-859-2151

Cage: 5B970

MALLINCKRODT BAKER, INC.

PHILLIPSBURG, NJ 08865 US

Telephone: 800-582-2537

Cage: 70829

CHLOROBENZENE (SARA III)

CAS: 108-90-7

RTECS: CZ0175000

Fraction By Weight: 90-100%

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM; 9192

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

LD50 LC50 Mixture:LD50, (ORAL) RATS - 2910 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: MAY CAUSE HEADACHE,
NAUSEA, VOMITING, DIZZINESS, DROWSINESS, IRRITATION OF RESPIRATORY
TRACT, LOSS OF CONSCIOUSNESS. EYE CONTACT: MAY CAUSE SEVERE
IRRITATION OR BURNS. SKIN CONTACT: MAY CA USE SEVERE IRRITATION OR
BURNS. INGESTION: MAY CAUSE NAUSEA, VOMITING, HEADACHES, DIZZINESS,
GASTROINTESTINAL IRRITATION
Effects of Overexposure:MAY INCLUDE DAMAGE TO KIDNEYS, LIVER, LUNGS,
BLOOD, OR CENTRAL NERVOUS SYSTEM. PROLONGED SKIN CONTACT MAY CAUSE
DERMATITIS.
Medical Cond Aggravated by Exposure:NONE IDENTIFIED

First Aid:INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. CALL A PHYSICIAN. EYE CONTACT: FLUSH EYES WITH PLENTY
OF WATER FOR 15 MINUTES. CALL A PHYSICIAN. SKIN CONTACT: FLUSH SKIN
WITH PLENTY OF WATER FOR 15 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES. CALL A PHYSICIAN. INGESTION: DO NOT INDUCE
VOMITING. IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. CALL A
PHYSICIAN.

Flash Point Method:CC
Flash Point:29C (84F)
Autoignition Temp:Autoignition Temp Text:638C
Lower Limits:1.3
Upper Limits:7.1
Extinguishing Media:DRY CHEMICAL, ALCOHOL FOAM OR CARBON DIOXIDE.
(WATER MAY BE INEFFECTIVE)
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE
EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:VAPORS MAY FLOW ALONG SURFACES TO DISTANT
IGNITION SOURCES AND FLASH BACK. CLOSED CONTAINERS EXPOSED TO HEAT
MAY EXPLODE.

Spill Release Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES,
SMOKING OR FLAMES IN AREA. STOP LEAK IF IT CAN BE DONE WITHOUT
RISK. USE WATER SPRAY TO REDU CE VAPOR. REPORTABLE QUANTITY-
100LBS.

Handling and Storage Precautions:BOND AND GROUND CONTAINERS WHEN
TRANSFERRING LIQUID. KEEP CONTAINER TIGHTLY CLOSED. STORE IN A
COOL, DRY, WELL-VENTILATED, FLAMMABLE LIQUID STORAGE.
Other Precautions:WASH THOROUGHLY AFTER HANDLING.AVOID SKIN,EYES &
CLOTHING CONTACT. NO SMOKING IN THE AREA.

Respiratory Protection:RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
CONCENTRATION EXCEED TLV. AT CONCENTRATIONS UP TO 1000 PPM, A
CHEMICAL CARTRIDGE RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE IS
RECOMMENDED. ABOVE THIS LEVEL, S CBA IS RECOMMENDED.
Ventilation:GENERAL OR LOCAL EXHAUST VENTILATION.
Protective Gloves:VITON GLOVES
Eye Protection:GOGGLES/FACE SHIELD
Other Protective Equipment:FULL PROTECTIVE CLOTHING,SAFETY SHOWER,EYE
WASH STATION
Work Hygienic Practices:WASH CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
REPORTABLE QUANTITY IS 100LBS.

HCC:F3
Boiling Pt:B.P. Text:132C(270F)
Melt/Freeze Pt:M.P/F.P Text:-49F,-45C
Vapor Pres:11.8
Vapor Density:3.9
Spec Gravity:1.11
Evaporation Rate & Reference:1.07 (BU-AC=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR COLORLESS LIQUIDWITH SWEET ALMOND LIKE ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, FLAME, AND OTHER SOURCES OF
IGNITION.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE, CARBON
MONOXIDE, CARBON DIOXIDE

Waste Disposal Methods:CONSULT YOUR LOCAL ENVIRONMENTAL OFFICER.
DISPOSE IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.