Product ID:#336 DUNCAN LIGHT ALMOND AEROSOL SPRAY PAIN
MSDS Date:08/01/1987
FSC:8010
NIIN:00N030922
MSDS Number: BPGVZ

DUNCAN ENTERPRISES

5673 E SHIELDS AVE
FRESNO, CA 93727
US

Emergency Phone: 203-623-4884

Info Phone: 209-291-4444

Cage: 21546

DUNCAN ENTERPRISES

FRESNO, CA 93727 US

Telephone: 209-291-4444

Cage: 21546

2-PENTANONE, 4-HYDROXY-4-METHYL-; (DIACETONE ALCOHOL); VP

CAS: 123-42-2

RTECS: SA9100000

Fraction By Weight: 0-5%

OSHA PEL 50 PPM

ACGIH TLV: 50 PPM

12.8 @

CAS: 110-19-0

RTECS: AI4025000

Fraction By Weight: 5-10%

OSHA PEL 150 PPM

ACGIH TLV: 150 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

70 @ 20C.

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 0-5%

OSHA PEL 200 PPM;300 PPM STEL

ACGIH TLV: 200 PPM;300 PPM STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (GLYCOL ETHER

CAS: 108-65-6

RTECS: AI8295000

Fraction By Weight: 0-5%

69 @ 20C.

CAS: 141-78-6

RTECS: AH5425000

Fraction By Weight: 5-10%

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

186 @ 20C.

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 40-45%

OSHA PEL 1000PPM

ACGIH TLV: 750PPM/1000STEL;9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PROPELLANT CONSISTING OF INGREDIENTS 8-11

RTECS: 9999999ZZ

Fraction By Weight: 19%

PROPANE

CAS: 74-98-6

RTECS: TX2275000

OSHA PEL 1000 PPM

ACGIH TLV: SIMPLE ASPHYXIANT

PROPANE, 2-METHYL-; (ISOBUTANE MIXTURE)

CAS: 75-28-5

RTECS: TZ4300000

BUTANE; (N-BUTANE)

CAS: 106-97-8

RTECS: EJ4200000

OSHA PEL 800 PPM

ACGIH TLV: 800 PPM

NON HAZARDOUS INGREDIENTS

SOURCES AT LOCATIONS DISTANT FROM MATERIAL

RTECS: 9999999ZZ

CLEANERS, AND WASH CLOTHING BEFORE REUSE.

RTECS: 9999999ZZ

PROT (NIOSH/MSHA) TC23C/EQUIVALENT), OR LEAVE

RTECS: 9999999ZZ

HARMFUL WHEN HIGH CONCENTRATIONS OF SOLVENT VAPOR

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: EXCESSIVE INHAL OF VAPS
CAN CAUSE NASAL & RESP IRRIT, DIZZ, WEAKNESS, FATIGUE, NAUS, HDCH,
POSS UNCON & EVEN ASPHYXIATION. EYE: CAN CAUSE SEV IRRIT, REDNESS,
TEARING, BLURRED VISION. ING EST: CAN CAUSE GI IRRIT, NAUS, VOMIT,
DIARRHEA. SKIN: CAN CAUSE IRRIT FOR SOME PERSONS. (EFTS OF
OVEREXPOS)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: CHRONIC: REPORTS HAVE ASSOCD RPTD &
PRLNGD OCCUP OVEREXPOS TO SOLVENTS W/PERMANENT BRAIN & NERVS SYS
DAM. SEV OVEREXPOS IN LAB ANIMALS HAS ALSO CAUSED LIVER
ABNORMALITIES & DAM TO KIDNEYS, L UNGS, & SPLEEN. INTENTIONAL
MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY
BE HARMFUL OR FATAL.
Medical Cond Aggravated by Exposure:CAN CAUSE ALLERGIC RESPIRATORY
AND/OR SKIN REACTIONS.

First Aid:INHAL:REMOVE TO FRESH AIR.IF BRTHG IS DFCLT, ADMINISTER O2.IF
BRTHG IS STOPPED, GIVE ARTF RESP & SEEK MD HELP. EYE: FLUSH W/WATER
FOR @ LST 15 MIN WHILE OCCASIONALLY HOLDING LIDS OPEN.GET MD
ATTN.INGE ST:DO NOT INDUCE VOMIT (ASPIR OF MATL INTO LUNGS CAN
CAUSE CHEM PNEUMONITIS, WHICH CAN BE FATAL).KEEP PERS WARM, QUIET &
GET MD ATTN/POIS CTL CTR. SKIN: WASH W/SOAP & WATER/VARIOUS HAND
(ING 13)

Flash Point:SUPP DATA
Lower Limits:1%
Extinguishing Media:"ALCOHOL" FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. WATER SPRAY MAY BE INEFTIVE. WATER MAY BE USED TO COOL CLSD
CNTNRS TO PVNT PRESS BUILD-UP & (SUPP DATA)
Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLODE &/AUTOIGNITE WHEN
EXPOS TO EXTREME HEAT. VAPS ARE HVR THAN AIR & MAY TRAVEL ALONG
GROUND/MAY BE MOVED BY VENT & IGNITED BY (SUPP DATA)

Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. VENTILATE
AREA, ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBENT, OR
OTHER ABSORBENT MATERIAL AND TRANSFER TO A CLOSED CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE IN AREAS ABOVE 120F OR IN
DIRECT SUNLIGHT OR NEAR HEAT OR OPEN FLAMES. DO NOT PUNCTURE OR
INCINERATE.
Other Precautions:STORE LARGE QUANTITIES IN BUILDINGS PROTECTED FOR
STORAGE OF NPFA CLASS 1C FLAMMABLE LIQUIDS.

Respiratory Protection:FOR CASUAL/OCCASIONAL USE - TO AVOID BRTHG VAPS/
SPRAY MIST, OPEN WINDOWS & DOORS/USE OTHER MEANS TO ENSURE FRESH
AIR ENTRY DURING APPLICATION & DRYING. IF YOU EXPERIENCE EYE
WATERING, HDCHS/DIZZ, INC REASE FRESH AIR. WEAR RESP (ING 14)
Ventilation:FOR REGULAR/CONTINUOUS USE - PROVIDE SUFFICIENT MECH (GEN)
&/ LOCAL EXHAUST VENT TO MAINTAIN EXPOSURE BELOW TLV'S.
Protective Gloves:CHEM RESISTANT GLOVES, SUCH AS NEOPRENE.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:WHERE SPECIAL OR UNUSUAL CONDITIONS EXIST,
THE EXPERT ASSISTANCE OF AN INDUSTRIAL HYGIENIST SHOULD BE SOUGHT.
Work Hygienic Practices:WASH HANDS BEFORE EATING OR USING WASHROOM. AS
WITH ALL CHEMICALS, MINIMIZE PERSONAL CONTACT & BREATHING VAPORS.
Supplemental Safety and Health
EVAP RATE: PRODUCTS >1, PROPELLANT <1 (BUTYL ACETATE=1). FL PT:
0F(-18C) (PROPELLANT APPROX -100F). FIRE FIGHT PROC: POSS
AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED, FOG
NOZ ARE PR EF. EXPLO HAZ: PILOT LIGHTS, OTHER FLAMES, SPKS,
HEATERS, SMOKING ELEC MOTORS/OTHER INGIT (ING 12)

HCC:V3
Boiling Pt:B.P. Text:>133F,>56C
Melt/Freeze Pt:M.P/F.P Text:1500F,816C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:<1 (H2O=1)
Evaporation Rate & Reference:SUPP DATA
Solubility in Water:SLIGHT TO MODERATE
Appearance and Odor:TYPICAL SOLVENT PAINT
Percent Volatiles by Volume:85-90

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS AND HEAT.
Stability Condition to Avoid:HEAT, SPARKS, AND OPEN FLAME.
Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS, CO/CO2,
VARIOUS HYDROCARBONS, NITROGEN COMPOUNDS, ETC., WHEN BURNED.

Waste Disposal Methods:MATERIAL COLLECTED ON ABSORBENT MATERIAL MAY BE
DEPOSITED IN A POSTED TOXIC SUBSTANCE LANDFILL I/A/W LOCAL, STATE
AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.