Product ID:UNOCAL 76 UNLEADED GASOLINE
MSDS Date:05/04/1990
FSC:9130
NIIN:00-148-7103
MSDS Number: BPPKG

UNION OIL CO OF CALIFORNIA UNOCAL CHEMICALS DIV

1201 W 5TH ST
LOS ANGELES, CA 90060
US

Emergency Phone: 202-483-7616/800-424-9300(CHEMTREC)

Info Phone: 800-356-3129

Cage: 23034

76 PRODUCTS CO

LOS ANGELES, CA 90017 US

Telephone: 213-977-7589

Cage: 23034

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9192

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 1.0-5.0%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 1.0-5.0%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 1.0-9.0%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

HEXANE (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: 1.0- 14%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 1-5%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: 0-10%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 1-5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9192

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE-INHALE:MISTS/VAPORS MAY CAUSE
FLUSHING,NAUSEA,CNS DEPRESSION(E.G.HEADACHE,DIZZINESS,FATIGUE).HIGH
CONCN. MAY CAUSE NARCOSIS,UNCONSCIOUSNESS,COLLAPSE &
DEATH.EYE:IRRITATION,TEARING, STINGING,BLUR RED
VISION.SKIN:IRRITATION,DRYING,CRACKING.ORAL:ASPIRATION HAZARD.MAY
CAUSE CNS DEPRESSION.CHRONIC:DERMATITIS.
Explanation of Carcinogenicity:CONTAINS BENZENE.
Effects of Overexposure:MISTS OR VAPORS MAY CAUSE FLUSHING, NAUSEA, CNS
DEPRESSION (E.G. HEADACHE, DIZZINESS, FATIGUE). HIGH CONCENTRATIONS
MAY CAUSE NARCOSIS, UNCONSCIOUSNESS, COLLAPSE & DEATH. CAN CAUSE
EYE IRRITATION, TEA RING, STINGING, BLURRED VISION. CAN CAUSE SKIN
IRRITATION, DRYING, CRACKING. ORAL: ASPIRATION HAZARD & CNS
EFFECTS.
Medical Cond Aggravated by Exposure:PERSONS WITH A SKIN DISORDER SHOULD
USE CAUTION WHEN HANDLING OR USING THIS PRODUCT.

First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN:WASH WITH
SOAP & WATER.EYE:FLUSH WITH WATER FOR 15 MINUTES,HOLDING EYELIDS
OPEN.INHALED:REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED.
ORAL:DO NOT INDUCE VOMITING.IF VICTIM IS DROWSY/UNCONSCIOUS,PLACE
ON THE LEFT SIDE WITH THE HEAD DOWN.CALL PHYSICIAN.

Flash Point Method:TCC
Flash Point:-45F,-43C
Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. WATER
MAY BE INEFFECTIVE BUT SHOULD BE USED TO COOL FIRE-EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-
APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE
OPERATED IN THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL
CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK.
CONTAINERS MAY RUPTURE DUE TO VAPOR PRESSURE BUILDUP.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT.ELIMINATE SOURCES OF
IGNITION.VENTILATE THE AREA.STOP LEAK IF POSSIBLE.CONTAIN THE
SPILL.PICK UP LARGE SPILL WITH NON-SPARKING TOOLS;SMALL SPILLS WITH
ABSORBENT MATERIAL.DO N OT LET LIQUID FROM ENTERING
SEWERS/STORMDRAINS.

Handling and Storage Precautions:STORAGE-OUTDOOR/DETACHED STORAGE IS
PREFERRED.INDOOR STORAGE SHOULD BE IN A STANDARD FLAMMABLE LIQUID
STORAGE ROOM.
Other Precautions:STORE IN APPROVED CONTAINERS.KEEP CONTAINERS TIGHTLY
CLOSED AWAY FROM SUNLIGHT & SOURCES OF IGNITION.BOND & GROUND ALL
EQUIPMENTS WHEN TRANSFERRING FROM ONE VESSEL TO ANOTHER.AVOID
BREATHING VAPORS.DO NOT GET IN EYE,ON SKIN OR CLOTHING.

Respiratory Protection:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS OPERATED IN POSITIVE PRESSURE MODE OR SUPPLIED-AIR
RESPIRATOR WITH FULL FACEPIECE AND OPERATED IN PRESSURE-DEMAND OR
OTHER POSITIVE PRESSURE MODE .
Ventilation:LOCAL AND MECHANICAL EXHAUST RECOMMENDED (EXPLOSION PROOF).
Protective Gloves:NEOPRENE, NITRILE, OR POLYVINYL ALCOHOL
Eye Protection:USE CHEMICAL SAFETY GOGGLES & FACESHIELD
Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND
IMPERVIOUS CLOTHING
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR DRINKING.
Supplemental Safety and Health
"EMPTY" CONTAINERS RETAIN RESIDUE AND CAN BE DANGEROUS.DO NOT
PRESSURIZE,CUT,WELD,BRAZE,SOLDER,DRILL,GRIND OR EXPOSE SUCH
CONTAINERS TO HEAT,FLAME,SPARKS.THEY MAY EXPLODE AND CAUSE INJURY/
DEATH.AVOID REPEATED OR PROLONGED CONTACT WITH SKIN.

HCC:F1
Boiling Pt:B.P. Text:85.0F,29.4C
Vapor Density:>1
Spec Gravity:O.75
Evaporation Rate & Reference:<1 ( BU AC=1 )
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR LIQUID - GASOLINE ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS SUCH AS CHLORINE, PERMANGANATE AND DICHROMATES
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES, SPARKS, STATIC
ELECTRICITY, HOT SURFACES & OTHER SOURCES OF IGNITION
Hazardous Decomposition Products:SIGNIFICANT AMOUNT OF CARBON MONOXIDE
AND SMALL AMOUNT OF OXIDES OF SULFUR AND NITROGEN, BENZENE AND
OTHER ORGANIC CMPD.

Waste Disposal Methods:WASTE MAY BE BURNED IN AN APPROVED INCINERATOR
OR DISPOSED OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND
FEDERAL LAWS AND REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.