Product ID:RES00228FE8912, POLYESTER RESIN DION FR 669
MSDS Date:02/01/1989
FSC:5350
NIIN:00N033301
MSDS Number: BPQFQ

REICHHOLD CHEMICALS INC

8540 BAYCENTER RD
JACKSONVILLE, FL 32256
US

Emergency Phone: 904-739-2170;800-424-9300(CHEMTREC)

Info Phone: 800-523-7934

Preparer: OCCUP HLTH/PROD SFTY DEPT

Cage: 1JM52

REICHHOLD CHEMICALS INC (VDR-CHEM COMMOD AGY,INC)

19129 JACKSONVILLE, FL 32245 US

Telephone: 904-739-2170, CHEMTREC 800-424-9300

Cage: 1JM52

GLOVES POLYVINYL ALCOHOL, POLETHYLENE, OR

RTECS: 9999999ZZ

GARMENTS SUCH AS APRONS, JACKETS, PANTS,

RTECS: 9999999ZZ

ANTICIPATED TO BE A CARCINOGEN (NTP).

RTECS: 9999999ZZ

STYRENE (SARA III)

CAS: 100-42-5

RTECS: WL3675000

Fraction By Weight: <40%

OSHA PEL 100 PPM

ACGIH TLV: S,50PPM/100STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PROPANE, 1-CHLORO-2, 3-EPOXY-; (EPICHLOROHYDRIN) (SARA

CAS: 106-89-8

RTECS: TX4900000

Fraction By Weight: <0.5%

OSHA PEL S, 5 PPM

ACGIH TLV: S, 2 PPM; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

METHANE, DICHLORO-; (METHYLENE CHLORIDE)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: <0.5%

OSHA PEL 500 PPM, C

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

88 G/M2

RTECS: 9999999VO

IN HUMANS ACUTELY OR CHRONICALLY EXPOSED

RTECS: 9999999ZZ

TREATMENT SHOULD BE DIRECTED AT CONTROL OF

RTECS: 9999999ZZ

RESPONSE CNTR (1-800-424-8802). WHEN PRODUCT IS

RTECS: 9999999ZZ

RESIDUE INCL FLAM/EXPLO VAPS. DO NOT CUT,

RTECS: 9999999ZZ

CNTNRS.DO NOT WEAR CONT LENS W/OUT PROPER EYE PROT

RTECS: 9999999ZZ

CONTENT. NOT FOR USE/STOR IN/AROUND HOME. GROUND &

RTECS: 9999999ZZ

W/OUT FULLY UNDERSTANDING REACTIVITY DATA. NO

RTECS: 9999999ZZ

WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR

RTECS: 9999999ZZ

IS NOT IGNITABLE AND IS NOT RCRA HAZARDOUS

RTECS: 9999999ZZ

PURIFYING WITH FILTER UNITS OK.

RTECS: 9999999ZZ

AREAS BELOW FLAM VAPOR CONCENTRATIONS. LOCAL EXHAUST

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYE: VAPS MAY CAUSE IRRIT, TEARING,
BLURRED VISION. DIRECT CONT W/RESIN MAY PRDCE CORNEAL DMG.SKIN:
RPTD/PRLNGD CONT CAN CAUSE IRRIT (POSS SEV). ABSORP OF LIQ THU SKIN
MAY PRDCE DMG TO INTERNAL ORGANS . INHAL: HIGH CONC OF VAPS CAN
CAUSE IRRIT OF RESP TRACT INCL NOSE & THROAT, HDCH, DIZZ, NAUS,
WEAK, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE:GRP 2B (IARC). ANTIC
TO BE CARCIN (NTP).STYRENE:GRP 2B (IARC).EPICHLOROHYDRIN:GRP 2A
(IARC), (ING 18)
Effects of Overexposure:HLTH HAZ: COLLAPSE, COMA & DEATH. LIVER &
KIDNEY DMG HAS BEEN REPORTED AT HIGH DOSES IN ANIMAL STUDIES.
CHLOROCARBON MATLS HAVE PRDCED SENSIT OF MYOCARDIUM TO EPINEPHRINE
IN LAB ANIMALS & COULD HAVE S IMILAR EFT IN HUMANS. ADRENOMIMETICS
(E.G., EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT FOR
LIFE-SUSTAINING USES (ING 5)
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING
DISEASE IN,OR HISTORY OF AILMENTS INVOLVING KIDNEY, LIVER, SKIN,
RESPIRATORY SYSTEM MAY BE AT A GREATER THAN NORM RISK OF DEVELOPING
ADVERSE EFTS WHEN EXPOS TO MATL.

First Aid:EYE: IMMED FLUSH W/LRG AMTS OF H*2O FOR AT LST 15 MIN. SEEK
MED AID. SKIN: REMOVE CONTAM CLTHG. WASH THORO W/SOAP & H*2O. IF
IRRIT PERSISTS, SEEK MED AID. WIPE MATL FROM SKIN. INHAL: REMOVE
FROM EXPOS .IF BRTHG HAS STOPPED/IS DFCLT,ADMIN ARTF RESP/O*2 AS
INDICATED.SEEK MED AID. INGEST:DO NOT INDUCE VOMIT.IMMED SEEK MED
AID.NOTE TO PHYS:THERE IS NO SPECIFIC ANTIDOTE FOR EFTS FROM
OVEREXP. (ING 6)

Flash Point Method:PMCC
Flash Point:84.2F,29.0C
Lower Limits:1.1%
Upper Limits:6.1%
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL OR FOAM. WATER MAY
BE INEFFECTIVE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD PRESS DEMAND SCBA &
FULL PROT EQUIP.USE H*2O TO COOL FIRE-EXPOS CNTNR/STRUCTURE/PROT
PERS.LRG FIRES:FIRE FIGHTING BEST DONE(SUPDAT)
Unusual Fire/Explosion Hazard:HEAT/FIRE CNDTNS: VAPS FORM FLAM/EXPLO
MIX IN AIR.VAPS HEAVY,MAY TRAVEL (GROUND,PIT,SEWER) TO IGNIT
SOURCE-FLASH.IF POLYMER OCCURS, EXPLO RUPTURING MAY (SUPDAT)

Spill Release Procedures:STOP LEAK IF NO RISK INVOLVED.STAY UPWIND. SML
SPILLS:TAKE UP W/SAND/OTHER NONCOMBUST ABSORB MATL. FLUSH AREA
W/H*2O.DIKE LRG SPILLS FOR LATER DISP.CONTAIN RUNOFF FROM FIRE
CNTRL & DILUTION H*2O. PROD RELS INTO ENVIRON MUST BE REPORTED TO
NATL(ING 7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN AREAS/BUILDINGS DESIGNED TO
COMPLY W/OSHA 1910.106. KEEP IN CLSD, LBLD CNTNR W/IN COOL (WELL
SHADED), DRY-VENT AREA.
Other Precautions:AVOID PRLNGD/RPTD BRTHG OF VAPS/MISTS/FUMES. AVOID
PRLNGD/RPTD CONT W/SKIN/EYES. HNDL & USE I/A/W OSHA 29CFR1910.106
LOC CODES. DO NOT WEAR CONTAM CLTHG. DISCARD CONTAM FOOTWEAR. SEE
REACTIVITY DATA. EMPTY CNTNRS MAY RETAIN PROD (ING 8)

Respiratory Protection:NOT REQD UNDER NORM USE CNDTNS.IF VENT DOES NOT
MAINTAIN INHAL EXPOS BELOW TLV (PEL), USE NIOSH/MSHA APPRVD UNIT AS
PER CURRENT 29 CFR1910.134 & MFR'S "INSTRUCTIONS" & "WARNINGS". IF
W/IN OSHA PROT FA CTOR, NIOSH/MSHA APPRVD AIR (ING 14)
Ventilation:NOT NORM REQD.PROVIDE SUFF GEN/LOC EXHST VENT IN
PATTERN/VOL TO CNTRL INHAL EXPOS BELOW CURRENT EXPOS LIMITS & (ING
15)
Protective Gloves:INDUS RESISTANT FLEXIBLE-TYPE (ING 16)
Eye Protection:CHEM WORK GOG/FULL LGTH FACESHLD .
Other Protective Equipment:WEAR INDUS-TYPE WORK CLTHG & SFTY FOOTWEAR.
DEPENDING ON WORKING CNDTNS, I.E., CONT POTNTL, WEAR RESISTANT PROT
(ING 17)
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. SHOWER & CLOTHING CHANGE RECOM AT END OF
EACH SHIFT.
Supplemental Safety and Health
FIRE FIGHT PROC: AT DISTANCE/PROT LOCATION. EXPLO HAZ: OCCUR. STYRENE
VAPS ARE UNINHIBITED. POLYMERS MAY FORM STOR TANK VENTS/FLAME
ARRESTORS RESULTING IN VENT STOPPAGE/EXPLOSIVE RUPTURING. VAPORS
CAN FORM EXPLOSIVE MIXTURE IN AIR AT ELEVATED TEMPS. FIRE CAN
CAUSE EVOLUTION OF HCL & SML AMTS OF CL*2 & PHOSGENE.

Boiling Pt:B.P. Text:295F,146C
Melt/Freeze Pt:M.P/F.P Text:LIQUID
Vapor Pres:4.5 @ 20C
Spec Gravity:1.0-1.4
pH:ACIDIC
Evaporation Rate & Reference:SLOWER (ETHER=1)
Solubility in Water:SLIGHT
Appearance and Odor:MORE VISCOUS THAN WATER. VISCOUS LIQUID WITH
STYRENE ODOR.
Percent Volatiles by Volume:20-70

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, ACIDS, CAUSTIC, METALLIC HALIDES (SALTS).
Stability Condition to Avoid:HEAT, OXIDIZING AGENTS, FREE RADICAL
CATALYSTS, PEROXIDE.
Hazardous Decomposition Products:SMOKE, CO, CO*2, HALOGENS AND HALOGEN
BY PRODUCTS.
Conditions to Avoid Polymerization:HEAT, OXIDIZING AGENTS, FREE RADICAL
CATALYSTS, PEROXIDE.

Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE, & FED REGS. LIQ &
SEMISOLID POLYESTER RESIN WASTE IS HAZ WASTE UNDER RCRA HAVING
CHARACT OF IGNIT-D001. IF POLYESTER RESIN WASTE IS STORED IN CLSD
DRUM, CONTAINED VAPS A RE IGNITABLE. SOLIDIFIED POLYESTER WASTE
(ING 13)

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.