Product ID:UNOCAL 76 UNLEADED PLUS 87 M/H GRADE, PRODUCT CODE 00406
MSDS Date:09/30/1993
FSC:9130
NIIN:01-272-0983
MSDS Number: BPQYQ

UNION OIL CO OF CALIFORNIA UNOCAL CHEMICALS DIV

1201 W 5TH ST
LOS ANGELES, CA 90060
US

Emergency Phone: 800-424-9300(CHEMTREC)/503-641-3222

Info Phone: 213-977-7589

Preparer: MSDS COORDINATOR

Cage: 23034

76 PRODUCTS CO

LOS ANGELES, CA 90017 US

Telephone: 213-977-7589

Cage: 23034

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 85-100%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9293

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 1-5%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 1-15%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 1-21%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

HEXANE (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: 0-4%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 1-5%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 1-5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9293

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYE IRRITANT. SKIN:MAY CAUSE MILD
IRRITATION, DRYING. INHALED:SLIGHRLY TOXIC. ASPIRATION HAZARD.
RESPIRATORY IRRITATION,CNS DEPRESSION. INGESTED:SLIGHTLY TOXIC.
CAUSES G/I IRRITATION, CNS DEPRESSION, NAUSEA, VOMITING.
ASPIRATION HAZARD DURING INGESTION & VOMITING.
Explanation of Carcinogenicity:CONTAINS BENZENE LISTED BY NTP & IARC
AND REGULATED BY OSHA. GASOLINE & GASOLINE ENGINE EXHAUST ARE ALSO
LISTED.
Effects of Overexposure:EYE:STINGING,TEARING,REDNESS & SWELLING.
SKIN:IRRITATION,REDNESS,BURNING,DRYING & CRACKING.
INHALED:RESPIRATORY IRRITATION,COUGHING NAUSEA, CNS DEPRESSION,
SHORTNESS OF BREATH. INGESTED:G/I IRRITATION , NAUSEA, VOMITING,
CNS DEPRESSION.
Medical Cond Aggravated by Exposure:PRE-EXISTING LUNG DISORDERS (E.G.
ASTHMA-LIK CONDITIONS) MAY BE AGGRAVATED BY EXPOSURE.

First Aid:IF IRRITATION PERSISTS OR IS SEVERE, SEE A DOCTOR. EYE:FLUSH
W/WATER 15 MIN. SKIN:WASH WITH SOAP & WATER. REMOVE CONTAMINATED
CLOTHING AND LAUNDER BEFORE REUSE. INHALED:IF ADVERSE SYMPTOMS
DEVELOP, R EMOVE TO FRESH AIR. AID/RESTORE BREATHING IF NECESSARY.
INGESTED:ASPIRATION HAZARD. GET IMMEDIATE MEDICAL CARE. INDUCE
VOMITING WITH IPECAC AT DIRECTION OF PHYSICIAN. NOTE TO
PHYSICIAN:SEE SUPP DATA

Flash Point Method:TCC
Flash Point:-45F,-43C
Autoignition Temp:Autoignition Temp Text:UNK
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON, FOAM OR WATER
SPRAY. WATER MAY BE INEFFECTIVE.
Fire Fighting Procedures:WEAR APPROPIATE PROTECTIVE EQUIPMENT INCLUDING
RESPIRATORY PROTECTION AS CONDITIONS WARRANT.USE WATER SPRAY TO
MINIMIZE OR DISPERSE VAPORS & COOL EQUIPMENT.
Unusual Fire/Explosion Hazard:VAPORS MAY TRAVEL CONSIDERABLE DISTANCES
TO IGNITION SOURCES, IGNITE, FLASHBACK OR EXPLODE. VAPOR/AIR
EXPLOSION HAZARD INDOORS/OUTDOORS OR IN SEWERS.

Spill Release Procedures:EXTREMELY FLAMMABLE! ELIMINATE SOURCES OF
IGNITION. STAY UP WIND. ISOLATE HAZARD AREA. STOP SPILL IF W/O
RISK. WEAR APPROPRIATE PROTECTIVE EQUIPMENT. DIKE FAR AHEAD OF
SPILL. NOTIFY FIRE & GOVERNMENT AUTHORITIES. IMMEDIATE CLEAN UP IS
RECOMMENDED.
Neutralizing Agent:NO INFORMATION GIVEN BY MFR ON MSDS.

Handling and Storage Precautions:KEEP TIGHTLY CLOSED. OPEN
SLOWLY(RELIEV PRESSURE). STORE IN A COOL,DRY,WELL VENTILATED AREA
W/O IGNITION SOURCES. BOND/GROUND EQUIPMENT.
Other Precautions:STORE ONLY IN APPROVED CONTAINERS. PROTECT CONTAINERS
FROM PHYSICAL DAMAGE. KEEP AWAY FROM INCOMPATIBLES. USE EXPLOSION
PROOF EQUIPMENT. DO NOT ENTER CONFINED SPACES W/O FOLLOWING SAFETY
PROCEDURES. W ASH THOROUGHLY AFTER HANDLING.

Respiratory Protection:WHEN EXPOSURE EXCEEDS ESTABLISHED EXPOSURE
LIMITS, USE RESPIRATOR OR GAS MASK WITH APPROPRIATE CARTRIDGES OR
CANISTERS (NIOSH APPROVED IF AVAILABLE) OR SUPPLIED AIR EQUIPMENT.
Ventilation:USE SUFFICIENT EXPLOSION PROOF VENTILATION TO MAINTAIN
AIRBORNE CONCENTRATIONS BELOW THE EXTABLISHED EXPOSURE LIMITS.
Protective Gloves:IMPERMEABLE
Eye Protection:APPROPRIATE EYE PROTECTION RECOMMENDED
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER. WEAR
IMPERVIOUS CLOTHING WHEN NEEDED.
Work Hygienic Practices:MFR: ? HMIS:USE GOOD INDUSTRIAL HYGIENE
PRACTICE. AVOID UNNECESSARY EXPOSURE. WASH THOROUGHLY BEFORE EATING
OR DRINKING
Supplemental Safety and Health
EXPOSURE TO HIGH CONCENTRATIONS MAY BE ASSOCIATED W/CARDIAC
ARRHYTHMIAS. EPINEPHRINE & OTHER SYMPATHOMIMETIC DRUGS MAY INITIATE
THEM. DRUGS W/LESS ARRHYTHMOGENIC POTENTIAL SHOULD BE CONSIDERED.
IF SY MPATHOMIMETIC DRUGS ARE USED, OBSERVE CLLOSELY FOR CARDIAC
ARRHYTHMAS.

HCC:F1
NRC/State Lic Num:NONE
Boiling Pt:B.P. Text:85.0F,29.4C
Vapor Density:>1
Spec Gravity:0.74
Viscosity:NA
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR LIQUID. GASOLINE ODOR.
Percent Volatiles by Volume:100%

Stability Indicator/Materials to Avoid:YES
CONTACT WITH STRONG OXIDIZING AGENTS SUCH AS CHLORINE, PERMANGANATES &
DICHROMATES MAY CAUSE FIRE OR RXPLOSION.
Stability Condition to Avoid:AVOID ALL POSSIBLE SOURCES OF IGNITION.
Hazardous Decomposition Products:COMBUSTION MAY YEILD SIGNIFICANT
AMOUNTAS OF CARBON MONOXIDE & SMALL AMOUNTS OF OXIDES OF SULFUR &
NITROGEN.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:PREVENT SPILL FROM ENTERING SEWERS, STORM
DRAINS, UNAUTHORIZED TREATMENT DRAINAGE SYSTEMS AND NATURAL
WATERWAYS. DISPOSE OF PRODUCT I/A/W FEDERAL, STATE & LOCAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.