Product ID:JP-4
MSDS Date:12/31/1993
FSC:9130
NIIN:01-305-5596
MSDS Number: BPQZH

DIAMOND SHAMROCK REFINING AND MARKETING CO

9830 COLONNADE BLVD
SAN ANTONIO, TX 78269-6000
US

Emergency Phone: 512-641-8800

Info Phone: 512-641-8800

Cage: 3P045

DIAMOND SHAMROCK REFINING AND MARKETING CO

696000 SAN ANTONIO, TX 78269-6000 US

Telephone: 210-641-8601

Cage: 3P045

PENTANE

CAS: 109-66-0

RTECS: RZ9450000

Fraction By Weight: <2.5%

OSHA PEL 1000 PPM/750 STEL

ACGIH TLV: 600 PPM/750STEL;9293

HEXANE (N-HEXANE)

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: <5.5%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

OTHER HEXANE ISOMERS

Fraction By Weight: <5.0%

OSHA PEL 500 PPM

ACGIH TLV: 500 PPM

CYCLOHEXANE (SARA III)

CAS: 110-82-7

RTECS: GU6300000

Fraction By Weight: <3.5%

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM, 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: <1.0%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

METHYLCYCLOHEXANE

CAS: 108-87-2

RTECS: GV6125000

Fraction By Weight: <8.0%

OSHA PEL 500 PPM

ACGIH TLV: 400 PPM; 9293

N-HEPTANE

CAS: 142-82-5

RTECS: MI7700000

Fraction By Weight: <7.0%

OSHA PEL 500 PPM/500 STEL

ACGIH TLV: 400 PPM/500STEL;9293

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: <2.0%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

OCTANE

CAS: 111-65-9

RTECS: RG8400000

Fraction By Weight: <5.5%

OSHA PEL 500 PPM/375 STEL

ACGIH TLV: 300 PPM/375STEL;9293

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: <4.0%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

NONANE

CAS: 111-84-2

RTECS: RA6115000

Fraction By Weight: <3.5%

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM; 9293

TRIMETHYL BENZENE (SARA III)

CAS: 25551-13-7

RTECS: DC3220000

Fraction By Weight: <1.5%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9293

NAPHTHALENE (SARA III)

CAS: 91-20-3

RTECS: QJ0525000

Fraction By Weight: <1.0%

OSHA PEL 10 PPM/15 STEL

ACGIH TLV: 10 PPM/15 STEL; 9293

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

EHTYLENE GLYCOL DIMETHYL ETHER (EGDME, EGDIME OR

CAS: 110-71-4

RTECS: KI1451000

Fraction By Weight: <0.2%

LD50 LC50 Mixture:NOT GIVEN FOR PRODUCT AS A WHOLE
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:MAY IRRITATE UPPER RESPIRATORY TRACT
WITH CENTRAL NERVOUS SYSTEM STIMULATION FOLLOWED BY DEPRESSION,
RESPIRATORY ARREST. PROLONGED AND REPEATED CONTACT MAY CAUSE SKIN
DEFATTING, DERMATITIS. MAY CAUSE SEVERE BURNING SENSATION AND EYE
IRRITATION. INGESTION MAY CAUSE IRRITAION OF MUCOUS MEMBRANES,
NAUSE, VOMITING.
Explanation of Carcinogenicity:CONTAINS B [71-43-2] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:EYE IRRITATION, SKIN IRRITATION, DERMATITIS,
UPPER RESPIRATORY TRACT IRRITATION, NAUSEA, VOMITING, DIARRHEA,
HEADACHE, INCREASE CARDIAC OUTPUT, LOSS OF CONSCIOUSNESS, HEART
DAMAGE, BRAIN DAMAGE, DEATH , IRRITATION OF MUCOUS MEMBRANES OF
THETHROAT, ESOPHAGUS AND STOMACH.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN AND/OR
RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS
PRODUCT.

First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS
OPEN. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING.
WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL
ATTENTION. IN HALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. GET
MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL
ATTENTION.

Flash Point:<-10F,<-23C
Lower Limits:1 %
Upper Limits:6 %
Extinguishing Media:FOAM, DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:CLOTHING, RAGS OR SIMILAR ORGANIC
MATERIALS CONTAMINATED WITH THIS PRODUCT AND STORED IN CLOSED SPACE
MAY UNDERGO SPONTANEOUS COMBUSTION.

Spill Release Procedures:ELIMINATE SOURCES OF IGNITION. EVACUATE AREA.
WEAR PROPER PERSONAL PROTECTIVE EQUIPMENT. CONTAIN SPILL. STOP LEAK
IF CAN DO SO WITHOUT RISK. ABSORB LIQUID WITH SUITABLE ABSORBENT
MATERIAL. COLLECT FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:PROTECT CONTAINERS AGAINST PHYSICIAL
DAMAGE. SEPARATE FROM OXIDIZING MATERIALS. STORE IN COOL, WELL
VENTILATED AREA AWAY FROM SOURCES OF IGNITION.
Other Precautions:AVOID SKIN CONTACT. LAUNDER CONTAMINATED CLOTHING
BEFORE REUSE. USE IN WELL VENTILATED AREAS.

Respiratory Protection:NOT REQUIRED UNDER NORMAL USE. USE NIOSH/MSHA
APPROVED RESPIRATORY PROTECTION FOLLOWING MANUFACTURER'S
RECOMMENDATION WHERE SPRAY, MIST OR VAPOR MAY BE GENERATED.
Ventilation:LOCAL EXHAUST AND MECHANICAL (GENERAL) VENTILATION TO
MAINTAIN EXPOSURE LEVELS.
Protective Gloves:IMPERVIOUS
Eye Protection:SAFETY GLASSES OR GOGGLES
Other Protective Equipment:PROTECTIVE CLOTHING AS REQUIRED TO AVOID
SKIN CONTACT. AN EMERGENCY EYE WASH STATION AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
CONTAMINATED CLOTHING SHOULD BE STORED IN WELL VENTILATED AREAS.

HCC:F2
Boiling Pt:B.P. Text:120-500F
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:2-3 PSI
Vapor Density:NOT GIVEN
Spec Gravity:0.75-0.76
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:TRACE
Appearance and Odor:COLORLESS LIQUID WITRH AROMATIC ODOR
Percent Volatiles by Volume:100 %

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, OPEN FLAME, SPARKS
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
UNIDENTIFIED ORGANIC COMPOUNDS.

Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR
LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.