Product ID:ETHYLENEDIAMINE
MSDS Date:01/29/1992
FSC:6810
NIIN:00-101-7203
MSDS Number: BPYCG

VAN WATERS AND ROGERS INC SUB OF UNIVAR

6100 CARILLON POINT
KIRKLAND, WA 98033
US

Emergency Phone: 206-889-3400

Info Phone: 206-889-3400

Preparer: MSDS COORDINATOR

Cage: 0STM5

VOPAK USA INC

KIRKLAND, WA 98033-7357 US

Telephone: 425-889-3400/425-889-3617

Cage: 0STM5

ETHYLENEDIAMINE (SARA III)

CAS: 107-15-3

RTECS: KH8575000

Fraction By Weight: 99%

OSHA PEL 10 PPM

ACGIH TLV: S, 10 PPM; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:ORAL LD50 (RAT) IS 1460 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: CONTACT WITH SKIN AND EYES MAY
CAUSE SEVERE IRRITATION OR BURNS. INHALATION OF VAPORS MAY CAUSE
SEVERE RESPIRAORY IRRITATION. SWALLOWING MAY CAUSE SEVERE DIGESTIVE
SYSTEM IRRITATION AND BURNS T O MOUTH, THROAT, AND ESOPHAGUS.
CHRONIC:MAY CAUSE PROLONGED OR REPEATED EXPOSURE MAY CAUSE LIVER OR
KINEY DAMAGE.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:INHALED: COUGHING, SHORTNESS OF BREATH, CHEST
PAIN. EYES: BURNING SENSATION, REDNESS, TEARING, BLURRED VISION,
PAIN. SKIN: REDNESS, SWELLING, PAIN. BURNS. INGESTED: SEVERE BURNS
AROUND MOUTH, SORE THR OAT, SEVERE STOMACH PAIN, NAUSEA, VOMITING,
DIARRHEA.
Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY, LIVER, OR
KIDNEY DISEASES MAY BE AGGRAVATED BY EXPOSURE.

First Aid:INHALED: MOVE TO FRESH AIR. GET MEDICAL ATTENTION. EYES:
FLUSH WITH LOTS OF WATER FOR 15 MINUTES, HOLD LIDS OPEN. SEE
DOCTOR. SKIN: REMOVE CONTAMINATED CLOTHES, FLUSH WITH LOTS OF
WATER, THEN WASH WIT H SOAP AND WATER. SEE DOCTOR. INGESTED:DO NOT
INDUCE VOMITING! IF CONSCIOUS, GIVE LARGE AMOUNT OF WATER OR MILK
TO DILUTE. GET IMMEDIATE MEDICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:=38.3C, 101.F
Autoignition Temp:=406.1C, 763.F
Lower Limits:2.6%
Upper Limits:14.2%
Extinguishing Media:WATER FOG, ALCOHOL FOAM, CARBON DIOXIDE, DRY
CHEMICAL
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE CLOTHING.

Spill Release Procedures:DO NOT ALLOW INTO SEWERS OR WATERWAYS. DILUTE
WITH WATER AND RECOVER OR ABSORB WITH INERT MATERIAL AND PLACE IN A
CONTAINER FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A COOL, DRY PLACE BELOW 120F
AND ABOVE 51F. STORE AWAY FROM INCOMPATIBLES.
Other Precautions:DO NOT STORE OR USE NEAR COPPER FIXTURES; THEY MAY
QUICKLY CORRODE.

Respiratory Protection:WHEN REPIRATORY PROTECTION IS REQUIRED FOR
CERTAIN OPERATIONS, USE NIOSH/MSHA APPROVED RESPIRATOR WITH ORGANIC
VAPOR CARTRIDGE. USE IN ACCORDANCE WITH 29 CFR 1910.134.
Ventilation:USE ONLY WITH ADEQUATE MECHANICAL VENTILATION OR LOCAL
EXHAUST.
Protective Gloves:NEOPRENE
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. CLOTHING
TO PREVENT PROLONGED OR REPEATED SKIN CONTACT.
Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
DESTROY CONTAMINATED LEATHER FOOTWEAR.

HCC:F7
Boiling Pt:=113.9C, 237.F
Melt/Freeze Pt:=10.6C, 51.F
Vapor Pres:10 MM HG
Vapor Density:2.1(AIR=1)
Spec Gravity:>0.893(WATER=1)
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID; AMMONIACAL ODOR

Stability Indicator/Materials to Avoid:YES
STRONG MINERAL ACIDS, STRONG OXIDIZING AGENTS, HALOGENATED ORGANICS,
ALDEHYDES, KETONES, AND ACRYLATES.
Stability Condition to Avoid:CONTACT WITH INCOMPATIBLES. AVOID SOURCES
OF IGNITION.
Hazardous Decomposition Products:NITROGEN OXIDES

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. MANUFACTURER RECOMMENDS INCINERATION AT
PERMITTED FACILITY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.