Product ID:Z99-410989-001 SULFURIC ACID ELECTROLYTE(M4
MSDS Date:08/05/1988
FSC:6140
NIIN:01-322-8512
MSDS Number: BQKVT

GNB INCORPORATED

829 PARKVIEW BOULEVARD
LOMBARD, IL 60148
US

Emergency Phone: 708-691-7886/800-424-9300(CHEMTREC)

Info Phone: 708-691-7886

Preparer: JAMES B. DOE, PE

Cage: OMM77

GNB INCORPORATED

MENDOTA HEIGHTS, MN 55118 US

Telephone: 612-681-5000

Cage: OMM77

SULFURIC ACID (SARA III)

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 20-40%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

NON HAZARDOUS INGREDIENTS

Fraction By Weight: 60-80%

LD50 LC50 Mixture:LD50 (ORAL RAT) IS 2140 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION OF VAPORS CAUSES SEVERE
IRRITATION OR BURNS OF THE RESPIRATORY SYSTEM, PULMONARY EDEMA, OR
LUNG INFLAMMATION. EYE CONTACT CAUSES SEVERE DAMAGE AND POSSIBLE
BLINDNESS. SKIN CONTACT CAUSES BU RNS AND POSSIBLE DEEP ULCERATION.
INGESTION CAUSES SEVERE BURNS TO MOUTH, THROAT, AND STOMACH.
Explanation of Carcinogenicity:THIS CHEMICAL IS NOT LISTED BY IARC,
NTP, OR OSHA AS A CARCINOGEN.
Effects of Overexposure:SEVERE IRRITATION OR BURNS TO EYES, NOSE AND
THROAT. PULMONARY EDEMA, BRONICAL EMPHYSEMA, CONJUNCTIVITIS,
STOMATITIS, DENTAL EROSION, NAUSEA AND VOMITING.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE RESPIRATORY TRACT MAY
BE AT INCREASED RISK FROM EXPOSURE.

First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING.
GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER
FOR 15 MINUTES HOLDING EYELIDS OPEN. GET PROMPT MEDICAL ATTENTION.
SKIN :REMOVE CONTAMINATED CLOTHING. WASH WITH PLENTY OF WATER FOR
15 MINUTES. GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING.
GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL
ATTENTION.

Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.

Spill Release Procedures:WEAR FULL PROTECTIVE EQUIPMENT. STOP LEAK IF
YOU CAN DO SO WITHOUT RISK. DIKE TO RETAIN RUNOFF. PUMP LIQUID TO
SALVAGE TANK. NEUTRALIZE SMALL AMOUNTS WITH SODA ASH OR LIME. MAKE
SLURRY AND SHOVEL INTO DISPOSAL DRUM.
Neutralizing Agent:SODIUM BICARBONATE OR A SODA ASH/SLAKED LIME MIXTURE
(50-50)

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP
CONTAINERS AWAY FROM HEAT. ISOLATE FROM INCOMPATIBLE MATERIALS. ADD
ACID TO WATER SLOWLY TO PREVENT SPLATTERING.
Other Precautions:ADDITION TO WATER RELEASES HEAT WHICH CAN RESULT IN
VIOLENT BOILING AND SPATTERING. ALWAYS ANDD SLOWLY AND IN SMALL
AMOUNTS. NEVER USE HOT WATER. NEVER ADD WATER TO ACIDS. ALWAYS ADD
ACIDS TO WATER. E MPTY CONTAINERS MAY BE HAZARDOUS.

Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION EXCEEDS TLV, A NIOSH
APPROVED SELF-CONTAINED BREATHING APPARATUS IS RECOMMENDED.
Ventilation:USE SUFFICIENT MECHANICAL (GENERAL) VENTILATION TO MAINTAIN
EXPOSURE BELOW TLV REQUIREMENTS.
Protective Gloves:POLYVINYL CHLORIDE GLOVES
Eye Protection:CHEMICAL SPLASH GOGGLES AND FACE SHIELD
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE IMPERVIOUS WORK CLOTHING, BOOTS AND APRON AS
REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO
NOT BREATHE VAPORS OR MISTS. DO NOT SMOKE IN VACINITY.

HCC:C1
Boiling Pt:B.P. Text:>219F,>104C
Melt/Freeze Pt:M.P/F.P Text:<8F,<-14C
Vapor Pres:>20.8 MMHG
Vapor Density:3.4(AIR=1)
Spec Gravity:1.130-1.140
Evaporation Rate & Reference:<1(N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR LIQUID WITH SHARP, PENETRATING ODOR

Stability Indicator/Materials to Avoid:YES
ORGANIC MATERIALS, STRONG OXIDIZING AGENTS
Stability Condition to Avoid:CONTACT WITH INCOMPATIBLE MATERIALS.
RUN0FF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD.
Hazardous Decomposition Products:OXIDES OF SULFUR AND HYDROGEN

Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL
APPLICABLE FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.