Product ID:#2 DIESEL FUEL
MSDS Date:12/31/1992
FSC:9140
NIIN:00-286-5294
MSDS Number: BQMBX

DIAMOND SHAMROCK REFINING AND MARKETING CO

9830 COLONNADE BLVD
SAN ANTONIO, TX 78269-6000
US

Emergency Phone: 512-641-8800

Info Phone: 512-641-8601

Cage: 3P045

DIAMOND SHAMROCK REFINING AND MARKETING CO

696000 SAN ANTONIO, TX 78269-6000 US

Telephone: 210-641-8601

Cage: 3P045

PETROLEUM MID-DISTILLATE (DIESEL MARINE FUEL)

CAS: 68476-34-6

Fraction By Weight: 100%

OSHA PEL 5 MG/M3 AS OIL MIST

ACGIH TLV: 5 MG/M3 AS OIL MIST

KEROSENE (PART OF COMPONENT 1)

CAS: 8008-20-6

RTECS: OA5500000

Fraction By Weight: 0-20% %

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM 9091

LIGHT HYDROCARBON BLEND (PART OF COMPONENT 1)

CAS: 64741-59-9

Fraction By Weight: 20-40% %

DISTILLATES,STRAIGHT RUN MIDDLE (PART OF COMPONENT 1)

CAS: 64741-44-2

RTECS: LX3296000

Fraction By Weight: 40-70% %

LD50 LC50 Mixture:TWA=100MG/M3/8HRS (NIOSH PROPOSED)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:UPPER RESPIRATORY TRACT
IRRITATION,CNS EFFECTS(ANESTHETIC LEADING TO RESPIRATORY
ARREST).SKIN:DEFATTING AGENT,IRRITANT.EYES:SEVERE BUT TEMPORARY
IRRITANT.INGEST:IRRITATES MUCOUS MEMBRANES OF THR
OAT,ESOPHAGUS,STOMACH.LUNG DAMAGE CAN RESULT FROM VOMITING.
Explanation of Carcinogenicity:HMIS NOTES THAT RTECS 92-4 LISTS THE
COMPONENTS OF THIS MATERIEL AS EITHER TUMORIGENS AND/OR MUTAGENS.
Effects of
Overexposure:INHAL:DIZZINESS,HEADACHE.OVEREXPOSURE-ANESTHESIA,COMA,
RESPIRATORY ARREST,IRREGULAR HEART
BEAT.SKIN:BURNING.EYES:BURNING,SWELLING OF
LIDS.INGEST:NAUSEA,VOMITING,CNS DEPRESSION.
Medical Cond Aggravated by Exposure:PERSONS WITH RESPIRATORY OR SKIN
AILMENTS MAY BE AT INCREASED RISK FROM EXPOSURE.

First Aid:EYES: IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR
15 MINUTES. SKIN: WASH WITH SOAP AND WATER. REMOVE CONTAMINATED
CLOTHING AND FOOTWEAR. INHALATION: REMOVE TO FRESH AIR. IF
BREATHING HAS ST OPPED, RESUSCITATE AND ADMINISTER OXYGEN IF
NEEDED. INGESTION: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. DO NOT INDUCE VOMITING. KEEP AIRWAY CLEAR. IN ALL CASES,
SEEK MEDICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:140F,60C
Lower Limits:1 %
Upper Limits:5 %
Extinguishing Media:DRY CHEMICAL, FOAM OR CARBON DIOXIDE OR WATER
SPRAY.
Fire Fighting Procedures:PRESSURE-DEMAND, SELF CONTAINED BREATHING
APPARATUS SHOULD BE PROVIDED FOR FIRE FIGHTERS IN BUILDINGS OR
CONFINED AREAS WHERE PRODUCT IS STORED.
Unusual Fire/Explosion Hazard:CLOTHING, RAGS, OR SIMILAR ORGANIC
MATERIAL CONTAMINATED WITH THE PRODUCT AND STORED IN A CLOSED SPACE
MAY UNDERGO SPONTANEOUS COMBUSTION.

Spill Release Procedures:USE PROPER RESPIRATORY AND PROTECTIVE
EQUIPMENT.ADSORB LIQUID WITH FLAME RETARDANT SAWDUST OR
DIATOMACEOUS EARTH;PLACE IN AN APPROPRIATE CONTAINER FOR
DISPOSAL.AVOID RUNOFF INTO WATERWAYS.ANY SUCH SPI LLS MUST BE
REPORTED.
Neutralizing Agent:NONE.

Handling and Storage Precautions:PROTECT FROM PHYSICAL DAMAGE.OUTSIDE
OR DETACHED STORAGE IS PREFERRED.STORE IN A COOL,WELL
VENTILATED,AWAY FROM SOURCE OF IGNITION & OXIDANTS.
Other Precautions:GROUND AND BOND CONTAINERS WHEN TRANSFERRING LIQUID.

Respiratory Protection:NOT REQUIRED UNDER NORMAL USE. USE NIOSH/MSHA
APPROVED RESPIRATORY PROTECTION FOLLOWING MANUFACTURER'S
RECOMMENDATION WHERE SPRAY, MIST OR VAPOR IS GENERATED. SUPPLIED
AIR RESPIRATORY PROTECTION IS RE QUIRED FOR HIGHER CONCENTRATIONS.
Ventilation:WORK IN WELL VENTILATED AREAS.ENGINEERING CONTROLS MUST BE
USED IF WORKING WITH HIGH VOLUMES.
Protective Gloves:IMPERMEABLE GLOVES
Eye Protection:FACE SHIELD & GOGGLES OR CHEMICAL GOGGLE
Other Protective Equipment:STANDARD WORK CLOTHING, ACCESSIBLE EYEWASH
AND SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING, DRINKING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
NONE.

HCC:F4
Boiling Pt:B.P. Text:330F,166C
Vapor Pres:NOT GIVEN
Vapor Density:NOT GIVEN
Spec Gravity:0.82-0.87
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:TRACE
Appearance and Odor:LIQUID:YELLOW TO STRAW COLOR;ARMATIC ODOR.ODOR
THRESHOLD=1PPM.
Percent Volatiles by Volume:100 %

Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS,SUCH AS CHLORINE,CONCENTRATED OXYGEN,SODIUM
HYPOCHLORITE(AND OTHER HYPOCHLORITES).
Stability Condition to Avoid:AVOID PHYSICAL DAMAGE. AVOID SOURCES OF
IGNITION.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE CARBON MONOXIDE, CARBON DIOXIDE AND OTHER HYDROCARBONS.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
LOCAL, STATE AND FEDERAL REGULATIONS. WASTE PRODUCT AND
CONTAMINATED MATERIAL WILL BE CONSIDERED A HAZARDOUS WASTE IF THE
FLASH POINT IS LESS THAN 140F REQ UIRING HAZMAT DISPOSAL.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.