Product ID:ETHANOL SDA 3A 200 PROOF
MSDS Date:09/28/1990
FSC:6810
NIIN:00-201-0904
MSDS Number: BRDHV

UNION CARBIDE CORP., INDUSTRIAL CHEMICALS DIVISION

39 OLD RIDGEBURY ROAD
DANBURY, CT 06817-0001
US

Emergency Phone: 800-822-4357

Info Phone: 304-744-3487

Cage: 61637

UNION CARBIDE CORP

DANBURY, CT 06817-0001 US

Telephone: 800-822-4357/732-563-5522 (MSDS)

Cage: 61637

ETHYL ALCOHOL (ETHANOL)

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 96.2%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9293

METHYL ALCOHOL (METHANOL) (SARA III)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 4.7%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ISOPROPYL ALCOHOL (SARA III)

CAS: 67-63-0

RTECS: NT8050000

Fraction By Weight: 25% PPM

OSHA PEL 400 PPM/500 STEL

ACGIH TLV: 400 PPM/500STEL;9293

ACETALDEHYDE (SARA III)

CAS: 75-07-0

RTECS: AB1925000

Fraction By Weight: 10% PPM

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: C25,A3 93-94

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD50 (ORAL RAT) IS 7060 MG/KG (ETHANOL)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION:MAY CAUSE HEADACHE,
DROWINESS & LASSITUDE, LOSS OF APPETITE & INABILITY TO CONCENTRATE.
IRRITATION OF THE THROAT. INGESTION: CAN CAUSE DEPRESSION OF CNS,
NAUSEA, VOMITING & DIARRHEA. EYE:LIQUID OR VAPOR MAY CAUSE
IRRITATION. SKIN: MAY CAUSE IRRITATION AND DEFATTING OF SKIN ON
PROLONGED CONTACT.
Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS
LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN.
Effects of Overexposure:MAY CAUSE EYE, SKIN & RESPIRATORY TRACT
IRRITATION. INDIVIDUAL RESPONSES TO METHYL ALCOHOL VARY. INGESTION
OF LESS THAN 30 ML HAS BEEN FATAL TO HUMANS. IN GENERAL, A FEW
OUNCES MAY CAUSE BLINDNESS AND DEATH; AS LITTLE AS 4 ML MAY BE
TOXIC IF INGESTED. MAY CAUSE HEADACHE, DROWINESS, CNS DEPRESSION,
NAUSEA, & DIARRHEA.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE SKIN, EYE, RESPIRATORY
TRACT, LIVER OR KIDNEY MAY BE AT INCREASED RISK FROM EXPOSURE.

First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING.
GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER
FOR 15 MINUTES. GET MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED
CLOTHIN G. FLUSH WITH WATER. IF IRRITATION PERSISTS, GET MEDICAL
ADVICE. INGESTION:DO NOT INDUCE VOMITING UNLESS INSTRUCTED TO DO
SO. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL
ATTENTION.

Flash Point Method:TCC
Flash Point:=13.3C, 56.F
Lower Limits:3.3(ETHANOL)
Upper Limits:36(METHANOL)
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS. VAPORS HEAVIER THAN
AIR. CAN TRAVEL ALONG GROUND AND FLASHBACK.

Spill Release Procedures:WEAR APPROPRIATE RESPIRATORY PROTECTION AND
PROTECTIVE CLOTHING. CONTAIN SPILLED MATERIAL. TRANSFER TO SECURE
CONTAINERS. WHERE NECESSARY, COLLECT USING ABSORBENT MEDIA.
ELIMINATE ANY SOURCE OF IGNITI ON. VENTILATE AREA. WASH RESIDUE
WITH WATER.
Neutralizing Agent:NOT APPLICABLE.

Handling and Storage Precautions:STORE IN A FLAMMABLE LIQUID STORAGE
ROOM OR CABINET. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE.
PROTECT CONTAINERS FROM PHYSICAL DAMAGE.
Other Precautions:MAKE FREQUENT CAREFUL LEAKAGE INSPECTIONS. ISOLATE
FROM OXIDEZERS, CHEMICALS CAPABLE OF SPONTANEOUS HEATING, MATERIALS
REACTING WITH AIR OR MOISTURE TO LIBERATE HEAT, IGNITION SOURCES
AND EXPLOSIVES. KEEP OUT OF DIRECT SUN & AWAY FROM HEAT.

Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXPOSURES BELOW PEL(TLV), USE NIOSH/MSHA APPROVED RESPIRATORS.
RESPIRATORS SHOULD BE SELECTED BASED ON THE FORM AND CONCENTRATION
OF CONTAMINANT IN AIR & IN ACCORDANCE WITH OSHA (29 CFR 1910.134).
Ventilation:MECHANICAL (GENERAL) ROOM VENTILATION IS NORMALLY ADEQUATE.
LOCAL EXHAUST MAY BE REQUIRED IF WORK AREA NOT VENTED.
Protective Gloves:NEOPRENE, NITRILE, VPC OR NATURAL RUBBER
Eye Protection:SAFETY GOGGLES WITH OPTIONAL FACE SHIELD
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO
NOT BREATHE VAPORS OR MISTS. CAUTION: FOR MANUFACTURING,
PROCESSING, REPACKING OR INDUSTRIAL USE. NOT FOR HOUSHOLD USE.
CONTAINE R HAZARDOUS WHEN EMPTY. EMPTIED CONTAINERS RETAIN RESIDUAL
LIQUID AND VAPOR. FOLLOW PRECAUTIONS ON LABEL AND IN MSDS.

HCC:F5
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=77.2C, 171.F
Melt/Freeze Pt:<-100.C, -148.F
Vapor Pres:48
Vapor Density:1.6
Spec Gravity:0.791
Evaporation Rate & Reference:3.6 (BUTYL ACETATE = 1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, WATER-WHITE LIQUID. CHARACTERISTIC ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:CARBON MONOXIDE CAN FORM ON INCOMPLETE
COMBUSTION.

Waste Disposal Methods:ALL RECOVERED MATERIAL SHOULD BE PACKAGED,
LABELED, TRANSPORTED, AND DISPOSED OR RECLAIMED IN ACCORDANCE WITH
ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS AND IN
CONFORMANCE WITH GOOD ENGINEERING PRACTICES.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.