Product ID:00375 UNLEADED PLUS GASOLINE
MSDS Date:10/24/1990
FSC:9130
NIIN:01-055-0816
MSDS Number: BRFRX

TEXACO INC.

BEACON, NY 12508-0509
US

Emergency Phone: 914-831-3400

Info Phone: 914-831-3400

Preparer: M.J. VONALLMEN

Cage: 38431

TEXACO INC

509 BEACON, NY 12508-0509 US

Telephone: 914-831-3400

Cage: 7B131

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 1-3.99%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 4-10.99%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 1-3.99%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 4-10.99%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 1-3.99%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9192

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: 0-15%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 95-99.9%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9293

ALIPHATIC PETROLEUM SOLVENT

CAS: 8008-20-6

RTECS: OA5500000

Fraction By Weight: .01-.09%

OSHA PEL 400 PPM PETR. DIST.

ACGIH TLV: 400 PPM RUBBER SOLV.

LD50 LC50 Mixture:ORAL LD50 (RAT) = 18.75 ML/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYES:SLIGHT TO MODERATE
IRRITATION.SKIN:MODERATELY IRRITATING.DERMALLY ABSORBED;LD50 DERMAL
RABBIT>5MG/KG.INHAL:IRRITATES EYES,NOSE,THROAT.CAUSES CNS EFFECTS.
INGEST:MAY CAUSE LUNG DAMAGE IF VOMITTED AFTER
SWALLOWING.CHRONIC-GASOLINE VAPORSMAY CAUSE LIVER AND KIDNEY
DAMAGE.
Explanation of Carcinogenicity:CONTAINS B [71-43-2] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:SKIN:REDNESS,EDEMA,DRYING.INHAL:CNS
EFFECTS-DIZZINESS,BLUISH SKIN COLOR.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES. SKIN: REMOVE
CONTAMINATED CLOTHING;WASH EXPOSED AREA WITH SOAP AND WATER.
INGESTION: DO NOT INDUCE VOMITING! CALL A PHYSICIAN. INHALATION:
REMOVE TO FRESH AIR. G IVE ARTIFICIAL RESPIRATION OR OXYGEN
IFNEEDED.CALL PHYSICIAN.

Flash Point Method:COC
Flash Point:-40F,-40C
Lower Limits:1.4 %
Upper Limits:7.6 %
Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE.
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE ON FLAMES, BUT SHOULD
BE USED TO COOL FIRE-EXPOSED CONTAINERS. USE A SELF-CONTAINED
BRETAHING APPARATUS AND FULL PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND TRAVEL
ALONG THE FLOOR;FLOWING GASOLINE GENERATES STATIC ELECTRICITY
...THIS PRESENTS A FLASHBACK HAZARD.

Spill Release Procedures:ELIMINATE IGNITION SOURCES. VENTILATE AREA.
AVOID BREATHING VAPORS. USE SCBA FOR LARGE SPILLS OR IN CONFINED
AREAS. CONTAIN SPILL IF POSSIBLE. REMOVE WITH NON-FLAMMABLE
ADSORBANT(EG.DIATOMACEOUS EARTH );PLACE IN APPROPRIATE CONTAINER
FOR DISPOSAL.
Neutralizing Agent:NONE

Handling and Storage Precautions:TRANSPORT, HANDLE AND STORE IN
ACCORDANCE WITH OSHA REGULATION 1910.106 AND APPLICABLE D.O.T.
REGULATIONS.
Other Precautions:DANGER! EXTREMELY FLAMMABLE. HARMFUL OR FATAL IF
SWALLOWED!

Respiratory Protection:SCBA OR SUPPLIED AIR RESPIRATORY PROTECTION
REQUIRED FOR ENTRY INTO TANKS, VESSELS, OR OTHER CONFINED SPACES.
Ventilation:ADEQUATE TO MEET PERMISSIBLE CONCENTRATIONS.
Protective Gloves:NITRILE, TEFLON, VITON
Eye Protection:CHEMICAL-TYPE GOGGLES, FACE SHIELD
Other Protective Equipment:PROTECTIVE CLOTHING SUCH AS UNIFORMS,
COVERALLS OR LAB COATS SHOULD BE WORN.
Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET
CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK
AREA.
Supplemental Safety and Health
NONE

HCC:F1
Boiling Pt:B.P. Text:>90F,>32C
Vapor Pres:465-775
Vapor Density:3 - 4.0
Spec Gravity:0.7 - .77
Evaporation Rate & Reference:N.D.
Solubility in Water:SLIGHT
Appearance and Odor:LIQUID;LIGHT STRAW TO LIGHT RED;GASOLINE ODOR
Percent Volatiles by Volume:100 %

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:HEAT, SPARKS, FLAME AND OTHER SOURCES OF
IGNITION.
Hazardous Decomposition Products:TOXIC LEVELS OF CARBON MONOXIDE,
CARBON DIOXIDE, IRRITATING ALDEHYDES AND KETONES.

Waste Disposal Methods:CONSIDERED RCRA HAZARDOUS WASTE;IT IS
TOXIC(BENZENE) AND IGNITABLE(FP=-40F).DISPOSE OF IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.