Product ID:MID-GRADE UNLEADED GASOLINE/NO-LEAD GASOLIN
MSDS Date:01/29/1991
FSC:9130
NIIN:00-148-7102
MSDS Number: BRGGP

TOTAL PETROLEUM INC

EAST SUPERIOR STREET
ALMA, MI 48802
US

Emergency Phone: 517-463-1164

Info Phone: 517-463-1164

Preparer: M. N. MARTIN

Cage: 6G102

TOTAL PETROLEUM INC

ALMA, MI 48801 US

Telephone: 517-463-1164

Cage: 6G102

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CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: 100%

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9293

BENZENE (SARA III), <2.5%

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: SEE # 1%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9293

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ETHYL BENZENE (SARA III), <1.6%

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: SEE # 1%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

P-XYLENE (P-DIMETHYLBENZENE) (SARA III), <1.5%

CAS: 106-42-3

RTECS: ZE2625000

Fraction By Weight: SEE # 1%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

M-XYLENE (M-DIMETHYLBENZENE) (SARA III), <4.0%

CAS: 108-38-3

RTECS: ZE2275000

Fraction By Weight: SEE # 1%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/15OSTEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

O-XYLENE (O-DIMETHYLBENZENE) (SARA III), <1.5%

CAS: 95-47-6

RTECS: ZE2450000

Fraction By Weight: SEE # 1%

OSHA PEL 100PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,2,4-TRIMETHYLBENZENE (SARA III), <2.5%

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: SEE # 1%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9293

TOLUENE (SARA III), <7.0%

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: SEE # 1%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PENTANE, <3%

CAS: 109-66-0

RTECS: RZ9450000

Fraction By Weight: SEE # 1%

OSHA PEL 1000 PPM/750 STEL

ACGIH TLV: 600 PPM/750STEL;9293

HEXANE (N-HEXANE), <3%

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: SEE # 1%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

HEXANE ISOMERS (OTHER THAN N-HEXANE), <10%

Fraction By Weight: SEE # 1%

OSHA PEL 500 PPM/1000 STEL.

ACGIH TLV: 500 PPM/1000 STEL.

LD50 LC50 Mixture:TLV FOR BENZENE IS 10 PPM.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE- INHALATION OF VAPORS MAY CAUSE
CNS DEPRESSION, CONVULSION, LOSS OF CONSCIOUSNESS. INGESTION HAS
SYMPTOMS SIMILAR TO INHALATION & ASPIRATION HAZARD. EYE/SKIN
CONTACT CAUSES IRRITATION. CHRONIC- DERMATITIS, NERVOUS SYSTEM,
KIDNEY, LIVER & BLOOD DISORDERS INCLUDING ANEMIA & LEUKEMIA. KIDNEY
CANCER IN LAB ANIMALS.
Explanation of Carcinogenicity:CONTAINS BENZENE. MAY CAUSE BLOOD
DISEASES INCLUDING LEUKEMIA. VAPORS MAY CAUSE KIDNEY CANCER IN MALE
RATS.
Effects of Overexposure:HEADACHE, NASAL & RESPIRATORY IRRITATION,
NAUSEA, DROWSINESS, FATIGUE, EYE & SKIN IRRITATION, PULMONARY
EDEMA, CONVULSION & LOSS OF CONSCIOUSNESS
Medical Cond Aggravated by Exposure:BENZENE- INDIVIDUALS WITH LIVER,
KIDNEY AND BLOOD DISEASES. HEXANE- INDIVIDUALS WITH NEUROLOGICAL
DISEASES. PETROLEUM SOLVENT- THOSE WITH EXISTING DERMATITIS.

First Aid:CALL A PHYSICIAN IN ALL CASES. EYES:IMMEDIATELY FLUSH WITH
WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP &
WATER. INHALED:REMOVE TO FRESH AIR & PROVIDE CPR/OXYGEN IF
NECESSARY. ORAL: DO NOT INDUCE VOMITING UNLESS INSTRUCTEDBY A
PHYSICIAN. CALL A PHYSICIAN IMMEDIATELY. IF VOMITING OCCURS
SPONTANEOUSLY, KEEP HEAD BELOW HIPS.

Flash Point Method:PMCC
Flash Point:<-45F,<-43C
Lower Limits:1.3
Upper Limits:6.0
Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL AND
VAPORIZING LIQUID TYPE EXTINGUISHERS. WATER MAY BE INEFFECTIVE.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT & A
FULL FACED SELF CONTAINED BREATHING APPARATUS/SUPPLIED-AIR
RESPIRATOR.COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:THE INVISIBLE VAPORS ARE HEAVIER THAN AIR
AND TRAVEL SOME DISTANCE TO IGNITION SOURCES & FLASH BACK. CAN FORM
FLAMMABLE MIXTURE WITH AIR & FLASH AT ROOM TEMP.

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENTS.ELIMINATE ALL
SOURCES OF IGNITION.USE EXPLOSION-PROOF TOOLS.SHUT OFF FUEL
SOURCE.DIKE SPILL.PREVENT LIQUID FROM ENTERING
SEWERS/WATERWAYS.RECOVER FREE LIQUID.ADD SAND,EARTH OR OTHER
ABSORBENT MATERIAL.TRANSFER TOCONTAINER.

Handling and Storage Precautions:STORE IN ACCORDANCE WITH NATIONAL FIRE
PROTECTION ASSOCIATION REGULATIONS. KEEP CONTAINERS CLOSED.
Other Precautions:"EMPTY" CONTAINERS RETAIN RESIDUE AND CAN BE
DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, SOLDER, DRILL OR EXPOSE
SUCH CONTAINERS TO HEAT, FLAME, SPARKS. THEY MAY EXPLODE AND CAUSE
INJURY/DEATH. AVOID REP EATED OR PROLONGED CONTACT WITH SKIN.

Respiratory Protection:NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS OR ORGANIC VAPOR RESPIRATOR OR SUPPLIED-AIR RESPIRATOR,
IF NEEDED.
Ventilation:LOCAL/MECHANICAL (GENERAL) VENTILATION - EXPLOSION PROOF,
WELL GROUNDED EQUIPMENTS
Protective Gloves:RUBBER RECOMMENDED
Eye Protection:CHEMICAL SPLASH GOGGLES & FACE SHIELD
Other Protective Equipment:IMPERVIOUS CLOTHING TO AVOID SKIN AND EYE
CONTACT. EYE WASH STATION & SAFETY SHOWER.
Work Hygienic Practices:AVOID CONTACT WITH EYES, SKIN OR CLOTHING. WASH
HANDS AFTER USING PRODUCT. AVOID BREATHING VAPORS OR MISTS.
Supplemental Safety and Health

HCC:F2
Boiling Pt:B.P. Text:<100F- 437F
Melt/Freeze Pt:M.P/F.P Text:NOT KNOWN
Vapor Pres:400 - 900
Vapor Density:3 - 4
Spec Gravity:0.65 - 0.75
Evaporation Rate & Reference:<1 (ETHER=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:A SILVER, GREY OR CLEAR LIQUID - GASOLINE ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, SPARKS, OPEN FLAMES AND OTHER
SOURCES OF IGNITION
Hazardous Decomposition Products:FUMES, CARBON MONOXIDE, CARBON DIOXIDE
AND OTHER DECOMPOSITION PRODUCTS

Waste Disposal Methods:RECYCLE AS MUCH AS POSSIBLE. TREATMENT, STORAGE,
TRANSPORTATION AND DISPOSAL MUST BE IN ACCORDANCE WITH ALL
APPLICABLE LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.