Product ID:E-SERIES FREEZE-IT;ES120,ES150.
MSDS Date:08/19/1994
FSC:5820
NIIN:00-229-1068
MSDS Number: BRGHK

Emergency Phone: 800-832-4401,800-424-9300(CHEMTREC)

Info Phone: 800-645-5244,800-832-4401

Preparer: MICHAEL S. WATKINS

Cage: 2M589

Telephone: 770-424-4888/800-645-5244

Cage: 2M589

CHLORODIFLUOROMETHANE (SARA III) (CERCLA)

CAS: 75-45-6

RTECS: PA6390000

Fraction By Weight: 100%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM; 9495

LD50 LC50 Mixture:LC50 (ORAL RAT)=300,000PPM/2HRS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: HARMFUL IF INHALED. HIGH
CONCENTRATIONS CAN DISPLACE OXYGEN AND CAUSE DIZZINESS,
UNCONSCIOUSNESS, AND EVEN DEATH. EYES: LIQUID IS IRRITATING AND CAN
CAUSE FROSTBITE. SKIN: CAN CAUSE IRRITA TION, FROSTBITE. INGESTION:
UNLIKELY DUETO VOLATILE NATURE. LIQUID MAY CAUSE FROSTBITE TO MOUTH
AND THROAT TISSUES.
Explanation of Carcinogenicity:NONE OF THE CHEMICALS IN THIS PRODUCT IS
LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN.
Effects of Overexposure:EYES/SKIN: IRRITATION, FROSTBITE. INHALATION:
DIZZINESS, UNCONCONSIOUSNESS, DEATH. INGESTION: UNLIKELY TO HAPPEN.
LIQUID CONTACT MAY CAUSE FROSTBITE TO MOUTH AND THROAT TISSUES.
Medical Cond Aggravated by Exposure:PRE-EXISTING MEDICAL CONDITIONS
INVOLVING THE HEART, LUNGS, SKIN, EYES.

First Aid:EYES: TREAT FOR FROSTBITE, FLUSH WITH WATER. REMOVE CONTACT
LENSES, CONTINUE FLUSHING. GET MEDICAL ATTENTION. SKIN: TREAT FOR
FROSTBITE. REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER.
GET MED ICAL ATTENTION. INHALATION: MOVE TO FRESH AIR. GIVE CPR IF
NOT BREATHING. GIVE OXYGEN IF NEEDED. GET MEDICAL ATTENTION.
INGESTION: TREAT FOR FROSTBITE. DO NOT INDUCE VOMITING. GET MEDICAL
ATTENTION.

Flash Point Method:TOC
Flash Point:NONFLAMMABLE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:NON-FLAMMABLE. USE ALCOHOL FOAM, CARBON DIOXIDE, OR
WATER SPRAY.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:CANS MAY VENT,RUPTURE OR EXPLODE;DEBRIS
AND/ OR TOXIC FUMES MAY BE RELEASED.

Spill Release Procedures:WEAR SCBA AND PERSONAL PROTECTIVE EQUIPMENT.
VENTILATE AREA. ABSORB SPILL WITH INERT MATERIAL. PLACE IN A
CHEMICAL WASTE CONTAINER FOR DISPOSAL. DO NOT FLUSH TO SEWER. AVOID
RUNOFF INTO STORM SEWERS A ND DITCHES WHICH LEAD TO WATERWAYS.
Neutralizing Agent:NONE

Handling and Storage Precautions:STORE IN COOL DRY PLACE AWAY FROM HEAT
AND OPEN FLAME. KEEP CONTAINER CLOSED. DO NOT STORE IN DIRECT
SUNLIGHT. DO NOT REUSE THIS CONTAINER.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. USE WITH ADEQUATE
VENTILATION. AVOID PROLONGED OR REPEATED CONTACT WITH EYES, SKIN,
AND CLOTHING. PRODUCT IS A LEVEL 1 AEROSOL. DO NOT PUNCTURE OR
INCINERATE. DO NOT ST ORE CONTAINERS ABOVE 120F.

Respiratory Protection:THIS MATERIAL DOES NOT HAVE ESTABLISHED EXPOSURE
LIMITS. WEAR A POSITIVE PRESSURE AIR-SUPPLIED RESPIRATOR IN
SITUATIONS WHERE THERE MAY BE POTENTIAL FOR AIRBORNE EXPOSURE.
Ventilation:MECHANICAL (GENERAL) VENTILATION IS USUALLY ADEQUATE. LOCAL
EXHAUST MAY BE NECESSARY TO CONTROL AIRBORNE LEVELS.
Protective Gloves:WEAR RUBBER/CHEMICAL RESISTANT GLOVES.
Eye Protection:SAFETY GLASSES WITH SIDE SHIELDS/GOGGLES
Other Protective Equipment:SAFETY SHOWER AND EYE BATH. INDUSTRIAL TYPE
WORK CLOTHING AND APRON AS REQUIRED TO AVOID PROLONGED OR REPEATED
CONTACT.
Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
NONE.

HCC:V2
Boiling Pt:B.P. Text:-41F,-41C
Vapor Pres:138 PSIG
Vapor Density:2.98A
Spec Gravity:1.19
Solubility in Water:0.30%
Appearance and Odor:CLEAR,COLORLESS LIQUIFIED GAS. SLIGHT ETHEREAL
ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
DO NOT MIX WITH POWDERED ALKALI AND ALKALINE EARTH METALS OR STRONG
OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT >120F, OPEN FLAMES, SOURCES OF
EXCESSIVE HEAT. DO NOT SPRAY NEAR OPEN FLAMES, RED HOT
SURFACES,IGNITION SOURCES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
HYDROCHLORIC AND HYDROFLURIC ACID AND POSSIBLY CARBONYL HALIDES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL REGULATIONS. WATER RUNOFF CAN CAUSE
ENVIRONMENTAL DAMAGES. U.S. REGULATIONS REQUIRE REPORTING SPILLS OF
THIS MATERIAL THAT COULD R EACH ANY SURFACE WATERS.
(1-800-424-8802)

Disclaimer (provided with this information by the compiling agencies):
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of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.