Product ID:R0-044
MSDS Date:09/23/1992
FSC:8010
NIIN:00-926-9174
MSDS Number: BRNQK

CRAWFORD LABS, INC

4165 S EMERALD AVE
CHICAGO, IL 60609
US

Emergency Phone: 312-433-1307

Info Phone: 312-376-7132

Preparer: DAVID SCHMETTERER

Cage: 5V430

CRAWFORD LABORATORIES, INC

CHICAGO, IL 60609 US

Telephone: 312-376-7132

Cage: 5V430

TRIMETHYLOLPROPANE (VAPOR PRESSURE 1 MM HG)

CAS: 77-99-6

Fraction By Weight: 1-5%

NORMAL BUTYL ACETATE (VAPOR PRESSURE 13 MM HG)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 20-50%

OSHA PEL 150 PPM

ACGIH TLV: 150 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PM ACETATE (VAPOR PRESSURE 4 MM HG)

CAS: 108-65-6

RTECS: AI8925000

Fraction By Weight: 5-20%

OSHA PEL NONE ESTABLISHED

ACGIH TLV: NONE ESTABLISHED

100 SOLVENT (VAPOR PRESSURE 9 MM HG)

CAS: 64742-95-6

Fraction By Weight: 1-5%

OSHA PEL 50 PPM

ACGIH TLV: 50 PPM

QUICK DRY MINERAL SPIRITS (VAPOR PRESSURE 8 MM HG)

CAS: 64475-85-0

RTECS: PY8240000

Fraction By Weight: 5-20%

TOLUENE DIISOCYANATE 80% 2,4 ISOMER (CAS 584-84-5)

CAS: 26471-62-5

RTECS: NQ9490000

Fraction By Weight: < 1%

OSHA PEL .02 PPM

ACGIH TLV: .01 PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:OVEREXPOSURE MAY PRODUCE VARIOUS
EFFECTS, INCLUDING, ACUTE TOXICITY, RESULTING IN HEADACHE,
DIZZINESS, NAUSEA, LOSS OF CONSCIOUSNESS. SEVERE EYE IRRITATION
POSSIBLY RESULTING IN PERMANENT DAMAGE. IRRI TATED MUCOUS
MEMBRANES. VOMITING DUE TOINGESTION. DEFATTING & DRYING OF THE
SKIN. SENSITIZATION AFTER REPEATED CONTACT.
Explanation of Carcinogenicity:THIS PRODUCT MAY CONTAIN TRACE AMOUNTS
OF SOME CHEMICALS KNOWN TO STATE OF CALIF TO BE CARCINOGENS OR
REPRODUCTIVE TOX.
Effects of Overexposure:OVERXPOSURE TO AROMATIC ISOCYANATES WILL CAUSE
IRRITATION TO THE RESPIRATORY TRACT (DRY THROAT, COUGH, SHORTNESS
OF BREATH, CHEST TIGHTNESS) RESULTING IN SINUSITIS, BRONCHITIS AND
ASTHMA-LIKE SYMPTOMS .

First Aid:EYES: FLUSH WITH PLENTY OF CLEAN LUKEWARM LOW PRESSURE WATER
FOR 15 MIN., OCCASIONALLY LIFTING EYELIDS. GET MED AID. INHALATION:
REMOVE TO FRESH AIR & RESTORE BREATHING. GET MED AID. KEEP VICTIM
WARM. NEVER GIVE AN UNCONSCIOUS PERSON LIQUIDS. INGESTION: CALL
PHYSICIAN IMMEDIATELY. ONLY INDUCE VOMITING ON INSTRUCTION OF
PHYSICIAN. IF VOMITING OCCURS SPONTANEOUSLY, KEEP HEAD BELOW HIPS,
CONTINUED...

Flash Point Method:SCC
Flash Point:82.0F,27.8C
Lower Limits:0.9 %
Extinguishing Media:FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:WATER USED TO KEEP EXPOSED CONTAINERS COOL, &
TO KEEP FLAMMABLE STRUCTURES WET. DON'T ENTER FIRE AREA W/O
ADEQUATE PROTECTION, HAZARDOUS DECOMP MAY BE PRESENT.
Unusual Fire/Explosion Hazard:WATER PRESSURE MAY SPREAD A FLAMMABLE
LIQUID FIRE. SEALED CONTAINERS MAY EXPLODE IF OVERHEATED.

Spill Release Procedures:WARNING - FLAMMABLE. ELIMINATE ALL IGNITION
SOURCES. HANDLING EQUIPMENT MUST BE GROUNDED TO PRVENT SPARKING.
SOAK UP WITH AN ABSORBENT & PLACE IN NON-LEAKING CONTAINERS. SEAL
TIGHTLY FOR PROPER DISPOS AL.

Handling and Storage Precautions:TREAT AS A HAZARDOUS-FLAMMABLE
MATERIAL. KNOW APPLICABLE D.O.T. REGULATIONS BEFORE ATTEMPTING TO
TRANSPORT THIS MATERIAL.
Other Precautions:WARNING: HOT ORGANIC CHEMICAL VAPORS/MISTS ARE
SUSCEPTIBLE TO SUDDEN SPONTANEOUS COMBUSTION WHEN MIXED WITH AIR.
IGNTION MAY OCCUR AT TEMPERATURES BELOW THOSE PUBLISHED IN THE
LITERATURE AS "AUTOIGNIT ION" OR "IGNITION" TEMPERATURES.

Respiratory Protection:IMPORTANT-MUST PROVIDE ADEQUATE VENTILATION TO
MAINTAIN VAPOR CONCENTRATIONS BELOW THE ESTABLISHED TLV LIMIT AS
GIVEN BY OSHA. IN MORE CONFINED AREAS A RESPIRATOR EQUIPED WITH
ORGANIC VAPOR CARTRIDGE SHOULD BE WORN.
Ventilation:MUST PROVIDE ADEQUATE VENTILATION
Protective Gloves:USE RUBBER GLOVES
Eye Protection:WEAR SAFETY GOGGLES, &/OR FACE SHIELD
Other Protective Equipment:HAVE EYE BATH AND SAFETY SHOWER AVAILABLE
Supplemental Safety and Health
...INGESTION: ..TO PREVENT ASPIRATION OF LIQUID INTO THE LUNGS. NEVER
GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. SKIN CONTACT: FLUSH
WITH WATER WHILE REMOVING CONTAMINATED CLOTHING & SHOES. FOLLOW BY
WASHING WITH SOAP & WATER. DO NOT REUSE CONTAMINATED CLOTHING OR
SHOES. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION

HCC:F3
Boiling Pt:B.P. Text:124 TO 552F
Vapor Density:> AIR
Spec Gravity:0.95
Viscosity:65 C.P.S.
Evaporation Rate & Reference:1.62 X N-BUTYL ACETATE
Solubility in Water:SLIGHT
Appearance and Odor:CLEAR/ SOLVENT ODOR
Percent Volatiles by Volume:68.4

Stability Indicator/Materials to Avoid:YES
MAY BE INCOMPATIBLE WITH OXIDIZING AGENTS & STRONG ALKALIES.
Stability Condition to Avoid:AVOID HEAT, SPARKS, OPEN FLAMES, &
INCOMPATIBILITIES ABOVE HIGH TEMPERATURE, STRONG OXIDIZING
CONDTIONS.
Hazardous Decomposition Products:INCOMPLETE COMBUSTION FOR PRODUCTS
LIKE THIS MAY GENERATE HIGHLY POISONOUS CARBON MONOXIDE & OTHER
TOXIC GASES.
Conditions to Avoid Polymerization:EXTENDED CONTACT WITH AIR/OXYGEN.
WARNING: DO NOT SPRAY-APPLY THIS MATERIAL.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH CURRENT
LOCAL, STATE & FEDERAL REGULATIONS. CONTACT AN APPROVED DISPOSAL
FACILITY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.